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Michael Graetzel

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Related publications (1,223)

Efficient Blue-Colored Solid-State Dye-Sensitized Solar Cells: Enhanced Charge Collection by Using an in Situ Photoelectrochemically Generated Conducting Polymer Hole Conductor

Michael Graetzel, Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Thomas Wesley Holcombe, Jiahuan Zhang, Yan Hao

A high power conversion efficiency (PCE) of 5.5% was achieved by efficiently incorporating a diketopyrrolopyrrole-based dye with a conducting polymer poly(3,4-ethylenediothiophene) (PEDOT) hole-transporting material (HTM) that was formed in situ, compared ...

Wiley-V C H Verlag Gmbh2016

Porphyrin based sensitizer for dye-sensitized solar cell

Michael Graetzel, Shaik Mohammed Zakeeruddin, Chenyi Yi, Fabrizio Giordano

The present invention relates to compounds of formula (I) based on a porphyrin core and a π-conjugated linker or acceptor introduced between the porphyrin core and an anchoring group having a high absorption coefficient covering the whole UV-Visible and ne ...

2016

Dye-sensitized solar cells with inkjet-printed dyes

Michael Graetzel, Shaik Mohammed Zakeeruddin, Syed Ghufran Hashmi

The slow process in which the light absorbing dye molecules are adsorbed from solution on the nano-crystalline TiO2 photoelectrode film has been a handicap to the fast and cost-effective fabrication of dye-sensitized solar cells (DSSCs) using printing tech ...

Royal Soc Chemistry2016

A low-cost spiro[fluorene-9,9 '-xanthene]-based hole transport material for highly efficient solid-state dye-sensitized solar cells and perovskite solar cells

Michael Graetzel, Ulf Anders Hagfeldt, Dongqin Bi, Peng Liu, Ming Cheng

A low-cost spiro[fluorene-9,9'-xanthene] (SFX) based organic hole transport material (HTM) termed X60 was designed and synthesized using a two-step synthetic route. Devices with X60 as HTM showed high power conversion efficiencies (PCEs) amounting to 7.30% ...

Royal Society of Chemistry2016

Origin of unusual bandgap shift and dual emission in organic-inorganic lead halide perovskites

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Gwénolé Jean Jacopin, Mohammad Ibrahim Dar, Simone Meloni, Neha Arora, Ariadni Boziki

Emission characteristics of metal halide perovskites play a key role in the current widespread investigations into their potential uses in optoelectronics and photonics. However, a fundamental understanding of the molecular origin of the unusual blueshift ...

2016

Perovskite Photovoltaics with Outstanding Performance Produced by Chemical Conversion of Bilayer Mesostructured Lead Halide/TiO2 Films

Michael Graetzel, Shaik Mohammed Zakeeruddin, Chenyi Yi, Xiong Li, Jingshan Luo

Wiley-Blackwell2016

Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Amita Ummadisingu, Konrad Domanski, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Jiyoun Seo, Taisuke Matsui, Michael Saliba

All of the cations currently used in perovskite solar cells abide by the tolerance factor for incorporation into the lattice. We show that the small and oxidation-stable rubidium cation (Rb+) can be embedded into a "cation cascade" to create perovskite mat ...

American Association for the Advancement of Science2016

Perovskite Solar Cell Stability in Humid Air: Partially Reversible Phase Transitions in the PbI2-CH3NH3I-H2O System

Michael Graetzel, Antonio Abate

After rapid progress over the past five years, organic-inorganic perovskite solar cells (PSCs) currently exhibit photoconversion efficiencies comparable to the best commercially available photovoltaic technologies. However, instabilities in the materials a ...

Wiley-VCH Verlag Berlin2016

Highly Efficient and Stable Perovskite Solar Cells based on a Low-Cost Carbon Cloth

Michael Graetzel, Ulf Anders Hagfeldt, Ludmilla Steier, Konrad Domanski, Fabrizio Giordano, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Taisuke Matsui, Michael Saliba

Wiley-VCH Verlag Berlin2016

Cu2O Nanowire Photocathodes for Efficient and Durable Solar Water Splitting

Michael Graetzel, Marcel Roland Schreier, Ludmilla Steier, Matthew Thomas Mayer, Jingshan Luo, Minkyu Son

Due to its abundance, scalability, and nontoxicity, Cu2O has attracted extensive attention toward solar energy conversion, and it is the best performing metal oxide material. Until now, the high efficiency devices are all planar in structure, and their pho ...

American Chemical Society2016

Enhancing Efficiency of Perovskite Solar Cells via N-doped Graphene: Crystal Modification and Surface Passivation

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Amita Ummadisingu, Jingshan Luo, Juan-Pablo Correa-Baena, Antonio Abate, Jiyoun Seo, Michael Saliba, Mahboobeh Hadadian

Controlling the morphology and surface passivation in perovskite solar cells is paramount in obtaining optimal opto-electronic properties. This study incorporates N-doped graphene nanosheets in the perovskite layer, which simultaneously induces an improved ...

Wiley2016

Intrinsic Halide Segregation at Nanometer Scale Determines the High Efficiency of Mixed Cation/Mixed Halide Perovskite Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Kevin Sivula, Xavier Adrian Jeanbourquin, Paul Gratia, Yonghui Lee, Iwan Zimmermann, Giulia Grancini, Filippo de Angelis

Compositional engineering of a mixed cation/mixed halide perovskite in the form of (FAP-bI(3))(0.85)(MAPbBr(3))(0.15) is one of the most effective strategies to obtain record-efficiency perovskite solar cells. However, the perovskite self-organization upon ...

2016

Molecular Origin and Electrochemical Influence of Capacitive Surface States on Iron Oxide Photoanodes

Michael Graetzel, Yelin Hu, Artur Braun, Florent Alexandre Boudoire

The origin, the nature, and the electronic structure of surface defects causing surface states on metal oxides and their role in solar water splitting have been under scrutiny for several decades. In the present study, the surface of hematite films is trea ...

American Chemical Society2016

Tin oxide as stable protective layer for composite cuprous oxide water-splitting photocathodes

Michael Graetzel, Marcel Roland Schreier, Stanley David Tilley, Morgan Mertens Stefik, Matthew Thomas Mayer

For a sustainable future, efficient solar energy harvesting and storage is required. Solar hydrogen production from photoelectrochemical water splitting is a promising technology and, in particular, cuprous oxide photocathodes are interesting photoelectrod ...

Elsevier Science Bv2016

A vacuum flash-assisted solution process for high-efficiency large-area perovskite solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jean-David Décoppet, Ulf Anders Hagfeldt, Chenyi Yi, Xiong Li, Jingshan Luo, Dongqin Bi

Metal halide perovskite solar cells (PSCs) currently attract enormous research interest because of their high solar-to-electric power conversion efficiency (PCE) and low fabrication costs, but their practical development is hampered by difficulties in achi ...

American Association for the Advancement of Science2016

Molecular Engineering of Potent Sensitizers for Very Efficient Light Harvesting in Thin-Film Solid-State Dye-Sensitized Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Marcel Roland Schreier, Norman Pellet, Chenyi Yi, Yelin Hu, Fabrizio Giordano, Xiaoyu Zhang, Yi Xu

Dye-sensitized solar cells (DSSCs) have shown significant potential for indoor arid building integrated photovoltaic applications. Herein we present three new D-A-pi-A organic sensitizers, XY1, XY2, and XY3, that exhibit high molar extinction coefficients ...

Amer Chemical Soc2016

A New 1,3,4-Oxadiazole-Based Hole-Transport Material for Efficient CH3NH3PbBr3 Perovskite Solar Cells

Michael Graetzel, Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Antonio Abate

A new hole-transport material (HTM) based on the 1,3,4-oxadiazole moiety (H1) was prepared through a single-step synthetic pathway starting from commercially available products. Thanks to a deep HOMO level, H1 was used as HTM in CH3NH3PbBr3 perovskite sola ...

Wiley-V C H Verlag Gmbh2016

Hole transporting and light absorbing material for solid state solar cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Peng Qin, Sanghyun Paek

The present invention relates to a compound of formula (I) based on quinozilino acridine and used as hole transporting and light absorbing material in a photovoltaic device, in particular in a solid state solar cell. ...

2016

Small molecule hole transporting material for optoelectronic and photoelectrochemical devices

Michael Graetzel, Mohammad Khaja Nazeeruddin, Paul Gratia

The present invention relates to a compound of formula (I) based on carbazole substituted by diphenylamine and used as organic hole conductors or hole transporting material in a optoelectronic or photoelectrochemical device. (I), D being being selected fro ...

2016

Molecular Design Principles for Near-Infrared Absorbing and Emitting Indolizine Dyes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Aswani Yella, Aron Joel Huckaba

Desirable components for dye-sensitzed solar cell ( DSC) sensitizers and fluorescent imaging dyes include strong donating building blocks coupled with well-balanced acceptor functionalities for absorption beyond the visible range. We have evaluated the eff ...

Wiley-Blackwell2016

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