Nitrogen-Incorporated Cobalt Sulfide/Graphene Hybrid Catalysts for Overall Water Splitting

Water electrolysis is an advanced and sustainable energy conversion technology used to generate H-2. However, the low efficiency of the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) hampers the overall water-splitting catalytic performance. Here, a hybrid catalyst was constructed from N-doped CoS(2)nanoparticles on N,S-co-doped graphene nanosheets (N-CoS2/G) using a facile method, and the catalyst exhibited excellent bifunctional activity. Introduction of N atoms not only promoted the adsorption of reaction intermediates, but also bridged the CoS(2)nanoparticles and graphene to improve electron transfer. Moreover, using thiourea as both N- and S-source ensured synthesis of much smaller-sized nanoparticles with more surface active sites. Surprisingly, the N-CoS2/G exhibited superior catalytic activity with a low overpotential of 260 mV for the OER and 109 mV for the HER at a current density of 10 mA cm(-2). The assembled N-CoS2/G : N-CoS2/G electrolyzer substantially expedited overall water splitting with a voltage requirement of 1.58 V to reach 10 mA cm(-2), which is superior to most reported Co-based bifunctional catalysts and other non-precious-metal catalysts. This work provides a new strategy towards advanced bifunctional catalysts for water electrolysis.