Publication

Synthesis and crystallographic characterisation of the heterodimetallic complex [(dibenzo-18-crown-6)K(m-Cl)3Ru(h6-p-cymene)]

Paul Joseph Dyson, Rosario Scopelliti
2007
Journal Articles

Abstract

The triple-chlorido-bridged heterodimetallic dinuclear complex [(dibenzo-18-crown-6)K(m-Cl)3Ru(h6-p-cymene)] contg. an (h6-arene)RuII fragment and a Group 1 metal crown ether fragment was synthesized and characterized by spectroscopy and X-ray crystallog. The solid-state structure clearly reveals the presence of the triple-chlorido-bridged dinuclear complex, whereas NMR investigations in different deuteriated solvents reveal the presence of an essentially 1:1 mixt. of 1 and starting materials, indicating the presence of a dynamic equil.

Official source

https://infoscience.epfl.ch/entities/publication/1f493357-3656-4238-8a0f-0259c998e0b2

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Paul Joseph Dyson, Rosario Scopelliti
2007
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/1f493357-3656-4238-8a0f-0259c998e0b2

About this result

Related concepts (11)

Solid-state chemistry

Solid-state chemistry, also sometimes referred as materials chemistry, is the study of the synthesis, structure, and properties of solid phase materials. It therefore has a strong overlap with solid-state physics, mineralogy, crystallography, ceramics, metallurgy, thermodynamics, materials science and electronics with a focus on the synthesis of novel materials and their characterization. A diverse range of synthetic techniques, such as the ceramic method and chemical vapour depostion, make solid-state materials.

Solid-state physics

Solid-state physics is the study of rigid matter, or solids, through methods such as solid-state chemistry, quantum mechanics, crystallography, electromagnetism, and metallurgy. It is the largest branch of condensed matter physics. Solid-state physics studies how the large-scale properties of solid materials result from their atomic-scale properties. Thus, solid-state physics forms a theoretical basis of materials science. Along with solid-state chemistry, it also has direct applications in the technology of transistors and semiconductors.

Solid

Solid is one of the four fundamental states of matter (the others being liquid, gas, and plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structural rigidity (as in rigid bodies) and resistance to a force applied to the surface. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire available volume like a gas.

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