Carbon Dioxide Based N-Formylation of Amines Catalyzed by Fluoride and Hydroxide Anions

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We describe a polymeric ionic liquid (PIL) derived from trimethyl(p-vinylbenzyl)ammonium chloride ([VBTAm]Cl) that efficiently catalyzes the N-formylation of amines employing CO2 and PhSiH3 at room temperature with low catalyst loadings in near-quantitativ ...

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N-formylation of amines with CO2 is base-catalyzed and studies of salt catalysts reveal that the reaction is efficiently catalyzed by "free" floating anions of high basicity, as represented in the cover image. More information can be found in the Full Pape ...

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Carbon Dioxide Based N-Formylation of Amines Catalyzed by Fluoride and Hydroxide Anions

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