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Michael Graetzel

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Related publications (1,218)

Page 2 of 61

Cyclometalated Iridium(III) Complexes Based on Phenyl-Imidazole Ligand

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti

Phenyl-imidazole-based ligands with various substitution patterns have been used as the main ligand for heteroleptic bis-cyclometalated Iridium complexes. Two series of complexes have been prepared and their photophysical and electrochemical properties wer ...

2011

On the stability enhancement of cuprous oxide water splitting photocathodes by low temperature steam annealing

Michael Graetzel, Morgan Mertens Stefik, Stanley David Tilley, Ludmilla Steier

Given the intermittent nature of solar radiation, the large-scale use of solar energy requires an efficient energy storage solution. So far, the only practical way to store such large amounts of energy is in the form of a chemical energy carrier, i.e., a f ...

Royal Soc Chemistry2014

Hydrogen evolution from a copper(I) oxide photocathode coated with an amorphous molybdenum sulphide catalyst

Michael Graetzel, Xile Hu, Heron Vrubel, Stanley David Tilley, Carlos Gilberto Morales Guio

Concerns over climate change resulting from accumulation of anthropogenic carbon dioxide in the atmosphere and the uncertainty in the amount of recoverable fossil fuel reserves are driving forces for the development of renewable, carbon-neutral energy tech ...

Nature Publishing Group2014

Influence of the Donor Size in D-pi-A Organic Dyes for Dye-Sensitized Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Pascal Comte, Thomas Moehl, Chenyi Yi, Joël Teuscher, Thomas Wesley Holcombe

We report two new molecularly engineered push-pull dyes, i.e., YA421 and YA422, based on substituted quinoxaline as a pi-conjugating linker and bulky-indoline moiety as donor and compared with reported IQ4 dye. Benefitting from increased steric hindrance w ...

American Chemical Society2014

Back Electron-Hole Recombination in Hematite Photoanodes for Water Splitting

Michael Graetzel, Florian Le Formal, Stanley David Tilley, Maurin Cornuz

The kinetic competition between electron-hole recombination and water oxidation is a key consideration for the development of efficient photoanodes for solar driven water splitting. In this study, we employed three complementary techniques, transient absor ...

American Chemical Society2014

Temperature-Dependent Ordering Phenomena of a Polyiodide System in a Redox-Active Ionic Liquid

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jacques-Edouard Moser, Jan Cornelius Brauer

Iodine added to iodide-based ionic liquids leads to dramatic changes of their physical properties which may have implications for technological applications. Here we study the phase diagram of 1-methyl 3-propylimidazolium iodide, the temperature versus iod ...

2012

Intermediate Phase Enhances Inorganic Perovskite and Metal Oxide Interface for Efficient Photovoltaics

Michael Graetzel, Ulf Anders Hagfeldt, David Lyndon Emsley, Wolfgang Richard Tress, Dominik Józef Kubicki, Yuhang Liu, Zaiwei Wang, Aditya Mishra, Brian Irving Carlsen, Claudia Esther Avalos, Haizhou Lu, Anand Agarwalla

Interfacial modification is crucial to fully develop the potential of semiconductor devices, including the revolutionary halide perovskite-based optoelectronics, such as photovoltaics, light-emitting diodes, and photodetectors. The all-inorganic halide per ...

CELL PRESS2020

Nanocrystalline Flash Annealed Nickel Oxide for Large Area Perovskite Solar Cells

Michael Graetzel, Felix Thomas Eickemeyer, Jovana Milic

The industrialization of perovskite solar cells requires adequate materials and processes to make them economically viable and environmentally sustainable. Despite promising results in terms of power conversion efficiency and operational stability, several ...

WILEY2023

Controlling Photoactivity in Ultrathin Hematite Films for Solar Water-Splitting

Michael Graetzel, Kevin Sivula, Florian Le Formal

A promising route to increase the performance of hematite (alpha-Fe2O3) photoelectrodes for solar hydrogen production through water-splitting is to use an extremely thin layer of this visible light absorber on a nanostructured scaffold. However, the typica ...

Wiley-Blackwell2010

Photoelectrochemical CO2 Reduction at a Direct CuInGaS2/Electrolyte Junction

Michael Graetzel, Kevin Sivula, Jun Ho Yum, Nestor Guijarro Carratala, Dan Ren, Yongpeng Liu, Meng Xia, Simon Nussbaum

Photoelectrochemical (PEC) CO2 reduction has received considerable attention given the inherent sustainability and simplicity of directly converting solar energy into carbonbased chemical fuels. However, complex photocathode architectures with protecting l ...

AMER CHEMICAL SOC2023

Addition of adamantylammonium iodide to hole transport layers enables highly efficient and electroluminescent perovskite solar cells

Michael Graetzel, David Lyndon Emsley, Wolfgang Richard Tress, Dominik Józef Kubicki, Jovana Milic

The efficiency of perovskite solar cells (PSCs) is currently limited by non-radiative recombination losses. One potential loss channel consists of electrons recombining at the interface with the hole transport layer (HTL). We synthesized adamantylammonium ...

ROYAL SOC CHEMISTRY2018

Influence of Halogen Atoms on a Homologous Series of Bis-Cyclometalated Iridium(III) Complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti, Ursula Röthlisberger, Ivano Tavernelli, Basile Curchod

A series of homologous bis-cyclometalated iridium(III) complexes Ir(2,4-di-X-phenyl-pyridine)2(picolinate) (X = H, F, Cl, Br) HIrPic, FIrPic, ClIrPic, and BrIrPic has been synthesized and characterized by NMR, X-ray crystallography, UV–vis absorption and e ...

2012

Computational Characterization of the Dependence of Halide Perovskite Effective Masses on Chemical Composition and Structure

Michael Graetzel, Ursula Röthlisberger, Giulia Palermo, Simone Meloni, Amir Hesam Salavati, Negar Ashari Astani

Effective masses are calculated for a large variety of perovskites of the form ABX(3) differing in chemical composition (A= Na, Li, Cs; B = Pb, Sn; X= Cl, Br, I) and crystal structure. In addition, the effects of some defects and dopants are assessed. We s ...

2017

WO3-Fe2O3 Photoanodes for Water Splitting: A Host Scaffold, Guest Absorber Approach

Michael Graetzel, Kevin Sivula, Florian Le Formal

Solar hydrogen production via watersplitting with hematite (Fe2O3) has been limited by poor light absorption and a small hole diffusion length. These drawbacks can be overcome by using a high-surface-area host to support a thin layer of hematite-allowing p ...

2009

Graphene-Templated Achiral Hybrid Perovskite for Circularly Polarized Light Sensing

Michael Graetzel, Anurag Krishna, Georgios Kakavelakis

This study points out the importance of the templating effect in hybrid organic-inorganic perovskite semiconductors grown on graphene. By combining two achiral materials, we report the formation of a chiral composite heterostructure with electronic band sp ...

2024

New Insights into the Interface of Electrochemical Flow Cells for Carbon Dioxide Reduction to Ethylene

Michael Graetzel, Shaik Mohammed Zakeeruddin, Dan Ren, Jing Gao

The implementation of an electrochemical flow cell has enabled improved efficiency for CO2 reduction. However, in situ spectroscopic insights into the interface are still lacking. Here, we investigate a series of copper layers with different thicknesses on ...

AMER CHEMICAL SOC2021

High-performance, nano-structured LiMnPO4 synthesized via a polyol method

Michael Graetzel, Nam Hee Kwon

A novel polyol synthesis was adopted to synthesize nano-structured LiMnPO4. This route yields well-crystallized nanoparticles with platelet morphology that are only similar to 30 nm thick oriented in the b direction. The obtained material presented a good ...

Elsevier2009

Nanostructured Photosystems for the Generation of Electricity and Fuels from Sunlight

Michael Graetzel

Learning from the concepts used by green plants photosynthesis, we have developed nanostructured systems affording efficient solar light harvesting and conversion to electricity and fuels. Solar cells using dyes or semiconducting nanoparticles as light har ...

Amer Inst Physics2013

Updates on Hydrogen Value Chain: A Strategic Roadmap

Michael Graetzel, Dan Ren

A strategic roadmap for noncarbonized fuels is a global priority, and the reduction of carbon dioxide emissions is a key focus of the Paris Agreement to mitigate the effects of rising temperatures. In this context, hydrogen is a promising noncarbonized fue ...

WILEY-V C H VERLAG GMBH2023

Electrochemical Properties of Cu(II/I)-Based Redox Mediators for Dye-Sensitized Solar Cells

Michael Graetzel, Ulf Anders Hagfeldt, Shaik Mohammed Zakeeruddin, Ladislav Kavan, Yasemin Saygili, Marina Freitag

Three Cu(II/I)-phenanthroline and Cu(II/I)-bipyridine redox mediators are studied on various electrodes and in variety of electrolyte solutions using cyclic voltammetry and impedance spectroscopy on symmetrical dummy cells. Graphene-based catalysts provide ...

2017