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It is possible to control the geometry and the composition of metallasupramolecular assemblies via the aspect ratio of their ligands. This point is demonstrated for a series of iron- and palladium-based coordination cages. Functionalized clathrochelate com ...

The bimetallic ruthenium complex [(1,3,5-C6H3i-Pr3)Ru(m-Cl)3RuCl(C2H4)(PCy3)] has been synthesized by reaction of [(1,3,5-C6H3i-Pr3)RuCl2)]2 with one equivalent of PCy3 in the presence of ethylene. It can be used as a catalyst precursor for the controlled ...

The dimeric ruthenium complex Cp^RuCl2 is easily accessible in a one-pot reaction from RuCl3(solv)(n) and tert-butylacetylene. It features sterically very demanding "Cp-roof" ligands (Cp^ = eta(5)-1-methoxy-2,4-tert-butyl-3-neopentylcyclopentadienyl), ...

Ditopic N-donor ligands with terminal 4-pyridyl groups are omnipresent in coordination-based self-assembly. The utilization of ligands with 3-pyridyl donor groups is significantly less common, because the intrinsic conformational flexibility of these ligan ...

A new method for the synthesis of industrially important azoimidazolium dyes is presented. The procedure is based on a reagent which is rarely used in the context of synthetic organic chemistry: nitrous oxide (“laughing gas”). N2O is first coupled to N-het ...

Metal-mediated cleavage of the N–N bond is a rarely observed phenomenon in the chemistry of nitrous oxide (N2O). We demonstrate that, upon activation of N2O with N-heterocyclic carbenes, zerovalent nickel is able to insert into the N–N bond to give nitrosy ...

The synthesis and characterization of a new class of neutral aminyl radicals is reported. Monoradicals were obtained by reduction of azoimidazolium dyes with potassium. Structural, spectroscopic, and computational data suggest that the spin density is cent ...

The reaction of cis-blocked, square-planar MII complexes with tetratopic N-donor ligands is known to give metallasupramolecular assemblies of the formula M2nLn. These assemblies typically adopt barrel-like structures, with the ligands paneling the sides of ...

Dinuclear clathrochelate complexes are easily accessible by reaction of zinc(II) triflate or cobalt(II) nitrate with arylboronic acids and phenoldioximes. The utilization of brominated arylboronic acids and/or brominated phenoldioximes allows preparing cla ...

Large coordination cages with unusual gyrobifastigium-like geometry were obtained by combining cis-blocked PtII or PdII complexes with clathrochelate-based metalloligands ...

Euro Solari

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The Ligand Aspect Ratio as a Decisive Factor for the Self-Assembly of Coordination Cages

A Bimetallic Ruthenium Complex as a Catalyst Precursor for the Atom Transfer Radical Polymerization of Methacrylates at Ambient Temperature

Contributions to the Chemistry of the Cyclopentadienyl Complex [Cp^RuCl2](2) ("Cp-roof" = eta(5)-1-Methoxy-2,4-tert-butyl-3-neopentylcyclopentadienyl)

Large, heterometallic coordination cages based on ditopic metallo-ligands with 3-pyridyl donor groups

Synthesis of Azoimidazolium Dyes with Nitrous Oxide

Insertion of Zerovalent Nickel into the N–N Bond of N-Heterocyclic-Carbene-Activated N2O

Neutral Aminyl Radicals Derived from Azoimidazolium Dyes

The Intricate Structural Chemistry of MII2nLn-Type Assemblies

Surface functionalization of dinuclear clathrochelates via Pd-catalyzed cross-coupling reactions: facile synthesis of polypyridyl metalloligands

Breaking the Symmetry: Assembly of Cylindrical Nanostructures with a C3-Symmetrical Ligand

Large heterometallic coordination cages with gyrobifastigium-like geometry

Ruthenium Half-Sandwich Complexes with Sterically Demanding Cyclopentadienyl Ligands

Atom-transfer radical reactions under mild conditions with [RuCl2(1,3,5-C6H3iPr3)]2 and PCy3 as the catalyst precursors

Novel cationic 1,2,4-selenadiazoles: synthesis via addition of 2-pyridylselenyl halides to unactivated nitriles, structures and four-center Se center dot center dot center dot N contacts (vol 50, pg 10689, 2021)

A Self-Assembled Receptor for the Recognition of Phosphate and Acetate in Neutral Aqueous Solution

A New Coupling Reaction for the Synthesis of Ruthenium Halfsandwich Complexes with Sterically Demanding Cyclopentadienyl Ligands