Publication

Solid-state synthesis of a MOF/polymer composite for hydrodeoxygenation of vanillin

Publications associées (32)

Local excitations in amorphous solids

Amorphous solids are structurally disordered. They are very common and include glasses, colloids, and granular materials, but are far less understood than crystalline solids. Key aspects of these materials are controlled by the presence of excitations in w ...

EPFL2021

An Investigation into the Intrinsic Peroxidase-Like Activity of Fe-MOFs and Fe-MOFs/Polymer Composites

Daniel Teav Sun, Wendy Lee Queen, Vikram Vinayak Karve

The quest for developing materials that provide a perfect trade-off between factors such as enzyme-like response, stability, and low cost has been a long-standing challenge in the field of biosensing. Metal-organic frameworks (MOFs) and their composites ha ...

Wiley2021

Structure and Reactivity of N-Heterocyclic Alkynyl Hypervalent Iodine Reagents

Rosario Scopelliti, Matthew Wodrich, Jérôme Waser, Farzaneh Fadaei Tirani, Eliott Hugo Joran Le Du

Ethynylbenziodoxol(on)e (EBX) cyclic hypervalent iodine reagents have become popular reagents for the alkynylation of radicals and nucleophiles, but only offer limited possibilities for further structure and reactivity fine-tuning. Herein, the synthesis of ...

2021

Structural elucidation and antibacterial activity of new dialkylstannyl- and chlorodialkylstannyl(IV) 3,4-dihydroisoquinoline-2-(1H)-carbodithioate

Rosario Scopelliti

In extension with growing concern to develop new antimicrobial organometallic drugs, an attempt has been made to synthesize five new antimicrobial organotin(IV) carbodithioates with general formula, Me2SnClL (1), Me2SnL2 (2), Et2SnClL (3), Et2SnL2 (4), Bu2 ...

ELSEVIER2021

Propelling the hydrogen economy: from chemical storage and delivery to utilization in biomass conversion

Lu Chen

Since H2 is a non-polluting, inexhaustible, efficient, and sustainable energy carrier, it has been forecast to become one of the major carriers of energy in the future and is also essential in the production of feedstock chemicals derived from renewable ca ...

EPFL2021

Computational studies for the description of electronic and optical properties for photocatalysis in Metal Organic Frameworks

Andres Adolfo Ortega Guerrero

Metal-organic frameworks(MOFs) are promising materials for photocatalytic applications. MOFs modular and porosity structure provides a platform to assemble photo-active and catalytic-sites building block units that can offer unique photo-physics. This feat ...

EPFL2021

Hydrogen production on demand by redox-mediated electrocatalysis: A kinetic study

Hubert Girault, Sunny Isaïe Maye, Danick Reynard

Producing hydrogen from water using a redox mediator on solid electrocatalyst particles in a reactor offers several advantages over classical electrolysis in terms of safety, membrane degradation, purity and flexibility. Herein, vanadium-mediated hydrogen ...

ELSEVIER SCIENCE SA2021

A study on synergies of combined pulp and fuel production

François Maréchal, Tuong-Van Nguyen, Erina Clare Mcdonald, Julia Granacher

To limit climate change by reducing global greenhouse gas emissions, a transition away from fossil fuels is required. Biofuels represent a promising low carbon alternative for sectors that are hard to electrify, such as aviation. The integration of bio ref ...

2021

Enhancing MOF performance through the introduction of polymer guests

Mehrdad Asgari, Daniel Teav Sun, Wendy Lee Queen, Li Peng, Olga Trukhina, Ilia Kochetygov, Vikram Vinayak Karve, Shuliang Yang, Anita Justin, Jordi Espin Marti

In this contribution, recent advances in the construction of MOF-polymer composites and their corresponding applications are briefly reviewed. The appearance of such architectures is becoming prominent in recent literature, due to the fact that the union o ...

2020

Pure Spin Current and Magnon Chemical Potential in a Nonequilibrium Magnetic Insulator

Kyongmo An, Li Shi

Nonequilibrium phenomena are ubiquitous in nature and in a wide range of systems, including cold atomic gases and solid-state materials. While these phenomena are challenging to describe both theoretically and experimentally, they are essential for the fun ...

American Physical Society2020

CO2 chemical transformations using metal-organic frameworks

Serhii Shyshkanov

During the last decades, intensive efforts have been applied to tackle the enormous emissions of CO2 into atmosphere. These efforts include not only developing efficient carbon capture techniques, but also the introduction of new ways to transform the capt ...

EPFL2020

Preparation of Highly Porous Metal-Organic Framework Beads for Metal Extraction from Liquid Streams

Emad Oveisi, Daniel Teav Sun, Wendy Lee Queen, Li Peng, Olga Syzgantseva, Olga Trukhina, Ilia Kochetygov, Shuliang Yang, Anita Justin, Hassan Abedini, Guanchu Lu

Metal-organic frameworks (MOFs) offer great promise in a variety of gas- and liquid-phase separations. However, the excellent performance on the lab scale hardly translates into pilot- or industrial-scale applications due to the microcrystalline nature of ...

AMER CHEMICAL SOC2020