Publication

A trinuclear metallasilsesquioxane of uranium(III)

Rosario Scopelliti, Marinella Mazzanti, Farzaneh Fadaei Tirani, Ivica Zivkovic, Nadir Jori, Maxime Christian Gérard Tricoire
2024
Journal Articles

Abstract

The silsesquioxane ligand (Bu-i)(7)Si7O9(OH)(3) ((POSSH3)-P-iBu) is revealed as an attractive system for the assembly of robust polynuclear complexes of uranium(III) and allowed the isolation of the first example of a trinuclear U(III) complex ([U-3((POSS)-P-iBu)(3)]) that exhibits magnetic communication and promotes dinitrogen reduction in the presence of reducing agent.

Official source

https://infoscience.epfl.ch/entities/publication/ca66416f-fdc4-4041-882f-f035b4ba8985

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A trinuclear metallasilsesquioxane of uranium(III)

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