Lecture

Pool Boiling II: Gibbs Free Energy Analysis

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Description

This lecture delves into the analysis of pool boiling phenomena, focusing on the Gibbs free energy of vapor embryos, onset of nucleate boiling, and bubble departure timescales. The formation of a vapor embryo and the Gibbs free energy change are explored, along with the critical heat flux and film boiling regime. The lecture also covers the Gibbs free energy change in different phases and the equilibrium bubble radius after embryo formation. The discussion extends to the Gibbs free energy change and the equilibrium bubble radius, emphasizing the critical heat flux and thermodynamic equilibrium between phases.

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Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Related concepts (32)

Boiling

Boiling is the rapid phase transition from liquid to gas or vapor; the reverse of boiling is condensation. Boiling occurs when a liquid is heated to its boiling point, so that the vapour pressure of the liquid is equal to the pressure exerted on the liquid by the surrounding atmosphere. Boiling and evaporation are the two main forms of liquid vapourization. There are two main types of boiling: nucleate boiling where small bubbles of vapour form at discrete points, and critical heat flux boiling where the boiling surface is heated above a certain critical temperature and a film of vapour forms on the surface.

Nucleate boiling

In fluid thermodynamics, nucleate boiling is a type of boiling that takes place when the surface temperature is hotter than the saturated fluid temperature by a certain amount but where the heat flux is below the critical heat flux. For water, as shown in the graph below, nucleate boiling occurs when the surface temperature is higher than the saturation temperature (TS) by between . The critical heat flux is the peak on the curve between nucleate boiling and transition boiling.

Vapor

In physics, a vapor (American English) or vapour (British English and Canadian English; see spelling differences) is a substance in the gas phase at a temperature lower than its critical temperature, which means that the vapor can be condensed to a liquid by increasing the pressure on it without reducing the temperature of the vapor. A vapor is different from an aerosol. An aerosol is a suspension of tiny particles of liquid, solid, or both within a gas.

Vapor pressure

Vapour pressure or equilibrium vapor pressure is the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate. It relates to the balance of particles escaping from the liquid (or solid) in equilibrium with those in a coexisting vapor phase. A substance with a high vapor pressure at normal temperatures is often referred to as volatile.

Boiling point

The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum, i.e., under a lower pressure, has a lower boiling point than when that liquid is at atmospheric pressure. Because of this, water boils at under standard pressure at sea level, but at at altitude.

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