Publication

Insertion of Zerovalent Nickel into the N–N Bond of N-Heterocyclic-Carbene-Activated N2O

Rosario Scopelliti, Kay Severin, Euro Solari, Alexander Tskhovrebov
2013
Journal Articles

Abstract

Metal-mediated cleavage of the N–N bond is a rarely observed phenomenon in the chemistry of nitrous oxide (N2O). We demonstrate that, upon activation of N2O with N-heterocyclic carbenes, zerovalent nickel is able to insert into the N–N bond to give nitrosyl complexes.

Official source

https://infoscience.epfl.ch/entities/publication/4aecd778-4b1a-4839-bd81-3f6a46d3636b

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Insertion of Zerovalent Nickel into the N–N Bond of N-Heterocyclic-Carbene-Activated N2O

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