Structure and Magnetic Properties of a Series of Uranium Bis-Siloxide Complexes

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Although chromium trihalides are widely regarded as a promising class of two-dimensional magnets for next-generation devices, an accurate description of their electronic structure and magnetic interactions has proven challenging to achieve. Here, we quanti ...

The silsesquioxane ligand (Bu-i)(7)Si7O9(OH)(3) ((POSSH3)-P-iBu) is revealed as an attractive system for the assembly of robust polynuclear complexes of uranium(III) and allowed the isolation of the first example of a trinuclear U(III) complex ([U-3((POSS) ...

NMR spectroscopy is a very powerful tool for investigating chemical systems at the atomic level because of its ability to provide information on the local environment and dynamics of the nuclei. Because of this, NMR has become one of the most popular analy ...

Context. Radio observations have revealed magnetic fields in the intracluster medium (ICM) of galaxy clusters, and their energy density is nearly in equipartition with the turbulent kinetic energy. This suggests magnetic field amplification by dynamo proce ...

The inherently low sensitivity of nuclear magnetic resonance (NMR) spectroscopy is the major limiting factor for its application to elucidate structure and dynamics in solids. In the solid state, nuclear spin hyperpolarization methods based on microwave-in ...

We extend the recently proposed semi-Lagrangian algorithm for the extremely anisotropic heat transport equation [Chacón et al., J. Comput. Phys., 272 (2014)] to deal with arbitrary magnetic field topologies. The original scheme (which showed remarkable num ...

Understanding the role of multimetallic cooperativity and of alkali ion-binding in the second coordination sphere is important for the design of complexes that can promote dinitrogen (N-2) cleavage and functionalization. Herein, we compare the reaction pro ...

Rigid saturated nitrogen-containing scaffolds such as 3-azabicyclo[3.1.0]hexanes are very important and frequently occurring motifs in biologically active compounds. We disclose a flexible two-step protocol for their efficient and selective access. A tailo ...

A new version of GBS (Ricci et al. (2012) [27]; Halpern et al. J. Comput. Phys. 315 (2016) 388-408; Paruta et al. (2018) [11]) is described. GBS is a three-dimensional, fluxdriven, global, two-fluid turbulence code developed for the self-consistent simulat ...

The valve mode is the most common operational mode of magnetorheological fluid (MRF) devices in engineering applications. Magnetorheological (MR) valves have been studied upon their self-sensing capabilities resulting from the electromagnetic induction phe ...

Structure and Magnetic Properties of a Series of Uranium Bis-Siloxide Complexes

Chat with Graph Search

Electronic excitations and spin interactions in chromium trihalides from embedded many-body wavefunctions

A trinuclear metallasilsesquioxane of uranium(III)

Development of Dynamic Nuclear Polarization Methods in Solution- and Solid-State NMR

Cosmic evolution of the Faraday rotation measure in the intracluster medium of galaxy clusters

Light-Induced 1H NMR Hyperpolarization in Solids at 9.4 and 21.1 T

An asymptotic-preserving semi-Lagrangian algorithm for the anisotropic heat transport equation with arbitrary magnetic fields

Dinitrogen cleavage by a dinuclear uranium(III) complex

Enantioselective Access to 3-Azabicyclo[3.1.0]hexanes by (CpRhIII)-Rh-x Catalyzed C-H Activation and Cp*Ir-III Transfer Hydrogenation

The GBS code for the self-consistent simulation of plasma turbulence and kinetic neutral dynamics in the tokamak boundary

Microfluidic device for analysis of magnetorheological fluids' properties

Spin and Heat Currents in Magnetic Nanostructures

A Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides

Monodispersed metal clusters in solid matrices: A new experimental setup