Publication

The influence of aluminium on the dissolution of amorphous silica and its relation to alkali silica reaction

Publications associées (30)

Report of RILEM TC 267-TRM: Improvement and robustness study of lime mortar strength test for assessing reactivity of SCMs

Mohsen Ben Haha, Mathieu Antoni, Karen Scrivener, Shashank Bishnoi, Pawel Tadeusz Durdzinski, Ruben Anton Snellings, Xuerun Li, Anuj Parashar, Yuvaraj Dhandapani

RILEM TC 267-TRM is studying tests for the reactivity supplementary cementitious materials (SCMs). In the first phase, the lime reactivity (LR) test, which is standardised in Indian standard (IS)-1727, gave promising correlations with 90-days cement mortar ...

SPRINGER2022

Microstructural developments of limestone calcined clay cement (LC3) pastes after long-term (3 years) hydration

Karen Scrivener, Franco Alberto Zunino Sommariva

LC3 is one of the most promising alternatives for a high-performance blended cement with a significantly lower clinker content and with potential for worldwide adoption. For this reason, understanding its long-term performance is relevant to ensure service ...

Pergamon-Elsevier Science Ltd2022

Resistance of cementitious materials to sulfate attack: quantifying performance with a reliable unidirectional approach

Qiao Wang

Depending on the environmental conditions, concrete materials can come into contact with sulfate ions which are widely present in rivers, underground water, sewers, seawater and soil. Sulfates can react with the cement paste in concrete and cause damage wh ...

EPFL2022

Aggregate dissolution in different pore solutions

Mahsa Bagheri

The occurrence of cracking due to alkali silica reaction (ASR) affects the service life of concrete structures. The dissolution of silica-containing minerals within aggregates causes the formation of ASR products, which fill macroscopic cracks and cause th ...

EPFL2021

The effect of alkali hydroxides and equilibration time on Al uptake by calcium silicate hydrates (C-S-H)

Sonya Barzgar

Cement production accounts for approximately 8% of man-made CO2 emissions. Lowering these CO2 emissions is currently one of the most important and urgent research topics within the cement community. To reduce these emissions, the Portland cement (PC) is pa ...

EPFL2021

Grafting of Alkali Metals on Fumed Silica for the Catalytic Dehydrogenation of Methanol to Formaldehyde

Christophe Jean Baranowski, Oliver Kröcher, Alimohammad Bahmanpour, Jack Brandon

Water free, non-oxidative catalytic dehydrogenation of methanol to formaldehyde is an important process for the formation of anhydrous, molecular formaldehyde (FA). Sodium or sodium-containing salts were shown to catalyze the reaction, but their reaction m ...

Wiley-VCH Verlag2021

Meso-scale finite element modeling of Alkali-Silica-Reaction

Jean-François Molinari, Roozbeh Rezakhani, Emil Gallyamov

The Alkali-Silica Reaction (ASR) in concrete is a chemical reaction, which produces an expansive product, generally called “ASR gel”, and causes cracking and damage in concrete over time. Affecting numerous infrastructures all around the world, ASR has bee ...

2021

Multi-scale investigation on mechanical behavior and microstructural alteration of C-S-H in carbonated Alite paste

Karen Scrivener

Carbonation treatment is a promising option to enhance recycled concrete aggregate (RCA) quality and eventually improve concrete performance. This study investigated the multi-scale mechanical properties of calcium silicate hydrates (C-S-H) in a mature ali ...

Pergamon-Elsevier Science Ltd2021

Evaluation of Total Reactive Oxide Ratios and Working Solution Ratios on Strength Development in Fly Ash-Based Geopolymers

Fly ash-based geopolymers are being developed as sustainable alternate binders for producing concrete. The consistent production of a stable geopolymeric binder suitable for use in structural applications from alkaline activation of low-calcium fly ash was ...

2020

The effect of sodium hydroxide on Al uptake by calcium silicate hydrates (C S H)

Christian Ludwig, Barbara Lothenbach, Sonya Barzgar, Alessio Di Giacomo, Mohamed Tarik

To reduce the CO2 emissions from cement production, Portland cement (PC) is partially replaced by supplementary cementitious materials (SCM). Reactions of SCM with PC during hydration leads to the formation of CSH with more silicon and aluminum than in PC, ...

2020