Publication

Vanadium complexes with N-heterocyclic vinylidene ligands

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Zhaowen Dong, Laura Piveteau, Paul Varava, Bastiaan Kooij
2022
Journal Articles

Abstract

The preparation and the structural characterization of vanadium complexes with terminal and bridging N-heterocyclic vinylidene ligands is reported. The synthesis of the complexes was enabled by utilization of diazoolefins as ligand precursors. Structural data and theoretical results show that N-heterocyclic vinylidenes can act as 6e− donor ligands, leading to strong metal–carbon interactions.

Official source

https://infoscience.epfl.ch/entities/publication/03604099-f951-407e-8223-abe9b6bf200c

About this result

This page is automatically generated and may contain information that is not correct, complete, up-to-date, or relevant to your search query. The same applies to every other page on this website. Please make sure to verify the information with EPFL's official sources.

Graph Chat

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Vanadium complexes with N-heterocyclic vinylidene ligands

Chat with Graph Search

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Synthesis and Reactivity of an Anionic Diazoolefin

A Geometric Transformer for Structural Biology: Development and Applications of the Protein Structure Transformer