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Hubert Girault

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Publications associées (430)

Water photo-oxidation on self-assembled organic/Co3O4 metal junctions in biphasic systems

Hubert Girault, Astrid Johana Olaya Avendano, Julieta Soledad Riva

A microwater vertical bar butyronitrile (W vertical bar BCN) interface was used to study the effect of the interfacial chemical polarization on the efficiency of the visible-light induced water oxidation reaction (WOR) by the electron acceptor/ photosensit ...

PERGAMON-ELSEVIER SCIENCE LTD2022

Rapid Noninvasive Skin Monitoring by Surface Mass Recording and Data Learning

Hubert Girault, Horst Pick, Natalia Gasilova, Andreas Stephan Lesch, Tzu-En Lin, Yingdi Zhu, Milica Jovic

Skin problems are often overlooked due to a lack of robust and patient-friendly monitoring tools. Herein, we report a rapid, noninvasive, and high-throughput analytical chemical methodology, aiming at real-time monitoring of skin conditions and early detec ...

2021

Soft-probe-scanning electrochemical microscopy reveals electrochemical surface reactivity of E. coli biofilms

Hubert Girault, Horst Pick, Emad Oveisi, Andreas Stephan Lesch, Sorour Darvishi

Investigating and understanding dynamic biofilm growth mechanisms is challenging, often because state-of-the-art optical characterization tools provide limited information. Micrometric electrochemical imaging of Escherichia coli biofilms using Soft-Probe-S ...

2021

Voltammetry in Two-Electrode Mode for Rapid Electrochemical Screening Using a Fully Printed and Flexible Multiplexer Sensor

Hubert Girault, Bhawna Nagar

A multiplexed electrochemical platform has been designed for electrochemical screening applications, such as bacteria detection. It includes 16x16 electrochemical cell array in a two-electrode mode fabricated by a combination of screen printing, inkjet pri ...

WILEY-V C H VERLAG GMBH2021

Visible-Light-Driven Water Oxidation on Self-Assembled Metal-Free Organic@Carbon Junctions at Neutral pH

Hubert Girault, Astrid Johana Olaya Avendano, Julieta Soledad Riva, Dominika Baster, Wanderson Oliveira Da Silva

Sustainable water oxidation requires low-cost, stable, and efficient redox couples, photosensitizers, and catalysts. Here, we introduce the in situ self-assembly of metal-atom-free organic-based semiconductive structures on the surface of carbon supports. ...

AMER CHEMICAL SOC2021

Prussian Blue Analogue-Sodium-Vanadium Hexacyanoferrate as a Cathode Material for Na-Ion Batteries

Hubert Girault, Emad Oveisi, Dominika Baster

Sodium-ion (Na-ion) batteries have been attracting great interest because of a wide range of potential applications and sodium abundance. Yet, the performance of Na-ion electrode materials needs improvement to be able to compete with lithium-ion electrode ...

AMER CHEMICAL SOC2021

Photonic Flash Synthesis of Mo2C/Graphene Electrocatalyst for the Hydrogen Evolution Reaction

Hubert Girault, Danick Reynard, Bhawna Nagar

Nowadays, molybdenum carbides (Mo2C) represent alternative electrocatalysts to noble metal for the hydrogen evolution reaction (HER). Here, a fast and simple process is proposed for the fabrication of Mo2C-based electrocatalysts on a carbon cloth substrate ...

AMER CHEMICAL SOC2021

Catalytic layer - membrane electrode assembly methods for optimum formation of triple phase boundaries and fuel cell performances

Hubert Girault, Victor Costa Bassetto, Solène Cindy Gentil, Wanderson Oliveira Da Silva

Proton Exchange Membrane Fuel Cell (PEMFC), designed mainly for mobility applications, converts chemical energy to electrical energy. The formation of electrodes for PEMFC is a delicate balancing of transport media. Conductivity of gas, electrons, and prot ...

Royal Society of Chemistry2021

Hydrogen production on demand by redox-mediated electrocatalysis: A kinetic study

Hubert Girault, Sunny Isaïe Maye, Danick Reynard

Producing hydrogen from water using a redox mediator on solid electrocatalyst particles in a reactor offers several advantages over classical electrolysis in terms of safety, membrane degradation, purity and flexibility. Herein, vanadium-mediated hydrogen ...

ELSEVIER SCIENCE SA2021

Combined hydrogen production and electricity storage using a vanadium-manganese redox dual-flow battery

Hubert Girault, Danick Reynard

A redox dual-flow battery is distinct from a traditional redox flow battery (RFB) in that the former includes a secondary energy platform, in which the pre-charged electrolytes can be discharged in external catalytic reactors through decoupled redox-mediat ...

ELSEVIER2021

The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface

Hubert Girault

H2O2 is a versatile chemical and can be generated by the oxygen reduction reaction (ORR) in proton donor solution in molecular solvents or room temperature ionic liquids (IL). We investigated this reaction at interfaces formed by eleven hydrophobic ILs and ...

2021

Ionosomes: Observation of Ionic Bilayer Water Clusters

Hubert Girault, Sunny Isaïe Maye, Pekka Eero Peljo, Evgeny Smirnov

Emulsification of immiscible two-phase fluids, i.e., one condensed phase dispersed homogeneously as tiny droplets in an outer continuous medium, plays a key role in medicine, food, chemical separations, cosmetics, fabrication of micro- and nanoparticles an ...

AMER CHEMICAL SOC2021

Experimental correlations and integration of gas boosters in a hydrogen refueling station

Hubert Girault, Heron Vrubel, Johnny Arlettaz, Yorick Ligen

2020

A Review: Electrochemical Biosensors for Oral Cancer

Hubert Girault, Tzu-En Lin, Ligang Wang, Sorour Darvishi

Oral cancer poses a serious threat worldwide owing to its soaring case-fatality rate and its metastatic characteristics of spreading to the other parts of the body. Despite the recent breakthroughs in biomedical sciences, the detection of oral cancer at an ...

2020

How to polarise an interface with ions: the discrete Helmholtz model

Hubert Girault, Astrid Johana Olaya Avendano, Grégoire Clément Gschwend

The distribution of electrolytes in an electric field usually relies on theories based on the Poisson-Boltzmann formalism. These models predict that, in the case of a metallic electrode, ionic charges screen the electrode potential, leading to concentratio ...

2020

Aqueous organic and redox-mediated redox flow batteries : A Review

Hubert Girault, Danick Reynard, Solène Cindy Gentil

Redox flow batteries (RFBs) are among the most investigated technologies for large scale energy storage applications. Since the first commercialization of all-vanadium RFB (in the early 90’s), the technology has evolved towards the development of new syste ...

2020

Oxygen Plasma/Bismuth Modified Inkjet Printed Graphene Electrode for the Sensitive Simultaneous Detection of Lead and Cadmium

Hubert Girault, Andreas Stephan Lesch, Victor Costa Bassetto, Milica Jovic, Prachi Gupta, Léopoldine Guenang Sonfack

In this work, a simple procedure for the preparation of an inkjet printed disposable graphene electrode is reported. Commercial graphene ink was printed on a kapton substrate and the resulting electrode was 30 min treated by oxygen plasma, then modified by ...

2020

Inkjet-Printed Carbon Nanotube Electrodes Modified with Dimer-captosuccinic Acid-Capped Fe3O4 Nanoparticles on Reduced Graphene Oxide Nanosheets for Single-Drop Determination of Trifluoperazine

Hubert Girault, Andreas Stephan Lesch, Milica Jovic

Here we report the design of a disposable single-drop voltammetric sensor for the quantitative determination of antipsy-chotic drug trifluoperazine (TFP). The sensor was build using inkjet-printed carbon nanotube (CNT) electrodes which were modified with d ...

2020

Flash light synthesis of noble metal nanoparticles for electrochemical applications: silver, gold, and their alloys

Hubert Girault, Carlos Manuel De Melo Pereira, Victor Costa Bassetto, Wanderson Oliveira Da Silva

The synthesis of noble metal nanoparticles (i.e., silver and gold) for electrochemical applications has been widely studied using mainly wet synthesis chemical methods or electrochemical deposition methods. In this work, we propose a single-step flash phot ...

SPRINGER2020

Oxidative Print Light Synthesis Thin Film Deposition of Prussian Blue

Hubert Girault, Mounir Driss Mensi, Emad Oveisi, Victor Costa Bassetto, Dominika Baster, Wanderson Oliveira Da Silva

Prussian blue (PB) and Prussian blue analogues (PBAs) are commonly synthesized by conventional methods, such as chemical precipitation, thermal decomposition, and electrochemical deposition. Herein, we have successfully synthesized Prussian blue by oxidati ...

2020

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