Publications related to Kinetics and energetics of metal halide perovskite conversion reactions at the nanoscale

Related publications (16)

Elimination of buried interfacial voids for efficient perovskite solar cells

Establishing optimal interfacial contact is crucial for enhancing the efficiency of perovskite solar cells (PSCs). However, formation of voids at buried interface of perovskite films often hinders this critical objective. Our investigation reveals that the ...

Elsevier2024

A crystal capping layer for formation of black-phase FAPbI3 perovskite in humid air

Michael Graetzel, Shaik Mohammed Zakeeruddin, Mingyang Wei

Black-phase formamidinium lead iodide (α-FAPbI3) perovskites are the desired phase for photovoltaic applications, but water can trigger formation of photoinactive impurity phases such as δ-FAPbI3. We show that the classic solvent system for perovskite fabr ...

2024

Advancing Graphene Imaging for Clear Identification of Lattice Defects: The Application of Revolve Sphere Levelling to Scanning Tunnelling Microscopy Images

Disha Bandyopadhyay

Application of revolve sphere levelling (RSL) as a practical and effective image processing tool for enhancing scanning tunnelling microscopy (STM) images of graphene atomic lattices is presented. Low-cost, ambient, and non-invasive STM methods overcome li ...

AMER CHEMICAL SOC2024

Understanding and Mitigating the Degradation of Perovskite Solar Cells Based on a Nickel Oxide Hole Transport Material during Damp Heat Testing

Christophe Ballif, Kevin Sivula, Jun Ho Yum, Mounir Driss Mensi, Yongpeng Liu, Christian Michael Wolff, Marion Solange Madeleine Dussouillez

The development of stable materials, processable on alarge area,is a prerequisite for perovskite industrialization. Beyond the perovskiteabsorber itself, this should also guide the development of all otherlayers in the solar cell. In this regard, the use o ...

AMER CHEMICAL SOC2023

Understanding and decoupling the role of wavelength and defects in light-induced degradation of metal-halide perovskites

Michael Graetzel, Ulf Anders Hagfeldt, Anurag Krishna

Light-induced degradation in metal halide perovskites is a major concern that can potentially hamper the commercialization of perovskite optoelectronic devices. The phenomena viz. ion migration, phase segregation, and defect intolerance are believed to be ...

Royal Soc Chemistry2023

Unveiling facet-dependent degradation and facet engineering for stable perovskite solar cells

Michael Graetzel, Felix Thomas Eickemeyer

A myriad of studies and strategies have already been devoted to improving the stability of perovskite films; however, the role of the different perovskite crystal facets in stability is still unknown. Here, we reveal the underlying mechanisms of facet-depe ...

American Association for the Advancement of Science2023

Optoelectronic or photovoltaic device with metal halide perovskite film treated by passivating agent

Michael Graetzel, Shaik Mohammed Zakeeruddin, Lukas Pfeifer, Anurag Krishna, Essa Awadh R Alharbi

This invention relates to an optoelectronic or photovoltaic device comprising a perovskite or metal halide perovskite film treated by one or more compounds of formula (I): ((R1-NH(R2)-R3)+)nW (I), wherein n is an integer selected from 1, 2, or 3; R1, R2, R ...

2023

Competition between Carrier Injection and Structural Distortions in Electron-Doped Perovskite Nickelate Thin Films

Duncan Thomas Lindsay Alexander, Bernat Mundet

The discovery of superconductivity in doped infinite-layer nickelate thin films has brought increased attention to the behavior of the doped perovskite phase. Despite this interest, the majority of existing studies pertain to hole-doped perovskite rare-ear ...

WILEY2023

Regulating crystallization dynamics and crystal orientation of methylammonium tin iodide enables high-efficiency lead-free perovskite solar cells

Long Ji

Tin (Sn)-based perovskite solar cells (PSCs) have attracted much attention because they are more environmentally friendly than lead-based PSCs. However, the fast crystallization of Sn-based perovskite films and the easy oxidation of Sn2+ to Sn4+ hinder the ...

2022

Phase Engineering and Alkali Cation Stabilization for 1T Molybdenum Dichalcogenides Monolayers

Dou Du

The technological barriers of the dimensional engineering and interfacial instability seriously hinder the scalable production of metallic (1T) transition metal dichalcogenides (TMD) monolayers. In this article, a facile and fast electron injection strateg ...

WILEY-V C H VERLAG GMBH2022

Unlocking the potential of boronsilicate glass passivation for industrial tunnel oxide passivated contact solar cells

Reuben Yeo Jueyuan

In this work, we present a breakthrough in boronsilicate glass (BSG) passivated industrial tunnel oxide passivated contact (i-TOPCon) solar cells. We find that a high-temperature firing process significantly improves the front side BSG passivation quality; ...

2021

Wafer‐Scale Functional Metasurfaces for Mid‐Infrared Photonics and Biosensing

Hatice Altug, Aleksandrs Leitis, Aurélian Michel John-Herpin, Ming-Lun Tseng

Metasurfaces have emerged as a breakthrough platform for manipulating light at the nanoscale and enabling on-demand optical functionalities for next-generation biosensing, imaging, and light-generating photonic devices. However, translating this technology ...

Wiley2021

Understanding the Interfaces between Triple-Cation Perovskite and Electron or Hole Transporting Material

Jessica Taylor Flach, Ulf Anders Hagfeldt

The properties of efficient solar cells fabricated with triple-cation perovskite placed between a mesoporous titania layer and a spiro-OMeTAD layer are studied by using devices either prepared under water-free drybox conditions or fabricated under ambient ...

AMER CHEMICAL SOC2020

Influence of local surface defects on the minority-carrier lifetime of passivating-contact solar cells

Christophe Ballif, Mathieu Gérard Boccard, Jan Haschke, Jean Cattin

Unlocking the full potential of passivating contacts, increasingly popular in the silicon solar cell industry, requires determining the minority carrier lifetime. Minor passivation drops limit the functioning of solar cells; however, they are not detected ...

AIP American Institute of Physics2020

Interfacial and bulk properties of hole transporting materials in perovskite solar cells: spiro-MeTAD versus spiro-OMeTAD

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt

Two spiro-MeTAD compounds (1 and 2) were synthesized, characterized by experimental and quantum mechanical methods, and used as hole transporting materials (HTMs) in perovskite solar cells (PSCs). The new compounds differ from spiro-OMeTAD only by the pres ...

Royal Society of Chemistry2020

Non-equilibrium kinetics and trajectory thermodynamics of synthetic molecular pumps

Cristian Pezzato

A major goal in the design of synthetic molecular machines is the creation of pumps that can use the input of energy to transport material from a reservoir at low chemical potential to a different reservoir at higher chemical potential, thereby forming and ...

ROYAL SOC CHEMISTRY2020