Publications associées à Deconvolution of Light-Induced Ion Migration Phenomena by Statistical Analysis of Cathodoluminescence in Lead Halide-Based Perovskites

Publications associées (15)

Strain-induced rubidium incorporation into wide-bandgap perovskites reduces photovoltage loss

Michael Graetzel, Shaik Mohammed Zakeeruddin, Mounir Driss Mensi, Ursula Röthlisberger, David Lyndon Emsley, Pascal Alexander Schouwink, Jing Gao, Felix Thomas Eickemeyer, Michael Allan Hope, Lukas Pfeifer, Nikolaos Lempesis, Virginia Carnevali, Ümmügülsüm Günes, Lorenzo Agosta, Yuxuan Zhang, Likai Zheng, Vladislav Slama, Francesco Biasoni

A-site cation mixing can enhance the photovoltaic performance of a wide-bandgap (WBG) perovskite, but rubidium (Rb) cation mixing generally forms a nonperovskite phase. We report that lattice strain locks Rb ions into the α-phase of the lattice of a triple ...

American Association for the Advancement of Science (AAAS)2025

Perovskite heteroepitaxy for high-efficiency and stable pure-red LEDs

Mohammad Khaja Nazeeruddin, Shun Tian

Ultrasmall CsPbI3 perovskite quantum dots (QDs) are the most promising candidates for realizing efficient and stable pure-red perovskite light-emitting diodes (PeLEDs)1, 2, 3, 4–5. However, it is challenging for ultrasmall CsPbI3 QDs to retain their soluti ...

2025

Pre-annealing for improved LPCVD deposited boron-doped poly-Si hole-selective contacts

Xinyu Zhang, Franz-Josef Haug, Luca Massimiliano Antognini, Josua Andreas Stückelberger

We demonstrate the beneficial effect of a pre-annealing step prior to the boron diffusion on passivation and contact resistivity of industrially LPCVD deposited poly-Si/SiOX hole-selective contacts. We investigate the influence of the pre-annealing tempera ...

ELSEVIER2023

Data-driven design of organic electronic materials

Jacob Terence Blaskovits

Singlet fission (SF) is a multiexciton-generating process whereby an excited state singlet (S1) is converted into two lower-energy triplets (T1). The inclusion of a SF-capable material into a photovoltaic device offers the potential for the absorption of p ...

EPFL2023

Traps for Electrons and Holes Limit the Efficiency and Durability of Polymer Light-Emitting Electrochemical Cells

Frank Nüesch, Wei-Hsu Hu, Camilla Arietta Vael-Garn

Polymer light-emitting electrochemical cells (PLECs) and light-emitting diodes (PLEDs) receive interest for large-area lighting and signage applications. During operation of a PLEC, a p-i-n junction develops where electrons and holes are injected into the ...

2022

Device Performance of Emerging Photovoltaic Materials (Version 2)

Mohammad Khaja Nazeeruddin

Following the 1st release of the "Emerging photovoltaic (PV) reports", the best achievements in the performance of emerging photovoltaic devices in diverse emerging photovoltaic research subjects are summarized, as reported in peer-reviewed articles in aca ...

WILEY-V C H VERLAG GMBH2021

Optical and structure properties of CH3NH3PbI3 perovskite films doped with Cesium

Anwar Qasem M Alanazi

Methylammonium lead iodide doped with cesium (MA(1-x)Cs(x)PbI(3), x = 0, 0.03, 0.05, 0.1) thin films were prepared with and without chlorobenzene (CB). X-ray diffraction analysis applying the Rietveld refinement method is carried out, and the effect of Cs ...

EDP Sciences2021

Solution-based heteroepitaxial growth of stable mixed cation/anion hybrid perovskite thin film under ambient condition via a scalable crystal engineering approach

Michael Graetzel, Shaik Mohammed Zakeeruddin, Fabrizio Giordano

The performance of perovskite solar cells is under direct control of the perovskite film quality and controlling the crystalinity and orientation of solution-processed perovskite film is a fundamental challenge. In this study, we present a scalable fabrica ...

Elsevier2020

Electroluminescence Dynamics in Perovskite Solar Cells Reveals Giant Overshoot Effect

Wolfgang Richard Tress, Marius Franckevicius

High performance of both photovoltaic and electroluminescent devices requires low nonradiative recombination losses. In perovskites, such loses strongly depend on the carrier traps related to the mobile ions and vacancies, causing I-V hysteresis of solar c ...

AMER CHEMICAL SOC2019

Extraction of p-n junction properties and series resistance in GaAs nanowire-based solar cells using light concentration

Anna Fontcuberta i Morral, Dmitry Mikulik, Pablo Romero Gómez

Series resistance in solar cells limit their maximum conversion efficiency and thus should be minimized. Generally, such losses originate from deficiencies at the contact or absorber level. Quantifying them is the first step for tackling its reduction. In ...

IOP PUBLISHING LTD2019

Additives, Hole Transporting Materials and Spectroscopic Methods to Characterize the Properties of Perovskite Films

Michael Graetzel, Shaik Mohammed Zakeeruddin, Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Marko Stojanovic, Amita Ummadisingu, Jiyoun Seo, Michael Saliba

The achievement of high efficiency and high stability in perovskite solar cells (PSCs) requires optimal selection and evaluation of the various components. After a brief introduction to the perovskite materials and their historical evolution, the first par ...

Schweizerische Chemische Gesellschaft2017

Spontaneous crystal coalescence enables highly efficient perovskite solar cells

Michael Graetzel, Ulf Anders Hagfeldt, Amita Ummadisingu, Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba

Perovskite solar cells have recently reached staggering efficiencies, through efforts focused on reducing grain boundaries, by enlarging the size of the crystalline domains that constitute the perovskite films. Here, we demonstrate that smaller crystallite ...

Elsevier Science Bv2017

Time-resolved Element-selective Probing of Charge Carriers in Solar Materials

Majed Chergui, Mercedes Hannelore Rittmann-Frank, Jochen Rittmann, Thomas Charles Henry Rossi, Fabio Giacomo Santomauro, Dominik Kinschel, James Michael Budarz

We review our recent results on the implementation of picosecond (ps) X-ray absorption spectroscopy to probe the electronic and geometric structure of centres formed by photoexcitation of solar materials such as TiO2 polymorphs and inorganic Cs-based perov ...

2017

High-Performance Perovskite Solar Cells with Enhanced Environmental Stability Based on Amphiphile-Modified CH3NH3PbI3

Mohammad Khaja Nazeeruddin, Rosario Scopelliti, Ulf Anders Hagfeldt, Emad Oveisi, Peng Gao, Peng Gao, Jingshan Luo, Dongqin Bi

A new aliphatic fluorinated amphiphilic additive is added to CH3NH3PbI3 perovskite to tune the morphology and enhance the environmental stability without sacrificing the performance of the devices. Judicious screening of the perovskite precursor solution r ...

Wiley-V C H Verlag Gmbh2016

New method for lateral mapping of bimolecular recombination in thin-film organic solar cells

Wolfgang Richard Tress

The best organic solar cells are limited by bimolecular recombination. Tools to study these losses are available; however, they are only developed for small area (laboratory-scale) devices and are not yet available for large area (production-scale) devices ...

Wiley-Blackwell2016