Home

Person

Rosario Scopelliti

About
Privacy
Disclaimer

Graph Chatbot

Related publications (393)

Synthesis and characterizations of N,N-bis(diphenylphosphino)ethylaniline derivatives and X-ray crystal structure of palladium (II), platinum (II) complexes

Rosario Scopelliti, Zhaofu Fei, Wee Han Ang

N,N-Bis(diphenylphosphino)ethylaniline compounds, Ph2PN-C6H4-C2H5, with ethyl groups at the ortho- and para-positions have been synthesized. Oxidation of the aminophosphines with hydrogen peroxide, elemental sulfur and selenium gave the corresponding ...

2008

Linked Metal-cluster Systems: Isolation and Characterization of {anti-[(p-cymene)RuCl]-m-[k 2-P,P';k 1-P''-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2

Hisham Ben Hamidane, Zoltan Beni, Rosario Scopelliti, Paul Joseph Dyson, Andrew Douglas Phillips, Christian Hartinger

The new mixed-metal complex {anti-[(p-cymene)RuCl]-m-[k 2-P,P';k 1-P''-(PPh2CH2)3CMe]-[AuCl]}PF6 and its cluster deriv. {anti-[(p-cymene)RuCl]-m-[k 2-P,P';k 1-P''-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2 have been prepd. and characterized. Notably, NMR sp ...

Springer US2008

Nickel Complexes of a Pincer NN2 Ligand: Multiple Carbon-Chloride Activation of CH2Cl2 and CHCl3 Leads to Selective Carbon-Carbon Bond Formation

Rosario Scopelliti, Oleg Vechorkin, Xile Hu

A new pincer-type bis(amido)amine (NN2) ligand and its lithium and nickel complexes, including Ni(II) methyl, ethyl, and phenyl complexes, were synthesized. The Ni(II) alkyl complexes react cleanly with alkyl halides including chlorides to form C−C coupled ...

2008

Boron-Based Rotaxanes by Multicomponent Self-Assembly

Kay Severin, Rosario Scopelliti, Nicolas Christinat

Royal Society of Chemistry2008

Mechanism of Pyridine-Ligand Exchanges at the Different Labile Sites of 3d Heterometallic and Mixed Valence μ3-oxo Trinuclear Clusters

André Merbach, Lothar Helm, Rosario Scopelliti, Fabrice Riblet

The syntheses and single crystal X-ray structural analysis of five novel hetero- and homometallic μ3-oxo trinuclear cluster with the formula [FeIII2MII(μ3-O)(μ-O2CCH3)6(4-Rpy)3] · x(4-Rpy) · y(CH3CN) where R ) Ph for 1(Fe2Mn),2(Fe2Fe), 3(Fe2Co), 4(Fe2Ni) a ...

2008

Multicomponent Assembly of Boronic Acid Based Macrocycles and Cages

Kay Severin, Rosario Scopelliti, Nicolas Christinat

Wiley-VCH Verlag GmbH2008

Visible-Light Excitation of Infrared Lanthanide Luminescence via Intra-Ligand Charge-Transfer State in 1,3-Diketonates Containing Push-Pull Chromophores

Jean-Claude Bünzli, Rosario Scopelliti, Frédéric Gumy

A new 1,3-diketonato ligand containing both an electron-donor [4-(dimethylamino)benzene] and an electron-acceptor (4- nitrobenzene) group and its lanthanide complexes have been prepared. They display an intense intra-ligand charge-transfer absorption trans ...

2008

Synthesis and crystallographic characterisation of the heterodimetallic complex [(dibenzo-18-crown-6)K(m-Cl)3Ru(h6-p-cymene)]

Rosario Scopelliti, Paul Joseph Dyson

The triple-chlorido-bridged heterodimetallic dinuclear complex [(dibenzo-18-crown-6)K(m-Cl)3Ru(h6-p-cymene)] contg. an (h6-arene)RuII fragment and a Group 1 metal crown ether fragment was synthesized and characterized by spectroscopy and X-ray crystallog. ...

2007

Relative carbanion basicities as driving force for an intramolecular silyl migration of lithiated biphenyls

Rosario Scopelliti

A solvent-dependent silyl migration of lithiated biphenyls is described, involving the intermediate formation of a pentacoordinated silicate complex. Differences in the relative basicities of the aryllithium intermediates are the possible driving force for ...

Elsevier2007

A Self-Assembled Receptor for the Recognition of Phosphate and Acetate in Neutral Aqueous Solution

Kay Severin, Rosario Scopelliti, Euro Solari, Zacharias Immanuel Grote

Royal Society of Chemistry2007

Formation of a Ruthenium mu-Carbide Complex with Acetylene as the Carbon Source

Kay Severin, Rosario Scopelliti, Euro Solari, Sébastien Gauthier

Reactions of the dinuclear ruthenium complex [(p-cymene)Ru(mu-Cl)3RuCl(C2H4)(PCy3)] with phenylacetylene or tert-butylacetylene gave the vinylidene complexes [(p-cymene)Ru(mu-Cl)3RuCl(=C=CHR)(PCy3)] (R = tBu, Ph), which were characterized crystallographica ...

2007

Ruthenium Half-Sandwich Complexes with Sterically Demanding Cyclopentadienyl Ligands

Kay Severin, Rosario Scopelliti, Euro Solari, Sébastien Gauthier, Barnali Dutta

2007

Multicomponent Assembly of Boron-Based Dendritic Nanostructures

Kay Severin, Rosario Scopelliti, Nicolas Christinat

2007

Development of nitrile-functionalized ionic liquids for C-C coupling reactions: implication of carbene and nanoparticle catalysts

Rosario Scopelliti, Paul Joseph Dyson, Dongbin Zhao, Zhaofu Fei, Wee Han Ang, Cinzia Chiappe

A series of nitrile-functionalized imidazolium salts (many of which are liquid at room temperature) have been prepared. The reactivity of these salts with PdCl2 has been studied, resulting in salts containing a tetrachloropalladate dianion or co ...

2007

Formation of Boronate Ester Polymers with Efficient Intrastrand Charge Transfer Transitions by Three-Component Reactions

Kay Severin, Rosario Scopelliti, Nicolas Christinat, Ursula Röthlisberger, Emmanuel Croisier, Michele Cascella

The three-component reaction of aryl boronic acids with 1,2,4,5-tetrahydroxybenzene and 1,2-bis(4-pyridyl)ethylene or 4,4-bipyridine leads to the formation of dark-purple boronate ester polymers. Crystallographic analyses show that the polymer strands have ...

2007

Thermodynamic Parameters Governing the Self-Assembly of Head–Head–Head Lanthanide Bimetallic Helicates

Jean-Claude Bünzli, Rosario Scopelliti, Thomas Binderup Jensen

The heterobitopic ligands LABX (X=1,2, 3,4 or 5),diff ering only by a Cl or NEt2 substituent,have been designed to complex with a pair of lanthanide ions to form triple-stranded bimetallic helicates of overall composition [Ln2ACHTUNGTRENUNG(LABX)3]6+. The ...

2007

Investigation into the formation of heteronuclear clusters of formula [ Ru6C(CO)16Ag2X 2]2- (X = Cl, Br or I)

Rosario Scopelliti, Paul Joseph Dyson, Wee Han Ang

Reaction of [Ru6C(CO)16]2− with an excess of AgX (X = Cl, Br or I) affords heteronuclear clusters of formula [{Ru6C(CO)16Ag2X}2]2− in 80% yield, which for X = I and X = ...

2007

Page 17 of 20

Rosario Scopelliti

Graph Chatbot

Synthesis and characterizations of N,N-bis(diphenylphosphino)ethylaniline derivatives and X-ray crystal structure of palladium (II), platinum (II) complexes

Linked Metal-cluster Systems: Isolation and Characterization of {anti-[(p-cymene)RuCl]-m-[k 2-P,P';k 1-P''-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2

Nickel Complexes of a Pincer NN2 Ligand: Multiple Carbon-Chloride Activation of CH2Cl2 and CHCl3 Leads to Selective Carbon-Carbon Bond Formation

Boron-Based Rotaxanes by Multicomponent Self-Assembly

Mechanism of Pyridine-Ligand Exchanges at the Different Labile Sites of 3d Heterometallic and Mixed Valence μ3-oxo Trinuclear Clusters

Multicomponent Assembly of Boronic Acid Based Macrocycles and Cages

Visible-Light Excitation of Infrared Lanthanide Luminescence via Intra-Ligand Charge-Transfer State in 1,3-Diketonates Containing Push-Pull Chromophores

Synthesis and crystallographic characterisation of the heterodimetallic complex [(dibenzo-18-crown-6)K(m-Cl)3Ru(h6-p-cymene)]

Relative carbanion basicities as driving force for an intramolecular silyl migration of lithiated biphenyls

A Self-Assembled Receptor for the Recognition of Phosphate and Acetate in Neutral Aqueous Solution

Formation of a Ruthenium mu-Carbide Complex with Acetylene as the Carbon Source

Ruthenium Half-Sandwich Complexes with Sterically Demanding Cyclopentadienyl Ligands

Multicomponent Assembly of Boron-Based Dendritic Nanostructures

Development of nitrile-functionalized ionic liquids for C-C coupling reactions: implication of carbene and nanoparticle catalysts

Formation of Boronate Ester Polymers with Efficient Intrastrand Charge Transfer Transitions by Three-Component Reactions

Thermodynamic Parameters Governing the Self-Assembly of Head–Head–Head Lanthanide Bimetallic Helicates

Investigation into the formation of heteronuclear clusters of formula [ Ru6C(CO)16Ag2X 2]2- (X = Cl, Br or I)

Dioxygen Activation by Diiminodipyrromethane Complexes of Ni, Pd, and Pt

Lithium Isotope Separation with 12-Metallacrown-3 Complexes

Facile, thermo-reversible cycloaddition of small molecules to a ruthenium(II) arene-diketiminate