Metal Soap Membranes for Gas Separation

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Ordered two-dimensional (2D) materials hosting Å-scale pores are highly promising for enabling challenging separation, thanks to well-defined pore geometry resulting in tight confinement of ions when hosted inside the pore. In addition, the 2D nature of th ...

Photocatalytic solar water splitting is a promising technology for producing green hydrogen that has the potential to compete economically with other commercially utilized carbon-based fuels. While this field has existed for decades, there has yet to be a ...

In this work, we studied the potential of using thin films deposited by plasma-enhanced chemical vapor deposition (PECVD) for two main purposes: introducing an n-type passivating contact at the front of a TOPCon solar cell, or simplifying the fabrication o ...

Single-layer graphene, hosting a high density of functionalized molecular-sieving atom-thick pores, is considered to be an excellent material for gas separation membranes. These functionalized atom-thick pores enable the shortest transport pathway across t ...

Plasmonic photochemistry has a large potential to replace energy-intensive chemical processes with low-temperature, low-pressure light-driven chemical reactions. Plasmonic nanostructures have emerged as promising photocatalysts with exceptional and tunable ...

Hydrogenated amorphous silicon (a-Si:H) is a material with a very good radiation hardness and with the possibility of deposition on flexible substrates like Polyimide (PI). Exploiting these properties, the HASPIDE (Hydrogenated Amorphous Silicon PIxels DEt ...

This Thesis provides a comprehensive and correlative investigation of the microstructure, chemical state, and electrochemical reactivity of manganese oxide (MnOx) films, aiming to gain a deeper understanding of the deposition and dissolution mechanism of M ...

Metal-organic frameworks (MOFs) are a rapidly growing class of materials that offer great promise in various applications. However, the synthesis remains challenging: for example, a range of crystal structures can often be accessed from the same building b ...

The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

Crystallization of amorphous layers has been demonstrated under various radically different laser-exposure conditions, including continuous wave (cw) and pulsed lasers. Here, we investigate the specific role of ionization in the crystallization of dielectr ...

The invention relates to methods for the preparation of ultrathin metal-organic frameworks (MOFs), in particular Zeolitic imidazolate frameworks (ZIFs) and uses thereof and resulting products thereof, in particular useful for the preparation of gas separat ...

The prospects are presented for precise measurements of the branching ratios of the purely leptonic Bc+ → τ+ντ and B+ → τ+ντ decays at the Future Circular Collider (FCC). This work is focused on the hadronic τ(+) → π(+)π(+)π(-) nu(tau) decay in both Bc+ → ...

An energy production system (100) comprising a fuel cell (102), a combustion unit (103) connected to a flue gas outlet (108) of the fuel cell, the combustion unit configured for combustion of oxidizable components in flue gas output by the fuel cell, the c ...

MOFs are a class of porous crystalline materials whose unique properties have led to applicability in several fields ranging from gas adsorption to drug delivery. Despite their high potential, MOFs are usually found as fine powders, a property that can lim ...

High-entropy alloys (HEAs), containing several metallic elements in near-equimolar proportions, have long been of interest for their unique mechanical properties. More recently, they have emerged as a promising platform for the development of novel heterog ...

Sensing and imaging of light in the shortwave infrared (SWIR) range is increasingly used in various fields, including bio-imaging, remote sensing, and semiconductor process control. SWIR-sensitive organic photodetectors (OPDs) are promising because organic ...

Due to the subtle balance of intermolecular interactions that govern structure-property relations, predicting the stability of crystal structures formed from molecular building blocks is a highly non-trivial scientific problem. A particularly active and fr ...

The design of metal-organic frameworks (MOFs) having large pore sizes and volumes often requires the use of complex organic ligands, currently synthesized using costly and time-consuming palladium-catalyzed coupling chemistry. Thus, in the present work, a ...

Metal-porphyrins are studied intensively due their potential applications, deriving from the variety of electronic and chemical properties, tunable by selecting metal centers and functional groups. Metalation, de- and trans-metalation processes are fundame ...

Metal Soap Membranes for Gas Separation

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Crystal, defect, and morphology engineering of porous two-dimensional materials for ionic separation

Solar-driven hydrogen production using organic semiconductor nanoparticles

Font Side Solutions for c-Si Solar Cells with High-Temperature Passivating Contacts

Functionalized Å-scale Pores in Graphene for Carbon Capture

Plasmonic Nanostructures for Photocatalysis: Material, Photonic and Electronic Effects

HASPIDE: a project for the development of hydrogenated amorphous silicon radiation sensors on a flexible substrate

Microstructure - Electrochemical Surface Reactivity Relationship of Electrochemically Grown Manganese Oxides Films

How Reproducible is the Synthesis of Zr-Porphyrin Metal-Organic Frameworks? An Interlaboratory Study

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Influence of ionization and cumulative effects on laser-induced crystallization in multilayer dielectrics

Method of preparation of ultrathin metal-organic frameworks & uses thereof

Method of preparation of ultrathin metal-organic frameworks & uses thereof

Prospects for Bc+ and B+ → τ+ντ at FCC-ee

Fuel cell energy generation system

Densification and shaping of pure Cu-BTC powders using a solid-state chemical transformation

Surface segregation in high-entropy alloys from alchemical machine learning

Shortwave Infrared-Sensitive, Narrowband Organic Upconversion Devices with a Gain

A data-driven interpretation of the stability of organic molecular crystals

A Simple, Transition Metal Catalyst-Free Method for the Design of Complex Organic Building Blocks Used to Construct Porous Metal-Organic Frameworks

Stabilization versus competing de-metalation, trans-metalation and (cyclo)-dehydrogenation of Pd porphyrins at a copper surface