Publications associées à Charge disproportionation in RNiO3 perovskites (R=rare earth) from high-resolution x-ray absorption spectroscopy

Publications associées (39)

Competition between Carrier Injection and Structural Distortions in Electron-Doped Perovskite Nickelate Thin Films

Duncan Thomas Lindsay Alexander, Bernat Mundet

The discovery of superconductivity in doped infinite-layer nickelate thin films has brought increased attention to the behavior of the doped perovskite phase. Despite this interest, the majority of existing studies pertain to hole-doped perovskite rare-ear ...

WILEY2023

Surfactant-based enrichment of rare earth elements from NdFeB magnet e-waste: Optimisation of cloud formation and rare earths extraction

Christian Ludwig, Rudolf Paul Wilhelm Jozef Struis, Ajay Bhagwan Patil

Appropriate waste and resource management are essential for a sustainable circular economy with reduced environmental impact. With critical resources, e-waste may serve as indirect raw material. For example, with NdFeB permanent magnets, Neodymium (Nd) and ...

2023

Murunskite - a new class of functional material

Davor Tolj

The subject of the present work is discovery and in-depth characterization of a new class of functional materials. Tuning of the bond polarity and orbital occupation with a goal of establishing balance between localization and delocalization of electrons - ...

EPFL2023

Universal scaling of tunable Yu-Shiba-Rusinov states across the quantum phase transition

Klaus Kern, Haonan Huang

Quantum magnetic impurities give rise to a wealth of phenomena attracting tremendous research interest in recent years. On a normal metal, magnetic impurities generate the correlation-driven Kondo effect. On a superconductor, bound states emerge inside the ...

NATURE PORTFOLIO2023

Monitoring of Protein and pH Levels in Human Biofluids using FD-SOI Silicon Nanowire Arrays

Luca Capua

Medical research and technological advancements are heading towards tailored healthcare approaches that prioritize individual needs, allowing for more accurate diagnoses, more effective treatments, and better patient outcomes overall. One such approach is ...

EPFL2023

Correlated insulator collapse due to quantum avalanche via in-gap ladder states

Xi Chen, Camille Didier Georges Aron

The significant discrepancy observed between the predicted and experimental switching fields in correlated insulators under a DC electric field far-from-equilibrium necessitates a reevaluation of current microscopic understanding. Here we show that an elec ...

Nature Portfolio2023

Erbium and thulium on MgO(100)/Ag(100) as candidates for single atom qubits

Harald Brune, François Patthey, Stefano Rusponi, Marina Pivetta, Fabio Donati, Aparajita Singha, Edgar Fernandes

Lanthanide atoms on surfaces are an exceptional platform for atomic-scale magnetic information storage. However, their potential as qubits remains unexplored due to the limited number of experimental setups that can coherently drive the spins of single ada ...

AMER PHYSICAL SOC2023

Magnetism and metal-organic self-assembly of rare-earth atoms on decoupling layers

Sébastien Reynaud

This thesis presents investigations of magnetic and structural properties of two dimensional metal-organic frameworks and of single atoms, both adsorbed on decoupling layers grown on metal surfaces, with focus on rare earth elements. We first report on a ...

EPFL2022

Separation and Recycling Potential of Rare Earth Elements from Energy Systems: Feed and Economic Viability Review

Christian Ludwig, Rudolf Paul Wilhelm Jozef Struis, Ajay Bhagwan Patil

This review explores the potential of separating and recycling rare earth elements (REEs) from different energy conversion systems, such as wind turbines, electric vehicles batteries, or lighting devices. The REEs include 17 elements (with global productio ...

2022

Three-dimensional Fermi surfaces from charge order in layered CsV3Sb5

Philip Johannes Walter Moll, Matthias Carsten Putzke, Yi-Chiang Sun, Chunyu Guo, Xiangwei Huang

The cascade of electronic phases in CsV3Sb5 raises the prospect to disentangle their mutual interactions in a clean, strongly interacting kagome lattice. When the kagome planes are stacked into a crystal, its electronic dimensionality encodes how much of t ...

AMER PHYSICAL SOC2022

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Aurélien René Willauer

The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

EPFL2022

Strontium Substituted Tricalcium Phosphate Bone Cement: Short and Long-Term Time-Resolved Studies and In Vitro Properties

Marta Di Fabrizio

Due to a significant influence of strontium (Sr) on bone regeneration, Sr substituted beta-tricalcium phosphate (Sr-TCP) cement is prepared and investigated by short- and long-term time-resolved techniques. For short-term investigations, energy-dispersive ...

WILEY2022

Long Spin Lifetime in Rare-Earth Single-Atom Magnets at Surfaces

Boris Sorokin

Further miniaturisation of magnetic storage devices requires an advent of new types of magnets, since classical ferromagnetic materials show lack of remanence at nano- and subnanoscale. A single atom can represent the smallest possible bit of information. ...

EPFL2022

Metal-wire-embedded alumina insulating material using micro- and nanoscale 3D printing for surface flashover mitigation in a vacuum

Guang-Yu Sun

A micro- and nanoscale 3D printing technique is applied to fabricate a functional insulating material that mitigates surface discharge in a vacuum based on microscopic electron multipactor suppression. The proposed alumina ceramic insulator design consists ...

2022

Proximity-Induced Novel Ferromagnetism Accompanied with Resolute Metallicity in NdNiO3 Heterostructure

Joël Mesot, Zoran Ristic, Marco Caputo

Employing X-ray magnetic circular dichroism (XMCD), angle-resolved photoemission spectroscopy (ARPES), and momentum-resolved density fluctuation (MRDF) theory, the magnetic and electronic properties of ultrathin NdNiO3 (NNO) film in proximity to ferromagne ...

2021

Extraction of Rare Earth Metals: The New Thermodynamic Considerations Toward Process Hydrometallurgy

Christian Ludwig, Andrea Testino, Rudolf Paul Wilhelm Jozef Struis, Ajay Bhagwan Patil

Successful management of secondary waste resources is essential for the viable circular economy. E-waste could serve as the potential urban mining source for the alternative supply chain of critical metals such as rare earth elements (REEs). The hydrometal ...

Springer Nature Switzerland AG2021

Quench behavior of high-temperature superconductor tapes for power applications: a strategy toward resilience

Nicolo' Riva

High-Temperature Superconductors (HTS) can be superconducting in liquid nitrogen 77 K, holding immense promises for our future. They can enable disruptive technologies such as nuclear fusion, lossless power transmission, cancer treatment devices, and techn ...

EPFL2021

Crystal Structures of AlCr2 and MoSi2: Same Structure Type vs. Different Bonding Pattern

Philip Johannes Walter Moll

In a joint effort utilizing modified sample preparation, microscopy, X-ray diffraction and micro-fabrication, it became possible to prepare single crystals of the "hidden" phase AlCr2. High-resolution X-ray diffraction analysis is described in detail for t ...

2021

Core-Valence Attosecond Transient Absorption Spectroscopy of Polyatomic Molecules

Jiri Vanicek, Nikolay Golubev

Tracing ultrafast processes induced by interaction of light with matter is often very challenging. In molecular systems, the initially created electronic coherence becomes damped by the slow nuclear rearrangement on a femtosecond timescale which makes real ...

2021

Measuring the Intra-Atomic Exchange Energy in Rare-Earth Adatoms

Harald Brune, François Patthey, Stefano Rusponi, Marina Pivetta

We present the first experimental determination of the intra-atomic exchange energy between the inner 4f and the outer 6s5d shells in rare-earth elements. Inelastic electron tunneling spectroscopy on individual rare-earth atoms adsorbed on metal-supported ...

American Physical Society2020