Publications related to Organic Spacers in 2D Perovskites: General Trends and Structure-Property Relationships from Computational Studies

Related publications (17)

High-Performance Perovskite Solar Cells with Zwitterion-Capped-ZnO Quantum Dots as Electron Transport Layer and NH4X (X = F, Cl, Br) Assisted Interfacial Engineering

Michael Graetzel, Shaik Mohammed Zakeeruddin, Mounir Driss Mensi, Thomas Paul Baumeler, Essa Awadh R Alharbi, Rashmi Runjhun, Felix Thomas Eickemeyer, Viktor Skorjanc, Anurag Krishna, Georgios Kakavelakis

The systematic advances in the power conversion efficiency (PCE) and stability of perovskite solar cells (PSCs) have been driven by the developments of perovskite materials, electron transport layer (ETL) materials, and interfacial passivation between the ...

Wiley2024

3D Conjugated Hole Transporting Materials for Efficient and Stable Perovskite Solar Cells and Modules

Keith Gregory Brooks, Paul Joseph Dyson, Zhaofu Fei, Tom Theodorus Antonius Lummen, Bin Ding, Yong Ding

The orthogonal structure of the widely used hole transporting material (HTM) 2,2 ',7,7 '-tetrakis(N, N-di-p-methoxyphenylamino)-9,9 '-spirobifluorene (Spiro-OMeTAD) imparts isotropic conductivity and excellent film-forming capability. However, inherently w ...

Wiley-V C H Verlag Gmbh2024

Buried Interface Engineering Enables Efficient and 1,960‐hour Isos‐L‐2i Stable Inverted Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Xiong Li, Mathias Dankl, Felix Thomas Eickemeyer, Nikolaos Lempesis, Mingyang Wei, Virginia Carnevali, Lorenzo Agosta

High-performance perovskite solar cells (PSCs) typically require interfacial passivation, yet this is challenging for the buried interface, owing to the dissolution of passivation agents during the deposition of perovskites. Here, this limitation is overco ...

Wiley2024

Intrinsic thermal stability of inverted perovskite solar cells based on electrochemical deposited PEDOT

Jing Gao

Thermal stability of perovskite materials is an issue impairing the long-term operation of inverted per-ovskite solar cells (PSCs). Herein, the thermal attenuation mechanism of the MAPbI3 films that deposited on two different hole transport layers (HTL), p ...

ELSEVIER2023

High-Work-Function 2D Perovskites as Passivation Agents in Perovskite Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Ulf Anders Hagfeldt, Antoine Philippe Van Muyden, Farzaneh Fadaei Tirani, Erfan Shirzadi, Hiroyuki Kanda, Brian Irving Carlsen, Fatemeh Ansari, Felix Thomas Eickemeyer, Olivier Ouellette, Hiroaki Jinno, Shun Tian

Various approaches have been employed to passivate the defects in perovskite films used in perovskite solar cells (PSCs). However, the passivation mechanism is often unclear at a molecular level, and the reason for enhanced PSC performance often remains el ...

Amer Chemical Soc2023

Ab initio study of water dissociation on a charged Pd(111) surface

Guoyuan Liu

The interactions between molecules and electrode surfaces play a key role in electrochemical processes and are a subject of extensive research, both experimental and theoretical. In this paper, we address the water dissociation reaction on a Pd(111) electr ...

2023

In-situ peptization of WO3 in alkaline SnO2 colloid for stable perovskite solar cells with record fill-factor approaching the shockley-queisser limit

Mohammad Khaja Nazeeruddin

SnO2-based electron transport layers (ETLs) offer outstanding band alignment, excellent chemical and UV stability, high transmittance, high conductivity, and processability at low temperatures. However, unfortunately, the state-of-the-art SnO2 colloid prec ...

Elsevier2022

Experimental and theoretical study of organic sensitizers for solid-state dye-sensitized solar cells (s-DSSCs)

Nikolaos Vlachopoulos

The effect of a series of triarylamine based D-pi-A organic dyes, namely RK1, BA504, BA741 and the simple L1 reference dye on solid-state dye sensitized solar cells (s-DSSCs) performances was studied. The solid hole transporting material (HTM) was obtained ...

ELSEVIER SCIENCE SA2022

Superhalogen Passivation for Efficient and Stable Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Hobeom Kim

Metal-halide perovskites are optoelectronic materials applied to solar cells as a light absorber due to their excellent optoelectronic properties. The power conversion efficiency of perovskite solar cells (PSCs) reaches 25.7% certified, which stands in com ...

WILEY-V C H VERLAG GMBH2022

Interfacial Passivation Engineering of Perovskite Solar Cells with Fill Factor over 82% and Outstanding Operational Stability on n-i-p Architecture

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Bowen Yang, Yeonju Kim, Jiajia Suo

Tremendous efforts have been dedicated toward minimizing the open-circuit voltage deficits on perovskite solar cells (PSCs), and the fill factors are still relatively low. This hinders their further application in large scalable modules. Herein, we employ ...

AMER CHEMICAL SOC2021

Hydrophobic Organic Ammonium Halide Modification toward Highly Efficient and Stable CsPbI(2.25)Br(0.75 )Solar Cell

Ulf Anders Hagfeldt, Zaiwei Wang

Inorganic cesium lead halide perovskite solar cells are promising candidates for next-generation photovoltaic applications. However, their phase instability and relatively low efficiency hinder their commercialization. Herein, hydrophobic organic ammonium ...

WILEY-V C H VERLAG GMBH2021

Tuning structural isomers of phenylenediammonium to afford efficient and stable perovskite solar cells and modules

Keith Gregory Brooks, Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Hiroyuki Kanda, Yen-Cheng Liu, Bin Ding

Salt passivation of perovskite often results in formation of 2D perovskite layers, which impaired charge transport behaviour. Here, the authors study the energy barrier of 2D perovskite formation upon passivation by different iodide salt, and provide insig ...

Nature Portfolio2021

Interfacial versus Bulk Properties of Hole-Transporting Materials for Perovskite Solar Cells: Isomeric Triphenylamine-Based Enamines versus Spiro-OMeTAD

Ulf Anders Hagfeldt, Bowen Yang, Yeonju Kim, Jiajia Suo

Here, we report on three new triphenylamine-based enamines synthesized by condensation of an appropriate primary amine with 2,2-diphenylacetaldehyde and characterized by experimental techniques and density functional theory (DFT) computations. Experimental ...

AMER CHEMICAL SOC2021

Synthesis of High-Performance Monolayer Molybdenum Disulfide at Low Temperature

Klaus Kern

The large-area synthesis of high-quality MoS2 plays an important role in realizing industrial applications of optoelectronics, nanoelectronics, and flexible devices. However, current techniques for chemical vapor deposition (CVD)-grown MoS2 require a high ...

WILEY-V C H VERLAG GMBH2021

Fluorescence-Based and Fluorescent Label-Free Characterization of Polymer Nanoparticle Decorated T Cells

Harm-Anton Klok, Demetri Psaltis, Tanja Thomsen, Ahmed Bassam Sayed Ayoub Mohamed Emam

Cells are attractive carriers for the transport and delivery of nanoparticulate cargo. The use of cell-based carriers allows one to enhance control over the biodistribution of drug-loaded polymers and polymer nanoparticles. One key element in the developme ...

American Chemical Society2021

Ultrathin polymeric films for interfacial passivation in wide band-gap perovskite solar cells

Sandy Sanchez Alonso

Wide band-gap perovskite solar cells have the potential for a relatively high output voltage and resilience in a degradation-inducing environment. Investigating the reasons why high voltages with adequate output power have not been realized yet is an under ...

NATURE RESEARCH2020

Fully textured monolithic perovskite/silicon tandem solar cells with 25.2% power conversion efficiency

Christophe Ballif, Laura Ding, Sylvain Nicolay, Quentin Thomas Jeangros, Davide Sacchetto, Mathieu Gérard Boccard, Matthieu Despeisse, Jérémie Werner, Florent Sahli, Loris Barraud, Raphaël Monnard, Gianluca Cattaneo, Bertrand Yves Paul Paviet-Salomon, Björn Niesen, Matthias Wolfgang Bräuninger

Tandem devices combining perovskite and silicon solar cells are promising candidates to achieve power conversion efficiencies above 30% at reasonable costs. State-of-the-art monolithic two-terminal perovskite/silicon tandem devices have so far featured sil ...

2018