Recherche

Afficher tous les résultats pour

Accueil

Personne

Paul Joseph Dyson

À propos
Confidentialité
Mentions légales

Graph Chatbot

Publications associées (668)

Page 2 sur 34

Heterobimetallic Ru(mu-dppm)Fe and homobimetallic Ru(mu-dppm)Ru complexes as potential anti-cancer agents

Paul Joseph Dyson, Lucinda Kate Batchelor

Two heterobimetallic mu-dppm bridged Fe,Ru complexes, [(eta(6)-Arene)RuCl2(mu-dppm)Fe(CO)I(eta(5)-C5H5)] (Ar - C6H6 (1) and p-cymene (2), dppm-1,1-bis(diphenylphosphino)methane) were obtained in a facile reaction between [Fe(eta(5)-C5H5)I(CO)(kappa(1)-dppm ...

2019

Principal Descriptors of Ionic Liquid Co-catalysts for the Electrochemical Reduction of CO2

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Dmitry Vasilyev, Serhii Shyshkanov, Erfan Shirzadi

Electrochemical reduction of carbon dioxide (CO2RR) is promoted by ionic liquid (IL) co-catalysts, and several mechanisms have been proposed to explain their role. Due to the complexity of the CO2RR and the limited number of active IL co-catalysts, a conse ...

AMER CHEMICAL SOC2020

Lysozyme-Induced Transcriptional Regulation of TNF-alpha Pathway Genes in Cells of the Monocyte Lineage

Isabelle Mireille Claude Schepens, Paul Joseph Dyson, Romain Hamelin, Florence Armand

Lysozyme is one of the most important anti-bacterial effectors in the innate immune system of animals. Besides its direct antibacterial enzymatic activity, lysozyme displays other biological properties, pointing toward a significant anti-inflammatory effec ...

2019

Retarding Thermal Degradation in Hybrid Perovskites by Ionic Liquid Additives

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Zhaofu Fei, Mounir Driss Mensi, Felix Daniel Bobbink, Cristina Roldán Carmona, Zhangjun Huang, Marius Franckevicius, Nikita Drigo

Recent years have witnessed considerable progress in the development of solar cells based on lead halide perovskite materials. However, their intrinsic instability remains a limitation. In this context, the interplay between the thermal degradation and the ...

2019

En route to CO2-containing renewable materials: catalytic synthesis of polycarbonates and non-isocyanate polyhydroxyurethanes derived from cyclic carbonates

Paul Joseph Dyson, Felix Daniel Bobbink, Antoine Philippe Van Muyden

Combining CO2-chemistry with biomass conversion allows renewable polymeric materials including polycarbonates and polyhydroxyurethanes (PHUs) to be generated. The demand for robust materials with modular properties that can be prepared on an industrial sca ...

Royal Society of Chemistry2019

3D Conjugated Hole Transporting Materials for Efficient and Stable Perovskite Solar Cells and Modules

Paul Joseph Dyson, Zhaofu Fei, Tom Theodorus Antonius Lummen, Bin Ding, Yong Ding, Keith Gregory Brooks

The orthogonal structure of the widely used hole transporting material (HTM) 2,2 ',7,7 '-tetrakis(N, N-di-p-methoxyphenylamino)-9,9 '-spirobifluorene (Spiro-OMeTAD) imparts isotropic conductivity and excellent film-forming capability. However, inherently w ...

Wiley-V C H Verlag Gmbh2024

Nitrogen-Incorporated Cobalt Sulfide/Graphene Hybrid Catalysts for Overall Water Splitting

Paul Joseph Dyson, Zhaofu Fei, Lu Chen, Yun Tong, Pengzuo Chen

Water electrolysis is an advanced and sustainable energy conversion technology used to generate H-2. However, the low efficiency of the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) hampers the overall water-splitting catalytic perf ...

WILEY-V C H VERLAG GMBH2020

Methanol production from CO(2)via an integrated, formamide-assisted approach

Gunay Imanzade, Jorge Gustavo Uranga, Paul Joseph Dyson, Andreas Züttel, Loris Giovanni Lombardo, Aswin Gopakumar

The synthesis of fuels from CO2 has made tremendous progress in recent years, although practical applications remain limited. Herein, we describe a cyclic process that produces MeOH from CO(2)via formamide intermediates, which are initially reduced using N ...

ROYAL SOC CHEMISTRY2020

Carbazole Treated Waterproof Perovskite Films with Improved Solar Cell Performance

Michael Graetzel, Paul Joseph Dyson, Ursula Röthlisberger, Felix Thomas Eickemeyer, Lukas Pfeifer, Virginia Carnevali, Nikolaos Lempesis, Vladislav Slama, Yeonju Kim, Haizhou Lu, Jaeki Jeong

Surface passivation has been widely employed to suppress non-radiative charge recombination and prevent interfacial charge accumulation in perovskite photovoltaics. In this report, carbazole modified with ammonium iodide connected via alkyl chains of diffe ...

Wiley-V C H Verlag Gmbh2024

Hydrogenation of the pivotal biorefinery platform molecule levulinic acid into renewable fuel gamma-valerolactone catalyzed by unprecedented highly active and stable ruthenium nanoparticles in aqueous media

Paul Joseph Dyson, Antoine Philippe Van Muyden

gamma-Valerolactone (GVL) is a key downstream product of renewable biomass with enormous potential for the manufacture of advanced biofuels, bio-based chemicals, materials or for its direct use as an additive to gasoline and is obtained by the hydrogenatio ...

Pergamon-Elsevier Science Ltd2022

Visualizing Interfacial Energy Offset and Defects in Efficient 2D/3D Heterojunction Perovskite Solar Cells and Modules

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Bin Ding, Yong Ding

Currently, the full potential of perovskite solar cells (PSCs) is limited by chargecarrier recombination owing to imperfect passivation methods. Here, the recombination loss mechanisms owing to the interfacial energy offset and defects are quantified. The ...

Wiley-V C H Verlag Gmbh2023

Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst

Paul Joseph Dyson, Gabor Laurenczy

Hydrogen is one of the essential reactants in the chemical industry, though its generation from renewable sources and storage in a safe and reversible manner remain challenging. Formic acid (HCO2H or FA) is a promising source and storage material in this r ...

American Association for the Advancement of Science2011

Research data supporting "High carrier mobility along the [111] orientation in Cu2O photoelectrodes"

Michael Graetzel, Paul Joseph Dyson, Ulf Anders Hagfeldt, Jingshan Luo, Dan Ren, Linfeng Pan, Lu Chen, Meng Xia, Wenzhe Niu

Included in the dataset are detailed information into the crystallography, morphology, electronic properties, (photo)electrochemical and carrier dynamics of both single-crystal Cu2O thin films and polycrystalline Cu2O with favored crystal orientations. Mul ...

Apollo - University of Cambridge Repository2024

Delineation of the Critical Parameters of Salt Catalysts in the N-Formylation of Amines with CO2

Paul Joseph Dyson, Daniel Ortiz Trujillo, Dmitry Vasilyev, Martin Hulla

N-formylation of amines with CO2 is base-catalyzed and studies of salt catalysts reveal that the reaction is efficiently catalyzed by "free" floating anions of high basicity, as represented in the cover image. More information can be found in the Full Pape ...

WILEY-V C H VERLAG GMBH2019

Discovery of a Highly Active Catalyst for Hydrogenolysis of C-O Bonds via Systematic, Multi-metallic Catalyst Screening

Paul Joseph Dyson, Ning Yan, Antoine Philippe Van Muyden, Sviatlana Siankevich

Hydrogenolysis of C-O bonds is a highly challenging reaction with the most efficient catalysts based on bimetallic assemblies. Systematic studies to identify the optimum metal combination have not been performed and, therefore, we designed a method to scre ...

Wiley-VCH Verlag2019

Insights into the Formation Mechanism of Rhodium Nanocubes

Paul Joseph Dyson, Ning Yan, Yuan Yuan

The mechanism of formation of rhodium nanocubes in the presence of tetradecyltrimethylammonium bromide and polyvinylpyrrolidone in ethylene glycol was studied in situ by XAFS, in conjunction with other ex situ techniques including MALDI-TOF MS, XRD, TEM, a ...

2012

A General and Facile Approach for the Electrochemical Reduction of Carbon Dioxide Inspired by Deep Eutectic Solvents

Paul Joseph Dyson, Dmitry Vasilyev

Deep eutectic solvents (DESs) were applied to the electrochemical CO2 reduction reaction (CO2RR). Choline-based DESs represent a non-toxic and inexpensive alternative to room-temperature ionic liquids (RTILs) as additives to the system or as electrolyte. F ...

2019

Why Are Ionic Liquids Liquid? A Simple Explanation Based on Lattice and Solvation Energies

Paul Joseph Dyson, Corinne Daguenet

We have developed a simple and quant. explanation for the relatively low melting temps. of ionic liqs. (ILs). The basic concept was to assess the Gibbs free energy of fusion (ΔfusG) for the process IL(s) -> IL(l), which relates to the m.p. ...

2006

A Gibeon meteorite yields a high-performance water oxidation electrocatalyst

Paul Joseph Dyson, Arnaud Magrez, Kevin Sivula, Nestor Guijarro Carratala, Florian Le Formal, Mathieu Steven Prévot, Aswin Gopakumar, Wiktor Stefan Bourée

Examining the electrocatalytic performance of naturally-occurring metallic minerals is of interest for energy conversion applications given their unique atomic composition and formation history. Herein, we report the electrocatalytic function of an iron-ba ...

2016

Solvent effects in catalysis: rational improvements of catalysts via manipulation of solvent interactions

Paul Joseph Dyson

In homogeneous catalysis, the main emphasis on improving catalyst performance (rate, yield and selectivity) is directed towards manipulation of the ligands. The steric and electronic effects of ligands are extremely well understood and the rational design ...

2016