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Publication

Large heterometallic coordination cages with gyrobifastigium-like geometry

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Euro Solari, Giacomo Cecot, Stéphanie Prior
2016
Journal Articles

Abstract

Large coordination cages with unusual gyrobifastigium-like geometry were obtained by combining cis-blocked PtII or PdII complexes with clathrochelate-based metalloligands

Official source

https://infoscience.epfl.ch/entities/publication/9e31d87e-a7e6-4f45-b3af-6038d9c187d0

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Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Euro Solari, Giacomo Cecot, Stéphanie Prior
2016
Journal Articles

Abstract

Large coordination cages with unusual gyrobifastigium-like geometry were obtained by combining cis-blocked PtII or PdII complexes with clathrochelate-based metalloligands

Official source

https://infoscience.epfl.ch/entities/publication/9e31d87e-a7e6-4f45-b3af-6038d9c187d0

About this result

Related concepts (4)

Sonogashira coupling

The Sonogashira reaction is a cross-coupling reaction used in organic synthesis to form carbon–carbon bonds. It employs a palladium catalyst as well as copper co-catalyst to form a carbon–carbon bond between a terminal alkyne and an aryl or vinyl halide. R1: aryl or vinyl R2: arbitrary X: I, Br, Cl or OTf The Sonogashira cross-coupling reaction has been employed in a wide variety of areas, due to its usefulness in the formation of carbon–carbon bonds.

Fullerene chemistry

Fullerene chemistry is a field of organic chemistry devoted to the chemical properties of fullerenes. Research in this field is driven by the need to functionalize fullerenes and tune their properties. For example, fullerene is notoriously insoluble and adding a suitable group can enhance solubility. By adding a polymerizable group, a fullerene polymer can be obtained. Functionalized fullerenes are divided into two classes: exohedral fullerenes with substituents outside the cage and endohedral fullerenes with trapped molecules inside the cage.

Bioconjugation

Bioconjugation is a chemical strategy to form a stable covalent link between two molecules, at least one of which is a biomolecule. Recent advances in the understanding of biomolecules enabled their application to numerous fields like medicine and materials. Synthetically modified biomolecules can have diverse functionalities, such as tracking cellular events, revealing enzyme function, determining protein biodistribution, imaging specific biomarkers, and delivering drugs to targeted cells.