Publication

A Bimetallic Ruthenium Complex as a Catalyst Precursor for the Atom Transfer Radical Polymerization of Methacrylates at Ambient Temperature

Rosario Scopelliti, Kay Severin, Euro Solari, Quoc Tuan Nguyen, Sébastien Gauthier
2006
Journal Articles

Abstract

The bimetallic ruthenium complex [(1,3,5-C6H3i-Pr3)Ru(m-Cl)3RuCl(C2H4)(PCy3)] has been synthesized by reaction of [(1,3,5-C6H3i-Pr3)RuCl2)]2 with one equivalent of PCy3 in the presence of ethylene. It can be used as a catalyst precursor for the controlled atom transfer radical polymerization of methacrylates at 35 °C. The resulting polymers show low polydispersities.

Official source

https://infoscience.epfl.ch/entities/publication/af8de734-2aa4-47e8-9864-a2cff913faa7

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A Bimetallic Ruthenium Complex as a Catalyst Precursor for the Atom Transfer Radical Polymerization of Methacrylates at Ambient Temperature

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