Publication

One-step access to N-enoxyimides by gold-catalysed addition of N-hydroxyimides to terminal alkynes

Nicolai Cramer, Coralie Danielle Annick Duchemin
2019
Journal Articles

Abstract

N-Enoxyimides have become attractive substrates for novel catalytic transformations, yet their tedious multi-step synthesis hampers full exploitation of their synthetic potential. We report a gold(I)-catalyzed protocol to access N-enoxyimides from simple and widely available terminal alkynes and the corresponding N-hydroxyimides in a single step. The transformation proceeds with aryl-, alkenyl- and alkyl alkynes, facilitating further studies of this substrate class in C-H functionalizations and photocatalysis.

Official source

https://infoscience.epfl.ch/entities/publication/3da9935e-bbec-45e1-a946-b845a7bcd625

About this result

This page is automatically generated and may contain information that is not correct, complete, up-to-date, or relevant to your search query. The same applies to every other page on this website. Please make sure to verify the information with EPFL's official sources.

Graph Chat

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

One-step access to N-enoxyimides by gold-catalysed addition of N-hydroxyimides to terminal alkynes

Chat with Graph Search

Polycondensation as a Universal Method for Preparing High-density Single-atom Catalyst Libraries

Electron beam-based direct writing of nanostructures using a palladium β-ketoesterate complex

Bridge editing of spin-flip emitters gives insight into excited state energies and dynamics