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César Pulgarin

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Publications associées (226)

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E. coli Inactivation by High-Power Impulse Magnetron Sputtered (HIPIMS) Cu Surfaces

César Pulgarin, Juan Kiwi, Andrzej Kulik

This study reports HIPIMS-sputtered samples of Cu-particulate films with currents at 6 and 60 amps leading to E. coil inactivation. The Cu coverage and nanoparticle structure of the fibers is reported by TEM. Evidence is presented of redox processes in the ...

2011

Light wavelength-dependent E. coli survival changes after simulated solar disinfection of secondary effluent

César Pulgarin, Sami Rtimi, Stefanos Giannakis

In this study, the photoreactivation and the modification of dark repair of E. coli in a simulated secondary effluent were investigated after initial irradiation under different conditions. The simulated solar exposure of the secondary wastewater was follo ...

Royal Society of Chemistry2015

Photocatalytic evaluation of TiO2/nylon systems prepared at different impregnation times

César Pulgarin, Juan Kiwi

TiO2/nylon fabrics were investigated for methanol degradation under UV light irradiation. TiO2 Degussa P-25 was supported on nylon by immersing the nylon in sol-gel TiO2 and silicone. The TiO2 layers on the nylon were explored as a function of the time of ...

Elsevier2011

Optimizing the solar photo-fenton process in the treatment of contaminated water. Determination of intrinsic kinetic constants for scale-up

César Pulgarin

The elimination of aromatic compounds present in surface water by photo-Fenton with sunlight as the source of radiation was studied. The concentrations of Fe3+ and H2O2 are key factors for this process. A solar simulator and a prototype parabolic collector ...

2005

In Vitro and In Vivo Effectiveness of an Innovative Silver-Copper Nanoparticle Coating of Catheters To Prevent Methicillin-Resistant Staphylococcus aureus Infection

César Pulgarin, Juan Kiwi, Sami Rtimi, Myriam Koumba Sarah Ballo

In this study, silver/copper (Ag/Cu)-coated catheters were investigated for their efficacy in preventing methicillin-resistant Staphylococcus aureus (MRSA) infection in vitro and in vivo. Ag and Cu were sputtered (67/33% atomic ratio) on polyurethane cathe ...

American Society for Microbiology2016

Kinetics and mechanism for transparent polyethylene-TiO2 films mediated self-cleaning leading to MB dye discoloration under sunlight irradiation

César Pulgarin, Juan Kiwi, Sami Rtimi, Rosendo Sanjines

Polyethylene-TiO2 (from now on PE-TiO2) transparent, non-scattering sputtered films have been found effective in the discoloration of methylene blue (MB) under low intensity solar simulated light. By Fourier transform attenuated infrared spectroscopy (ATR- ...

Elsevier Science Bv2015

Photocatalytic degradation of p-halophenols in TiO2aqueous suspensions: halogen effect on removal rate aromatic intermediates and toxicity variations

César Pulgarin, Sandra Parra Cardona, Miléna Lapertot

he influence of the halogen upon the TiO2 photocatalytic degradation of p-halophenols in water has been investigated. Phenol was used as the reference compound. Compared with its value for phenol, the apparent first-order rate constant of removal, k, was s ...

2006

Impact of different light intermittence regimes on bacteria during simulated solar treatment of secondary effluent: Implications of the inserted dark periods

César Pulgarin, Stefanos Giannakis

In this study, the effect of light intermittence on solar disinfection of secondary treated wastewater was investigated. Synthetic secondary effluent was spiked with Escherichia coli and submitted to 3 different light intermittence regimes by circulating t ...

Pergamon-Elsevier Science Ltd2013

Field solar degradation of pesticides and emerging water contaminants mediated by polymer films containing titanium and iron oxide with synergistic heterogeneous photocatalytic activity at neutral pH

César Pulgarin, Félicien Mazille

Photocatalytic degradation of phenol, nalidixic acid, mixture of pesticides, and another of emerging contaminants in water was mediated by TiO2 and iron oxide immobilized on functionalized polyvinyl fluoride films (PVFf-TiO2-Fe oxide) in a compound parabol ...

2010

Detrimental vs. beneficial influence of ions during solar (SODIS) and photo-Fenton disinfection of E. coli in water: (Bi)carbonate, chloride, nitrate and nitrite effects

César Pulgarin, Stefanos Giannakis

In this work, we studied the effect of inorganic ions occurring in natural waters on E. coli inactivation by solar and photo-Fenton processes, two crucial methods for drinking water treatment in sunny or developing countries. HCO3-, Cl-, SO42-, NO3-, NO2- ...

2020

TiO2 PHOTOCATALYTIC INACTIVATION UNDER SIMULATED SOLAR LIGHT OF BACTERIAL CONSORTIA IN DOMESTIC WASTEWATERS PREVIOUSLY TREATED BY UASB, DUCKWEED AND FACULTATIVE PONDS

César Pulgarin, Julian Andrés Rengifo Herrera

In this work, TiO2 photocatalysis was used to disinfect domestic wastewaters previously treated by different biological treatment systems: Upward-flow Anaerobic Sludge Blanket (UASB), facultative pond, and duckweed pond. The microorganisms monitored were E ...

Sociedade Brasileira de Quimica / Sociedade Brasileira de Química2010

New helio-photocatalytic-photovoltaic hybrid system for simultaneous water decontamination and solar energy conversion

César Pulgarin, Victor Sarria

Test results for a designed and installed hybrid photocatalytic–photovoltaic system (HPPS) are presented in this paper. The HPPS consists of one device with dual functions: The photocatalytic system uses UV radiation to promote degradation of organic pollu ...

2005

Effect of advanced oxidation processes on the micropollutants and the effluent organic matter contained in municipal wastewater previously treated by three different secondary methods

César Pulgarin, Luiz Felippe De Alencastro, Dominique Grandjean, Stefanos Giannakis

In this study, wastewater from the output of three different secondary treatment facilities (Activated Sludge, Moving Bed Bioreactor and Coagulation-Flocculation) present in the municipal wastewater treatment plant of Vidy, Lausanne (Switzerland), was furt ...

Elsevier2015

Abatement of organics and Escherichia coli by N, S co-doped TiO2 under UV and visible light. Implications of the formation of singlet oxygen (1O2) under visible light

László Forró, César Pulgarin, Juan Kiwi, Andrzej Sienkiewicz, Julian Andrés Rengifo Herrera

2009

Evaluation of the efficiency of the photo Fenton disinfection of natural drinking water source during the rainy season in the Sahelian region

César Pulgarin, Juliette Ndounla

The photo-disinfection of water from two different wells (W1, pH: 4.6–5.1 ± 0.02) and (W2 pH: 5.6–5.7 ± 0.02) was carried out during the rainy season at Ouagadougou–Burkina Faso, West Africa. The weather variation during the rainy season significantly affe ...

Elsevier2014

Effect of Fe(II)/Fe(III) species, pH, irradiance and bacterial presence on viral inactivation in wastewater by the photo-Fenton process: Kinetic modeling and mechanistic interpretation

César Pulgarin, Sami Rtimi, Michaël Bensimon, Stefanos Giannakis, Anna Carratala Ripolles

Advanced Oxidation Processes and in particular photo-Fenton, represent promising strategies of pathogen inactivation in wastewater effluents. Nevertheless, its full potential is not yet unlocked, as the efficacy of photo-Fenton against viruses has not been ...

Elsevier2017

Irreversible inactivation of carbapenem-resistant Klebsiella pneumoniae and its genes in water by photo-electro-oxidation and photo-electro-Fenton- Processes action modes

César Pulgarin

Carbapenem-resistant Klebsiella pneumoniae is a critical priority pathogen according to the World Health Organization's classification. Effluents of municipal wastewater treatment plants (EWWTP) may be a route for K. pneumoniae dissemination. Herein, the i ...

ELSEVIER2021

Grafted semiconductors on PE-films leading to bacterial inactivation: Synthesis, characterization and mechanism

César Pulgarin, Juan Kiwi, Sami Rtimi

This study reports the colloidal preparation FeOx, TiO2 and FeOx-TiO2 grafted on polyethylene (PE) films leading to bacterial inactivation. A fast bacterial inactivation was attained by the FeOx-TiO2 compared to the FeOx-PE film due to the interfacial char ...

Elsevier2017

Employing bacterial mutations for the elucidation of photo-Fenton disinfection: Focus on the intracellular and extracellular inactivation mechanisms induced by UVA and H2O2

César Pulgarin, Stefanos Giannakis

The bacterial inactivation mechanisms by solar light and the photo-Fenton process is still a matter of debate. In this study, we bring evidence towards the elucidation of the mechanisms that govern photo-Fenton disinfection at near-neutral pH. With the use ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Acids from fruits generate photoactive Fe-complexes, enhancing solar disinfection of water (SODIS): A systematic study of the novel " fruto-Fenton " process, effective over a wide pH range (4-9)

César Pulgarin, Stefanos Giannakis, Aline Laetitia Schaub

This study aimed to enhance solar disinfection (SODIS) by the photo-Fenton process, operated at natural pH, through the re-utilization of fruit wastes. For this purpose, pure organic acids present in fruits and alimentary wastes were tested and compared wi ...

Pergamon-Elsevier Science Ltd2024