Publications associées à Interplay of Kinetic and Thermodynamic Reaction Control Explains Incorporation of Dimethylammonium Iodide into CsPbI3

Publications associées (11)

Dipolar Carbazole Ammonium for Broadened Electric Field Distribution in High-Performance Perovskite Solar Cells

Felix Thomas Eickemeyer, Likai Zheng, Jaeki Jeong

Perovskite solar cells (PSCs) with ammonium passivation exhibit superior device performance and stability. Beyond typical chemical passivation, ammonium salts control the electronic structure of perovskite surfaces, yet the molecular structure-property rel ...

2025

De-doping engineering for efficient and heat-stable perovskite solar cells

Michael Graetzel

In conventional n-i-p perovskite solar cells, unsolved issues persist, particularly concerning notorious performance degradation under prolonged heat exposure at 85°C. By reducing the concentration of 4-tert-butylpyridine (tBP) and lithium bis(trifluoromet ...

2025

Effect of imidazole-based additives on the voltage of dye sensitized solar cells with Cu(II/I) redox mediators

Michael Graetzel, Ladislav Kavan

Acetonitrile solutions of Cu(tmby)22+ exhibit aging-dependent changes of UV–Vis spectra, which were attributed to partial reduction to Cu(tmby)2+. This effect is boosted by the addition of imidazole bases, i.e., N-methyl-benzimidazole (NMB) or 5‑chloro-1-e ...

2025

Dataset to accompany publication "Quantum-mechanical effects in photoluminescence from thin crystalline gold films"

Giulia Tagliabue, Alan Richard Bowman, Fateme Kiani Shahvandi, Theodoros Tsoulos

This dataset accompanies the publication "Quantum-mechanical effects in photoluminescence from thin crystalline gold films" published in Light: Science & Applications (https://doi.org/10.1038/s41377-024-01408-2). The data can be used to reproduce plots 1-4 ...

Zenodo2024

Sequential Carrier Transfer Can Accelerate Triplet Energy Transfer from Functionalized CdSe Nanocrystals

Philippe Benjamin Green

Nanocrystal (NC)-sensitized triplet-fusion upconversion is a rising strategy to convert long-wavelength, incoherent light into higher-energy output photons. Here, we chart the photophysics of tailor-functionalized CdSe NCs to understand energy transfer to ...

2023

High Performance Semiconducting Nanosheets via a Scalable Powder-Based Electrochemical Exfoliation Technique

Kevin Sivula, Aleksandra Radenovic, Victor Carle Adrien Boureau, Miao Zhang, Tzu-Heng Chen

The liquid-phase exfoliation of semiconducting transition metal dichalcogenide (TMD) powders into 2D nanosheets represents a promising route toward the scalable production of ultrathin high-performance optoelectronic devices. However, the harsh conditions ...

2022

Thermodynamics and dielectric response of BaTiO3 by data-driven modeling

Nicola Marzari, Michele Ceriotti, Giovanni Pizzi, Michele Kotiuga, Max David Veit, Lorenzo Gigli

Modeling ferroelectric materials from first principles is one of the successes of density-functional theory and the driver of much development effort, requiring an accurate description of the electronic processes and the thermodynamic equilibrium that driv ...

NATURE PORTFOLIO2022

A Machine Learning Model of Chemical Shifts for Chemically and Structurally Diverse Molecular Solids

Artur Andrzej Stefaniuk, David Lyndon Emsley, Michele Ceriotti, Manuel Cordova, Albert Hofstetter, Federico Maria Paruzzo

Nuclear magnetic resonance (NMR) chemical shifts are a direct probe of local atomic environments and can be used to determine the structure of solid materials. However, the substantial computational cost required to predict accurate chemical shifts is a ke ...

2022

Method of modifying the structure of perovskite films

Michael Graetzel, Shaik Mohammed Zakeeruddin, Hong Zhang

A method of modifying the structure of a perovskite film prepared on a substrate, wherein an organic or inorganic salt crown ether complex is applied on a free surface of the so-prepared perovskite film. A perovskite solar cell, wherein a perovskite layer ...

2022

Nanosegregation in arene-perfluoroarene pi-systems for hybrid layered Dion-Jacobson perovskites

Michael Graetzel, Shaik Mohammed Zakeeruddin, Pascal Alexander Schouwink, Lukas Pfeifer, Jovana Milic, Laura Piveteau, Masaud Hassan S Almalki, Algirdas Ducinskas

Layered hybrid perovskites are based on organic spacers separating hybrid perovskite slabs. We employ arene and perfluoroarene moieties based on 1,4-phenylenedimethylammonium (PDMA) and its perfluorinated analogue (F-PDMA) in the assembly of hybrid layered ...

2022

Spatial Modulation of Vibrational and Luminescence Properties of Monolayer MoS & x2082; Using a GaAs Nanowire Array

Anna Fontcuberta i Morral, Wonjong Kim, Jean-Baptiste Leran, Mirjana Dimitrievska, Lucas Güniat, Didem Dede, Valerio Piazza, Akshay Balgarkashi

The integration of transition-metal dichalcogenides (TMDs) with non-planar substrates such as nanopillars provides a way to spatially modify the optical properties mainly through the localized strain. Similar studies to date have utilized insulating SiO2 n ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2022