Publication

How Strained are Carbomeric-Cycloalkanes?

Publications associées (30)

Open and Closed Radicals: Local Geometry around Unpaired Electrons Governs Magic-Angle Spinning Dynamic Nuclear Polarization Performance

Dominik Józef Kubicki, Manuel Cordova, David Lyndon Emsley, Gabriele Stevanato, Yu Rao, Georges Guévork Jean-Jacques Menzildjian, Moreno Lelli

The development of magic-angle spinning dynamic nuclear polarization (MAS DNP) has allowed atomic-level characterization of materials for which conventional solid-state NMR is impractical due to the lack of sensitivity. The rapid progress of MAS DNP has be ...

2020

Mechanics and co-evolution of allosteric materials and proteins

Riccardo Ravasio

The regulation of several processes inside and outside the cell depends on the action of a particular class of enzymes, called allosteric. In allosteric macromolecules, binding a ligand at one site affects the binding activity at a distal functional site, ...

EPFL2020

Pronounced grain boundary network evolution in nanocrystalline Cu subjected to large cyclic strains

Thomas La Grange

The grain boundary network of nanocrystalline Cu foils was modified by the application of cyclic loadings and elevated temperatures. Broadly, the changes to the boundary network were directly correlated with the applied temperature and accumulated strain, ...

2019

High-speed mechano-active multielectrode array for investigating rapid stretch effects on cardiac tissue

Samuel Rosset, Herbert Shea, Alexandre Poulin, Christian Dellenbach, Matthias Imboden, Etienne de Coulon, Stephan Rohr

Systematic investigations of the effects of mechano-electric coupling (MEC) on cellular cardiac electrophysiology lack experimental systems suitable to subject tissues to in-vivo like strain patterns while simultaneously reporting changes in electrical act ...

Nature Research2019

Tensile response of Strain-Hardening Ultra High Performance Fiber Reinforced Concretes under low loading rates and low temperatures

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Strain Hardening Ultra High Performance Fiber Reinforced Concretes (SH-UHPFRC) are cementitious materials with exceptional mechanical properties and outstanding durability making them ideal materials for rehabilitation, for the improvement of load carrying ...

EPFL2019

Silicon Corrosion in Neutral Media: The Influence of Confined Geometries and Crevice Corrosion in Simulated Physiological Solutions

Patrik Schmutz, Stefano Mischler, Emilija Ilic, Roland Hauert

Silicon (Si) based implantable components are widely used to restore functionalities in the human body. However, there have been reported instances of Si corroding after only a few years of implantation. A key parameter often overlooked when assessing Si s ...

2019

Electrical energy generated by silicone elastomers filled with nanospring- carbon- nanotubes

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Dielectric elastomer generators (DEGs) are flexible capacitors that convert mechanical into electrical energy. They rely on an external voltage source to charge the capacitor during each operation cycle. An alternative to this is an autonomous DEG which op ...

Royal Society of Chemistry2019

Corrosion Mechanisms of Diamond-like Carbon Coated Interlayers & Interfaces

Emilija Ilic

Diamond-like carbon (DLC) coatings can improve the wear resistance of articulating implants. However despite successful in-vitro testing, some DLC coated joint replacements had to be revised prematurely, mainly due to coating delamination induced by corros ...

EPFL2019

Developing Reactions of Strained Rings : Enantioselective Desymmetrization of meso-Diaminocyclopropanes and Annulation of Donor-Acceptor Aminocyclobutanes

Daniele Perrotta

Carbo- and heterocyclic structures containing nitrogen-substituted stereocenters are recurrent structural motifs in natural and bioactive compounds, therefore constituting a privileged class of synthetic targets. In this regard, substituted three- and four ...

EPFL2018

Frequency-dependent decoupling of domain-wall motion and lattice strain in bismuth ferrite

Dragan Damjanovic

Dynamics of domain walls are among the main features that control strain mechanisms in ferroic materials. Here, we demonstrate that the domain-wall-controlled piezoelectric behaviour in multiferroic BiFeO3 is distinct from that reported in classical ferroe ...

Nature Research2018