Publications related to Steric hindrance driven passivating cations for stable perovskite solar cells with an efficiency over 24%

Related publications (16)

Solar-driven Plastic Reforming with Co2 Conversion to Value-added Chemicals Using Bifunctional Copper Hydroxide Catalyst

During coupling with carbon dioxide reduction reactions (CO2RR), plastic reforming as an effective alternative anodic reaction to replace oxygen evolution reaction (OER), offers dual benefits of reducing energy consumption and producing valuable chemicals. ...

WILEY-V C H VERLAG GMBH2025

Identification and Mitigation of Degradation Mechanisms Induced by Heat and Light in NiOx-based Perovskite Solar Cells

Marion Solange Madeleine Dussouillez

Perovskite solar cells (PSCs) offer an attractive solution to increase the efficiency of PV panels via perovskite/silicon tandems thanks to their potential cost-effectiveness and high efficiency. In inverted PSC architecture (p-i-n), commonly used hole con ...

EPFL2024

Phase-stable indium sulfide achieves an energy conversion efficiency of 14.3% for solar-assisted carbon dioxide reduction to formate

Michael Graetzel, Jingshan Luo, Jing Gao, Jun Li

Tremendous efforts have been made in developing highly selective catalysts for electrochemical CO 2 conversion to formate. However, the rapid deactivation resulting from structural reconstruction and phase transition poses considerable challenges to the sy ...

Cell Press2024

High Scandium concentration AlScN resonators for 5G applications

Marco Liffredo

Each one of the billions of smartphones on the planet contains some acoustic filter for signal routing and processing, commonly made with Surface Acoustic Wave (SAW) or Bulk Acoustic Wave (BAW) resonators. The frequency of a SAW resonator can be easily set ...

EPFL2024

Engineering ligand reactivity enables high-temperature operation of stable perovskite solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Felix Thomas Eickemeyer, Zaiwei Wang, Mingyang Wei

Perovskite solar cells (PSCs) consisting of interfacial two- and three-dimensional heterostructures that incorporate ammonium ligand intercalation have enabled rapid progress toward the goal of uniting performance with stability. However, as the field cont ...

American Association for the Advancement of Science2023

Cyclopentadiene-Based Hole-Transport Material for Cost-Reduced Stabilized Perovskite Solar Cells with Power Conversion Efficiencies Over 23%

Michael Graetzel, Shaik Mohammed Zakeeruddin, Yuhang Liu, Felix Thomas Eickemeyer, Hongwei Zhu, Thomas Paul Baumeler

Hole transport materials (HTM) are an important component in perovskite solar cells (PSC). Despite a multitude of HTMs developed in recent years, only few of them lead to solar cells with efficiencies over 20%. Therefore, it is still a challenge to develop ...

2021

Methylamine Gas Treatment Affords Improving Semitransparency, Efficiency, and Stability of CH3NH3PbBr3-Based Perovskite Solar Cells

Michael Graetzel, Hongwei Zhu

High bandgap semitransparent solar cells based on CH3NH3PbBr3 perovskites are attractive for building integration, tandem cells, and electrochemical applications. The lack of control of the CH3NH3PbBr3 perovskite growth limit the exploitation of CH3NH3PbBr ...

WILEY-V C H VERLAG GMBH2021

Formation and Stabilization of Inorganic Halide Perovskites for Photovoltaics

Ulf Anders Hagfeldt, Zaiwei Wang

In the last decade, halide perovskites have emerged as new semiconductors that revolutionize the photovoltaic field. Among this family of materials, all-inorganic halide perovskites are becoming a research paradigm because of their outstanding photophysica ...

ELSEVIER2021

Innovative Renewable Technology Integration for Nearly Zero-Energy Buildings within the Re-COGNITION Project

Alessandro Francesco Aldo Virtuani

With the 2010/31/EU directive, all new buildings shall be nearly zero-energy buildings (nZEB) from 2020 onward, with the aim of strongly reducing the energy consumption related to the building sector. To achieve this goal, it is not sufficient to focus on ...

MDPI2021

FeO-based nanostructures and nanohybrids for photoelectrochemical water splitting

Kevin Sivula

The need to satisfy the growing global population's enormous energy demands is a major challenge for modern societies. Photoelectrochemical (PEC) water splitting (WS) is seen as a leading strategy for producing an extremely promising renewable store of ene ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Lead Halide Perovskite Quantum Dots to Enhance the Power Conversion Efficiency of Organic Solar Cells

Kevin Sivula, Jun Ho Yum, Liang Yao, Nestor Guijarro Carratala, Florian Le Formal, Yongpeng Liu, Rebekah Anne Wells, Han-Hee Cho, Barbara Alexandra Primera Darwich, Lucie Navratilova

The facile synthesis, solution-processability, and outstanding optoelectronic properties of emerging colloidal lead halide perovskite quantum dots (LHP QDs) makes them ideal candidates for scalable and inexpensive optoelectronic applications, including pho ...

Wiley-VCH Verlag GmbH2019

The Quest for Stability of Perovskite Solar Cells: Understanding Degradation, Improving Lifetimes and Towards Experimental Standards

Konrad Domanski

Perovskite solar cells (PSCs) have attracted a substantial interest owing to a very fast achievement of efficiencies >20 % within only several years of development. However, for any solar cell to become technologically viable, two additional milestones hav ...

EPFL2018

Valence Level Character in a Mixed Perovskite Material and Determination of the Valence Band Maximum from Photoelectron Spectroscopy: Variation with Photon Energy

Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Tor Jesper Jacobsson

A better understanding of the electronic structure of perovskite materials used in photovoltaic devices is essential for their development and optimization. In this investigation, synchrotron-based photoelectron spectroscopy (PES) was used to experimentall ...

American Chemical Society2017

Intrinsic and Extrinsic Stability of Formamidinium Lead Bromide Perovskite Solar Cells Yielding High Photovoltage

Shaik Mohammed Zakeeruddin, Mohammad Ibrahim Dar, Gwénolé Jean Jacopin, Fabrizio Giordano, Neha Arora, Norman Pellet, Mojtaba Abdi Jalebi

We report on both the intrinsic and the extrinsic stability of a formamidinium lead bromide [CH(NH2)(2)PbBr3 = FAPbBr(3)] perovskite solar cell that yields a high photovoltage. The fabrication of FAPbBr(3) devices, displaying an outstanding photo voltage o ...

American Chemical Society2016

Double D-pi-A Dye Linked by 2,2'-Bipyridine Dicarboxylic Acid: Influence of para- and meta-Substituted Carboxyl Anchoring Group

Michael Graetzel, Mohammad Khaja Nazeeruddin, Peng Gao, Peng Gao, Aravind Kumar Chandiran

Starting from 2,2-bipyridine dicarboxylic acid, two new (D--A)(2) sensitizers, including m-DA with the carboxyl anchoring group substituted meta to the donor-bridge moiety and p-DA with a para-substituted anchoring group, were synthesized in order to evalu ...

Wiley-Blackwell2015

Low-Temperature Atomic Layer Deposition of Crystalline and Photoactive Ultrathin Hematite Films for Solar Water Splitting

Michael Graetzel, Jingshan Luo, Matthew Thomas Mayer, Marcel Roland Schreier, Ludmilla Steier

We developed a low-temperature atomic layer deposition route to deposit phase pure and crystalline hematite (alpha-Fe2O3) films at 230 degrees C without the need for postannealing. Homogenous and conformal deposition with good aspect ratio coverage was dem ...

American Chemical Society2015