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Hubert Girault

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Publications associées (430)

Highly Loaded Mildly Edge‐Oxidized Graphene Nanosheet Dispersions for Large‐Scale Inkjet Printing of Electrochemical Sensors

Hubert Girault, Horst Pick, Andreas Stephan Lesch, Victor Costa Bassetto, Yingdi Zhu, Milica Jovic, Bhawna Nagar

Inkjet printing of electrochemical sensors using a highly loaded mildly edge‐oxidized graphene nanosheet (EOGN) ink is presented. An ink with 30 mg/mL EOGNs is formulated in a mixture of N‐methyl pyrrolidone and propylene glycol with only 30 min of sonicat ...

2020

Vanadium‐manganese redox flow battery: Study of Mn(III) disproportionation in the presence of other metallic ions

Hubert Girault, Sunny Isaïe Maye, Pekka Eero Peljo, Danick Reynard, Solène Cindy Gentil, Vimanshu Chanda

The Mn(III)/Mn(II) redox couple with a standard potential of +1.51 V vs . SHE has drawn interest for the design of V/Mn redox flow battery (RFB). However, Mn(III) disproportionation leads to a loss of capacity, an increase of pressure drop and electrode pa ...

Wiley2020

Discrete Helmholtz charge distribution at liquid-liquid interfaces: Electrocapillarity, capacitance and non-linear spectroscopy studies

Hubert Girault, Grégoire Clément Gschwend

The structure of the polarised interface between two immiscible electrolyte solutions (ITIES) has usually been deduced from electrocapillarity and capacitance measurements. However, these two methods only offer an indirect access to the surface change dens ...

ELSEVIER SCIENCE SA2020

Energy efficient hydrogen drying and purification for fuel cell vehicles

Hubert Girault, Heron Vrubel, Yorick Ligen

High-purity standards are required for hydrogen used in fuel cell vehicles. The relative abundance of contaminants is highly influenced by the production pathway. Hydrogen obtained from water electrolysis presents three main pollutants: Nitrogen, Oxygen an ...

Elsevier2020

Structure and reactivity of the polarised liquid–liquid interface: what we know and what we do not

Hubert Girault, Astrid Johana Olaya Avendano, Grégoire Clément Gschwend, Pekka Eero Peljo

Charge transfer phenomena at the interface between two immiscible electrolyte solutions (ITIES) are electrochemical reactions taking place in soft media. Owing to their liquid nature, the ITIES shows a large panel of electrochemical reactions including ele ...

2020

Discrete Helmholtz model: a single layer of correlated counter-ions. Metal oxides and silica interfaces, ion-exchange and biological membranes

Hubert Girault, Grégoire Clément Gschwend

The mechanism by which interfaces in solution can be polarised depends on the nature of the charge carriers. In the case of a conductor, the charge carriers are electrons and the polarisation is homogeneous in the plane of the electrode. In the case of an ...

2020

Photo-recycling the Sacrificial Electron Donor: Towards Sustainable Hydrogen Evolution in a Biphasic System

Hubert Girault, Mohamad Hojeij, Peiyu Ge

H-2 may be evolved biphasically using a polarised liquid|liquid interface, acting as a "proton pump", in combination with organic soluble metallocenes as electron donors. Sustainable H-2 production requires methodologies to recycle the oxidised donor. Here ...

WILEY-V C H VERLAG GMBH2020

Assembling Ni-Fe Layered Double Hydroxide 2D Thin Films for Oxygen Evolution Electrodes

Hubert Girault, Andreas Stephan Lesch, Victor Costa Bassetto, Massimo Rosa

Continuous hydrothermal flow synthesis (CHFS) of Ni-Fe layered double hydroxide (LDH) leads to waterborne dispersions of 2D nanoplatelets in the range of 10-50 nm in lateral size. Conversion of the as-synthesized LDH nanoplatelet dispersion into inkjet pri ...

AMER CHEMICAL SOC2020

Skin cell analysis

Hubert Girault, Horst Pick, Andreas Stephan Lesch, Tzu-En Lin, Yingdi Zhu, Milica Jovic

The present invention describes an adhesive tape stripping transfer method for quick and non-invasive diagnosis of skin diseases by MALDI-TOF mass spectrometry analysis. Cells from the epidermis layer of a suspicious skin area of a patient are collected us ...

2020

Montmorillonite clay-modified disposable ink-jet-printed graphene electrode as a sensitive voltammetric sensor for the determination of cadmium(II) and lead(II)

Hubert Girault, Andreas Stephan Lesch, Victor Costa Bassetto, Milica Jovic, Léopoldine Guenang Sonfack

This work describes a new sensitive sensor for the simultaneous electrochemical determination by square wave anodic stripping voltammetry of Cd2+ and Pb2+ ions in aqueous solution, based on a disposable ink-jet-printed graphene electrode (IPGE) modifed by ...

2020

Communication-Scanning Electrochemical Microscopy Analysis of Interleukin-6 in Oral Cancer

Hubert Girault, Ligang Wang, Sorour Darvishi

Scanning electrochemical microscopy (SECM) offers a highly sensitive and convenient approach for electrochemical mapping of interleukin-6 (IL-6), an oral cancer protein biomarker. In this study, we utilized the SECM to map the distribution of IL-6 for imag ...

ELECTROCHEMICAL SOC INC2020

Mechanistic study of the photo‐generation of hydrogen by decamethylruthenocene

Hubert Girault, Laurent Alexis Clément Vannay, Manuel Alejandro Méndez Agudelo, Heron Vrubel, Sunny Isaïe Maye, Micheal Diarmaid Scanlon, Pekka Eero Peljo, Lucie Josette Renée Rivier

Hydrogen evolution by decamethylruthenocene (Cp*2RuII) was studied in detail highlighting that metallocenes are capable of photo‐reducing hydrogen without the need of an additional sensitizer. Electrochemical, gas chromatographic and spectroscopic (UV/vis, ...

2019

Non-Precious Electrodes for Practical Alkaline Water Electrolysis

Hubert Girault, Alberto Battistel, Alejandro Nicolás Colli

Water electrolysis is a promising approach to hydrogen production from renewable energy sources. Alkaline water electrolyzers allow using non-noble and low-cost materials. An analysis of common assumptions and experimental conditions (low concentrations, l ...

2019

Standard ion transfer potential at the water|butyronitrile interface

Hubert Girault, Astrid Johana Olaya Avendano, Victor Costa Bassetto, Julieta Soledad Riva

Butyronitrile is an organic solvent stable enough to be used in photochemical reactions at liquid/liquid interfaces. However, it provides a rather short polarisation window making the analysis of ion transfer across the water|butyronitrile interface challe ...

2019

Two dimensional diffusion-controlled triplet–triplet annihilation kinetics

Pierre-François Marie Brevet, Hubert Girault, Astrid Johana Olaya Avendano, Grégoire Clément Gschwend, Morgan Kazmierczak

Diffusion controlled chemical reactions are usually observed in three dimensionalmedia. In contrast, planar bimolecular reactions taking place between reagents adsorbed at a soft interface are two-dimensional and therefore cannot be studied within the same ...

2019

Solid electrochemical energy storage for aqueous redox flow batteries: The case of copper hexacyanoferrate

Hubert Girault, Grégoire Clément Gschwend, Pekka Eero Peljo, Danick Reynard, Evgeny Smirnov, Christopher Raymond Dennison, Elena Zanzola, Solène Cindy Gentil

All redox flow batteries suffer from low energy storage density in comparison with conventional Li-ion batteries. However, this issue can be mitigated by utilization of solid energy storage materials to enhance the energy storage capacity. In this paper we ...

2019

On-Site Purification of Copper-Contaminated Vanadium Electrolytes by using a Vanadium Redox Flow Battery

Hubert Girault, Heron Vrubel, Danick Reynard, Christopher Raymond Dennison, Alberto Battistel

Corrosion of carbon-based electrodes and bipolar plates is a major hurdle and can be a cause of failure in commercial vanadium redox flow batteries (VRFBs). Carbon corrosion was found to occur in a commercial VRFB (10 kW/40 kWh), whereby cracks through bip ...

WILEY-V C H VERLAG GMBH2019

1D Amorphous Tungsten-Based Ternary Refractory Metal Sulfides for Catalytic Hydrogen Evolution at Soft Interfaces

Hubert Girault, Imren Hatay

Transition metals incorporated into molybdenum sulfide and tungsten sulfide matrixes are promising candidates for hydrogen evolution due to the unique chemical and physical properties. Here, we first describe a general strategy for the synthesis of rod-lik ...

WILEY-V C H VERLAG GMBH2019

Catalytic Hydrogen Evolution by Molybdenum-Based Ternary Metal Sulfide Nanoparticles

Hubert Girault

The search for highly active earth-abundant elements and nonexpensive catalysts for hydrogen evolution reaction is a vital and demanding task to minimize energy consumption. Transition metals incorporated into molybdenum sulfides are promising candidates f ...

AMER CHEMICAL SOC2019

Local Study on Hydrogen and Hydrogen Gas Bubble Formation on a Platinum Electrode

Hubert Girault, Andreas Stephan Lesch, Christopher Raymond Dennison, Alberto Battistel

This work investigates the effect of current density on the hydrogen gas bubble formation during electrolysis on a platinum electrode. Local detection of bubble evolution was performed electrochemically by using a hydrogen-collecting microelectrode placed ...

AMER CHEMICAL SOC2019

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