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Singlet fission (SF) is a promising multiexciton-generating process. Its demanding energy splitting criterion - that the S-1 energy must be at least twice that of T-1 - has limited the range of materials capable of SF. We propose heteroatom oxidation as a robust strategy to achieve sufficient S-1/T-1 splitting, and demonstrate the potential of this approach for intramolecular SF.
Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, David Lyndon Emsley, Mounir Driss Mensi, Felix Thomas Eickemeyer, Pascal Alexander Schouwink, Lukas Pfeifer, Jing Gao, Michael Allan Hope, Vladislav Slama, Virginia Carnevali, Nikolaos Lempesis, Likai Zheng, Lorenzo Agosta, Ümmügülsüm Günes, Yuxuan Zhang, Francesco Biasoni
Mohammad Khaja Nazeeruddin, Shun Tian