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Related publications (22)

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Effect of different ions on dissolution rates of silica and feldspars at high pH

Karen Scrivener, Mahsa Bagheri

The dissolution kinetics of silica-containing minerals in aggregates influences strongly the process of ASR in concrete. In this paper, the effect of different ions on the dissolution rates of SiO2 (amorphous and quartz) and feldspars at high pH values was ...

Pergamon-Elsevier Science Ltd2022

Aggregate dissolution in different pore solutions

Mahsa Bagheri

The occurrence of cracking due to alkali silica reaction (ASR) affects the service life of concrete structures. The dissolution of silica-containing minerals within aggregates causes the formation of ASR products, which fill macroscopic cracks and cause th ...

EPFL2021

Role of Iron Sulfide Phases in the Stability of Noncrystalline Tetravalent Uranium in Sediments

Rizlan Bernier-Latmani, Luca Loreggian

Uranium (U) in situ bioremediation has been investigated as a cost-effective strategy to tackle U contamination in the subsurface. While uraninite was believed to be the only product of bioreduction, numerous studies have revealed that noncrystalline U(IV) ...

AMER CHEMICAL SOC2020

Active sulfur cycling in the terrestrial deep subsurface

Rizlan Bernier-Latmani, Manon Frutschi, Emma Bell

The deep terrestrial subsurface remains an environment where there is limited understanding of the extant microbial metabolisms. At Olkiluoto, Finland, a deep geological repository is under construction for the final storage of spent nuclear fuel. It is th ...

2020

An alternative model for the formation of hydrous Mg/Ni layer silicates ("deweylite"/"garnierite") in faulted peridotites of New Caledonia: II. Petrography and chemistry of white and green clay infillings

Gabrielle Dublet

This study, which complements a first mineralogical work, presents detailed petrographic and chemical data on the sequences of clay infillings commonly found in serpentine veins of reactivated faults from the New Caledonian peridotite formation. Chemical t ...

E SCHWEIZERBARTSCHE VERLAGSBUCHHANDLUNG2019

Hydro-mechanical response of Opalinus Clay shale: dependency on composition and burial depth

Eleonora Crisci

Shales are sedimentary formation currently studied for their involvement in many geo-energy related applications, such as radioactive waste disposal, CO2 sequestration, oil and gas extraction. In Switzerland the Opalinus Clay shale has been selected has ho ...

EPFL2019

Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide

Rosario Scopelliti, Marinella Mazzanti, Marta Falcone, Rory Patrick Kelly

Herein, we report the synthesis and characterisation of the first terminal uranium(V) sulfide and a related UV trithiocarbonate complex supported by sterically demanding tris(tert-butoxy)siloxide ligands. The reaction of the potassium-bound UV imido comple ...

2017

Selecting the best AOP for isoxazolyl penicillins degradation as a function of water characteristics: Effects of pH, chemical nature of additives and pollutant concentration

César Pulgarin

To provide new insights toward the selection of the most suitable AOP for isoxazolyl penicillins elimination, the degradation of dicloxacillin, a isoxazolyl penicillin model, was studied using different advanced oxidation processes (AOPs): ultrasound (US), ...

Elsevier2017

Study of a photocatalytic process for removal of antibiotics from wastewater in a falling film photoreactor: Scavenger study and process intensification feasibility

Sami Rtimi

This study focused on the removal of antibiotic by coupling of heterogeneous photocatalysis with ozonation and hydrogen peroxide. The main objective was to intensify the efficiency of photocatalytic activity for better and faster antibiotic elimination/min ...

Elsevier2017

New method for measuring compressibility and poroelasticity coefficients in porous and permeable rocks

Lucas Xan Pimienta

Over the last decades, a large understanding has been gained on the elastic properties of rocks. Rocks are, however, porous materials, which properties depend on both response of the bulk material and of the pores. Because in that case both the applied ext ...

Amer Geophysical Union2017

Synthesis and reactivity of a terminal uranium(IV) sulfide supported by siloxide ligands

Rosario Scopelliti, Marinella Mazzanti, Julie Renée Michelle Andrez

The reactions of the tetrasiloxide U(III) complexes [U(OSi(OtBu)3)4K] and [U(OSi(OtBu)3)4][K18c6] with 0.5 equiv. of triphenylphosphine sulfide led to reductive S-transfer reactions, affording the U(IV) sulfide complexes [SU(OSi(OtBu)3)4K2]2, 1, and [{SU(O ...

2016

Environmental Mineralogy: New challenges, new materials

Rizlan Bernier-Latmani

The close links between mineralogy and materials science are leading to major developments in how society deals more effectively with energy and environmental challenges. The fast expanding field of "environmental mineralogy" helps mitigate major environme ...

Mineralogical Soc Amer2015

Control of groundwater pH during bioremediation: Improvement and validation of a geochemical model to assess the buffering potential of ground silicate minerals

David Andrew Barry, Christof Holliger, Alessandro Brovelli, Elsa Marina Lacroix

Accurate control of groundwater pH is of critical importance for in situ biological treatment of chlorinated solvents. The use of ground silicate minerals mixed with groundwater is an appealing buffering strategy as silicate minerals may act as long-term s ...

Elsevier2014

Shock Events in the Solar System: The Message from Minerals in Terrestrial Planets and Asteroids

Philippe Gillet

Impacts are central to the origin and evolution of planets of the Solar System. The shapes of craters, which can reach up to 1,000 km in diameter on the Moon, provide critical information on the large-scale dynamics of the impact and related shock. Mineral ...

Annual Reviews2013

Speciation of aqueous tellurium(IV) in hydrothermal solutions and vapors, and the role of oxidized tellurium species in Te transport and gold deposition

Lothar Helm, Pascal Grundler

Despite the close association between tellurium (Te) and gold (Au) in many epithermal, orogenic, and intrusion-related hydrothermal ore deposits, the hydrothermal chemistry of Te remains poorly understood. We studied the protonation/ deprotonation and stru ...

Elsevier2013

Evaluation of silicate minerals for pH control during bioremediation: Application to chlorinated solvents

David Andrew Barry, Christof Holliger, Alessandro Brovelli, Elsa Marina Lacroix

Accurate control of groundwater pH is of critical importance for in situ biological treatment of chlorinated solvents. This study evaluated a novel approach for buffering subsurface pH that relies on the use of silicate minerals as a long-term source of al ...

2012

An innovative ultrasound, Fe2+ and TiO2 photoassisted process for bisphenol a mineralization

César Pulgarin, Jessica Ivana Nieto Juarez

This paper explores the degradation of a model pollutant, bisphenol A, by an advanced oxidation process that combines sonolysis, Fe2+, and TiO2 in a photoassisted process. Experiments were done under saturated oxygen conditions. The effect of different Fe2 ...

2010

Synthesis and characterization of ether-derivatized aminophosphines and their application in C-C coupling reactions

Paul Joseph Dyson, Rosario Scopelliti, Zhaofu Fei

Four new bis(phosphino)amine ligands (Ph2P)2N-C6H3-R, where R = 3,5-OMe (1), 2,5-OMe (2), 2,4-OMe (3) or 3,4-OMe (4), were prepd. via aminolysis of the corresponding dimethoxyanilines with 2 equiv. of diphenylphosphine chloride in the presence of tri-Et am ...

Elsevier2010

Mineralization enhancement of a recalcitrant pharmaceutical pollutant in water by advanced oxidation hybrid processes

César Pulgarin

Degradation of the biorecalcitrant pharmaceutical micropollutant ibuprofen (IBP) was carried out by means of several advanced oxidation hybrid configurations. TiO2 photocatalysis, photo-Fenton and sonolysis - all of them under solar simulated illumination ...

Elsevier2009

A DEMS study of methanol and formic acid oxidation on boron-doped diamond electrode

Christos Comninellis, György Foti, Agnieszka Kapalka

The electrochemical oxidation of methanol and formic acid in 1 M HClO4 is studied on boron-doped diamond electrode using differential electrochemical mass spectrometry (DEMS). DEMS is used to identify products and intermediates of the reaction monitored on ...

2009