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Michael Graetzel

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Publications associées (1 223)

Bistriphenylamine-based organic sensitizers with high molar extinction coefficients for dye-sensitized solar cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Hoi Nok Tsao, Filippo de Angelis

A series of novel bistriphenylamine-based organic sensitizers (coded as RC-dyes) with high molar extinction coefficients (>5.0 x 10(4) M-1 cm(-1)) have been synthesized for dye-sensitized solar cells (DSSCs). By changing the length of the pi-conjugation br ...

2012

A Simple Approach to Room Temperature Phosphorescent Allenylidene Complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Davide Di Censo, Rosario Scopelliti, Ursula Röthlisberger, Ivano Tavernelli, Basile Curchod

Wiley-Blackwell2012

Recent developments in redox electrolytes for dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Carole Graetzel, Mingkui Wang

Redox electrolytes have proven to be extremely important in determining the performance of dye-sensitized solar cells (DSCs). The design and understanding of the redox couple, especially iodide free systems, has become a recent focus of DSC electrolyte res ...

Royal Society of Chemistry2012

Molecular-Scale Interface Engineering of Nanocrystalline Titania by Co-adsorbents for Solar Energy Conversion

Michael Graetzel, Shaik Mohammed Zakeeruddin, Robin Humphry-Baker, Péter Kalman Péchy, Mingkui Wang

The use of mixed self-assembled monolayers, combining hydrophobic co-adsorbents with the sensitizer, has been demonstrated to enhance the efficiency of dye-sensitized solar cells (DSCs). Herein, the influence of the anchoring groups of the co-adsorbents on ...

2012

Adsorbate-Induced Modification of Surface Electronic Structure: Pyrocatechol Adsorption on the Anatase TiO2 (101) and Rutile TiO2 (110) Surfaces

Michael Graetzel

Photoemission and near-edge X-ray absorption fine structure (NEXAFS) techniques have been used to study the adsorption of pyrocatechol on anatase TiO2 (101) and rutile TiO2 (110) single crystals. Photoemission results suggest the pyrocatechol molecule adso ...

American Chemical Society2012

Anthocyanins and betalains as light-harvesting pigments for dye-sensitized solar cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Alessandro Sinopoli, Jun Ho Yum

We present the photoelectrochemical properties of dye-sensitized solar cells using natural pigments containing betalains and anthocyanins as sensitizers. The dyes extracted from grape, mulberry, blackberry, red Sicilian orange, Sicilian prickly pear, eggpl ...

2012

Influence of Halogen Atoms on a Homologous Series of Bis-Cyclometalated Iridium(III) Complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti, Ursula Röthlisberger, Ivano Tavernelli, Basile Curchod, Frédéric Steimer

A series of homologous bis-cyclometalated iridium(III) complexes Ir(2,4-di-X-phenyl-pyridine)2(picolinate) (X = H, F, Cl, Br) HIrPic, FIrPic, ClIrPic, and BrIrPic has been synthesized and characterized by NMR, X-ray crystallography, UV–vis absorption and e ...

2012

Near-UV to red-emitting charged bis-cyclometallated iridium(III) complexes for light-emitting electrochemical cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Davide Di Censo, Rosario Scopelliti

Herein we report a series of charged iridium complexes emitting from near-UV to red using carbene-based (NC)-C-boolean AND: ancillary ligands. Synthesis, photophysical and electrochemical properties of this series are described in detail together with X-ra ...

Royal Society of Chemistry2012

Metal complexes for use as dopants and other uses

Michael Graetzel, Mohammad Khaja Nazeeruddin, Julian Burschka

The invention relates to electrochemical devices comprising complexes of cobalt comprising at least one ligand with a 5- or six membered, N-containing heteroring. The complex are useful as p- and n- dopants, as over of electrochemical devices, in particula ...

2012

Modeling Ruthenium-Dye-Sensitized TiO2 Surfaces Exposing the (001) or (101) Faces: A First-Principles Investigation

Michael Graetzel, Mohammad Khaja Nazeeruddin, Ladislav Kavan, Filippo de Angelis

We present a first-principles computational investigation on the adsorption mode and electronic structure of the highly efficient heteroleptic ruthenium dye C101, [NaRu(4,4'-bis(5-hexylthiophene-2-yl)-2,2'-bipyridine)(4-carboxylic acid-4'-carboxylate-2,2'- ...

American Chemical Society2012

Cyclometalated Ruthenium Dyes for DSSC

Michael Graetzel, Mohammad Khaja Nazeeruddin

A novel thiocyanate-free cyclometalated ruthenium sensitizer for solar cells is designed and developed. Upon anchoring to nanocrystalline TiO2 films, it exhibits a remarkable incident monochromatic photon-to-current conversion efficiency of 83%. The solar ...

Technical Assoc of Photopolymers Japan2012

A silica sol-gel design strategy for nanostructured metallic materials

Michael Graetzel, Scott Charles Warren

Batteries, fuel cells and solar cells, among many other high-current-density devices, could benefit from the precise meso-to macroscopic structure control afforded by the silica sol-gel process. The porous materials made by silica sol-gel chemistry are typ ...

Nature Publishing Group2012

Electrical Properties of Nb-, Ga-, and Y-Substituted Nanocrystalline Anatase TiO2 Prepared by Hydrothermal Synthesis

Michael Graetzel, Aravind Kumar Chandiran

Nanocrystalline anatase titanium dioxide powders were produced by a hydrothermal synthesis route in pure form and substituted with trivalent Ga3+ and Y3+ or pentavalent Nb5+ with the intention of creating acceptor or donor states, respectively. The electri ...

Wiley-Blackwell2012

Correlating long-lived photogenerated hole populations with photocurrent densities in hematite water oxidation photoanodes

Michael Graetzel, Kevin Sivula

Photogenerated charge carrier dynamics are investigated as a function of applied bias in a variety of different hematite photoanodes for solar water oxidation. Transient absorption spectroscopy is used to probe the photogenerated holes, while transient pho ...

2012

Light scattering enhancement from sub-micrometer cavities in the photoanode for dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Takeru Bessho, Nripan Mathews

A simple cell architecture that achieves enhanced light harvesting with less dye quantity while simultaneously improving the power conversion efficiency (PCE) of dye-sensitized solar cells is presented. Polystyrene (PS) spheres of sub-micrometer size were ...

Royal Society of Chemistry2012

Significant Improvement of Dye-Sensitized Solar Cell Performance by Small Structural Modification in π-Conjugated Donor-Acceptor Dyes

Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Robin Humphry-Baker, Joël Teuscher, Magdalena Anna Marszalek, Mateusz Barnaba Wielopolski, Amaresh Mishra

Two donor-π-acceptor (D-π-A) dyes are synthesized for application in dye- sensitized solar cells (DSSC). These D-π-A sensitizers use triphenylamine as donor, oligothiophene as both donor and π-bridge, and benzothiadiazole (BTDA)/cyanoacrylic acid as accept ...

Wiley-Blackwell2012

Tuning spectral properties of phenothiazine based donor-pi-acceptor dyes for efficient dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Robin Humphry-Baker, Magdalena Anna Marszalek

Two novel metal-free organic donor-pi-acceptor dyes were synthesized using electron-rich 10-butyl-(2-methylthio)-10H-phenothiazine as a donor and cyanoacrylic acid as an acceptor. The spectral response of the dye was tuned by introducing a vinylene thiophe ...

Royal Society of Chemistry2012

Themed issue: nanomaterials for energy conversion and storage

Michael Graetzel, Kuppuswamy Kalyanasundaram

The rich and diverse aspect of nanomaterials for energy conversion and storage has been the research topic for many researchers. Photovoltaic solar cells for the direct conversion of sunlight to electricity can be grouped under three generations. One appro ...

Royal Society of Chemistry2012

Evaluation of a Ruthenium Oxyquinolate Architecture for Dye-Sensitized Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Jun Ho Yum, Yu-Ting Huang, Chenxu Zhao

Synthesis of the Ru(dcbpy)(2)(OQN) complex is reported in which dcbpy and OQN(-) are the bidentate 4,4'-dicarboxy-2,2'-bipyridyl and 8-oxyquinolate ligands, respectively. Spectroscopic, electrochemical, and theoretical analyses are indicative of exten ...

2012

Enhancing the efficiency of a dye sensitized solar cell due to the energy transfer between CdSe quantum dots and a designed squaraine dye

Michael Graetzel, Mohammad Khaja Nazeeruddin, Guido Viscardi, Lioz Etgar

The power conversion efficiency of a dye-sensitized solar cell with tailored squaraine dye enhanced by 47%, due to Forster resonance energy transfer from CdSe quantum dots to the squaraine dye. The incident photons to collection efficiency of electrons ind ...

2012

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