Publications de Paul Joseph Dyson

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A series of diruthenium(I) aminocarbyne complexes of general formula Ru2Cp2(CO)(L)(mu-CO){mu-CNMe (Cy)} (L = NH3, 2; Py, 3, PPh3, 4; DMSO, 5; thiourea, 6) and [Ru2Cp2(mu-H)(CO)(2){mu-CNMe (Cy)}], 7, were prepared from the tric ...

New water-soluble 3,5,6-bicyclophosphite ligands based on glucose modified with uracil, 5-fluorouracil or thymine are reported. The phosphite ligands were subsequently reacted with bis[dichlorido(η6-p-cymene)ruthenium(II)] and trirutheniumdodecacarbonyl to ...

A series of half-sandwich cyclopentadienyl rhodium(III) and iridium(III) complexes of the type [CpM(curc/bdcurc) Cl] and [CpM(curc/bdcurc)(PTA)][SO3CF3], in which Cp* = pentamethylcyclopentadienyl, curcH = curcumin and bdcurcH = bisdemethoxycurcumin as O ...

Osmium compounds are attracting increasing attention as potential anticancer drugs. In this context, a series of bifunctional organometallic osmium(II)-p-cymene complexes functionalized with alkyl or perfluoroalkyl groups were prepared and screened for the ...

The emerging CsPbI3 perovskites are highly efficient and thermally stable materials for wide-band gap perovskite solar cells (PSCs), but the doped hole transport materials (HTMs) accelerate the undesirable phase transition of CsPbI3 in ambient. Herein, a d ...

Tridentate cycloplatinated thiosemicarbazone complexes have been prepared from a biologically significant ligand, 3,4-dichloroacetophenone thiosemicarbazone (1). The tetranuclear complex 2 was prepared by reaction of the ligand with K-2[PtCl4]. Two mononuc ...

The selective catalytic decomposition of formic acid into hydrogen and carbon dioxide has been achieved in water under mild conditions. For the first time, a ruthenium ion in combination with series of oligocationic, ammoniomethyl-substituted triarylphosph ...

The employment of 2D perovskites is a promising approach to tackling the stability and voltage issues inherent in perovskite solar cells. It remains unclear, however, whether other perovskites with different dimensionalities have the same effect on efficie ...

The modulation of the metastatic progression of breast cancer has been evaluated in vitro and in vivo with RAPTA-T, [Ru(η6-toluene)Cl2(PTA)], an organometallic ruthenium compd. In vitro RAPTA-T inhibits some steps of the metastatic process such as the deta ...

The invention relates to a method for direct conversion of plastic materials into methane and/or liquid fuel and use of ruthenium-modified zeolite to catalyse this conversion. ...

Ruthenium(II)-arene RAPTA-type compounds have been extensively explored for their medicinal properties. Herein a comprehensive review of this class of compounds is provided. A discussion of the basic RAPTA structure is given together with the ways it has b ...

Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) has been used to probe the interaction of the anticancer drug cisplatin with oligonucleotides. The binding kinetics, the nature of the adducts formed, and the location of the binding s ...

Dinudear metal complexes have emerged as a promising class of anticancer compounds with the ability to cross-link biomolecular targets. Here, we describe two novel series of phosphine-linked dinudear ruthenium(II) p-cyrnene and gold(I) complexes, in which ...

Three new dinuclear arene ruthenium metalla-clips of the general formula [(p-cymene)(2)Ru2Cl2(mu-L)] have been prepared from {(p-cymene)(2)Ru2Cl2(p-Cl)(2)] and H2L organic linkers (H2La = diethyl-1,2-diazeneclicarboxylate, H2Lb = N,N'-bis(2-hydroxyethyl)ox ...

Ru-II(arene) anticancer compounds with maleimide functionality were prepared to allow selective interaction with thiol-containing biomolecules and thereby enforcing the selective delivery of the compounds to the tumour. ...

Spiro-OMeTAD is a widely used hole transport material (HTM) in perovskite solar cells (PSCs), but its inherent low hole mobility and poor thermal stability affect the overall performance of PSCs. To overcome these limitations, we develop a series of fluore ...

Paul Joseph Dyson

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Conservative management of retinoblastoma: Challenging orthodoxy without compromising the state of metastatic grace. "Alive, with good vision and no comorbidity" (vol 73, 100764, 2019)

Tuning In Vitro Cytotoxicity in Diruthenium(I) bis-Cyclopentadienyl Complexes

Ruthenium(II)–arene and triruthenium-carbonyl cluster complexes with new water-soluble phopsphites based on glucose: Synthesis, characterization and antiproliferative activity

Organometallic rhodium(III) and iridium(III) cyclopentadienyl complexes with curcumin and bisdemethoxycurcumin co-ligands

Anticancer Organometallic Osmium(II)-p-cymene Complexes

Dopant‐Free Hole Transport Materials Afford Efficient and Stable Inorganic Perovskite Solar Cells and Modules

Exploring the Versatility of Cycloplatinated Thiosemicarbazones as Antitumor and Antiparasitic Agents

Ruthenium(II)-Catalyzed Hydrogen Generation from Formic Acid using Cationic, Ammoniomethyl-Substituted Triarylphosphine Ligands

Passivation Mechanism Exploiting Surface Dipoles Affords High-Performance Perovskite Solar Cells

Thermoresponsive Chlorambucil Derivatives for Tumour Targeting

Modulation of the metastatic progression of breast cancer with an organometallic ruthenium compound

Direct conversion of plastic materials into methane and liquid fuels

The development of RAPTA compounds for the treatment of tumors

High Resolution Mass Spectrometry for Studying the Interactions of Cisplatin with Oligonucleotides

Introduction to the Organometallics in Biology and Medicine Issue

Influence of the Linker Length on the Cytotoxicity of Homobinuclear Ruthenium(II) and Gold(I) Complexes

Strategy to Optimize the Biological Activity of Arene Ruthenium Metalla-Assemblies

Maleimide-functionalised organoruthenium anticancer agents and their binding to thiol-containing biomolecules

Rational design of platinum(IV) compounds to overcome glutathione-S-transferase mediated drug resistance

Fluorene-Terminated π-Conjugated Spiro-Type Hole Transport Materials for Perovskite Solar Cells