Publications associées à One-Pot Synthesis of 1-[(Triisopropylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one (TIPS-EBX): Process Safety Assessment and Impact of Impurities on Product Stability

Publications associées (31)

Anonymous Tokens with Stronger Metadata Bit Hiding from Algebraic MACs

On the one hand, the web needs to be secured from malicious activities such as bots or DoS attacks; on the other hand, such needs ideally should not justify services tracking people's activities on the web. Anonymous tokens provide a nice tradeoff between ...

2023

Hypervalent Iodine: New Reagents and Functionalization of Peptides

Eliott Hugo Joran Le Du

Alkynes are found in a multitude of natural or synthetic bioactive compounds. In addition to the capacity of these chemical motifs to impact the physicochemical properties of a molecule of interest, the well-established reactivity of alkynes makes them ide ...

EPFL2023

Advancing efficiency and reliability in thermal analysis of laser powder-bed fusion

Christian Leinenbach

In laser based powder-bed fusion of metals (PBF-LB/M), parts are fabricated by melting layers of powder using a high-intensity laser beam. During this process, the material is exposed to rapid cooling rates and intense thermal gradients, which are the unde ...

2023

New SIDH Countermeasures for a More Efficient Key Exchange

Tako Boris Fouotsa

The Supersingular Isogeny Diffie-Hellman (SIDH) protocol has been the main and most efficient isogeny-based encryption protocol, until a series of breakthroughs led to a polynomial-time key-recovery attack. While some countermeasures have been proposed, th ...

Springer2023

PROFACTORY: Improving IoT Security via Formalized Protocol Customization

Mathias Josef Payer

As IoT applications gain widespread adoption, it becomes important to design and implement IoT protocols with security. Existing research in protocol security reveals that the majority of disclosed protocol vulnerabilities are caused by incorrectly impleme ...

USENIX ASSOC2022

High-Throughput Sizing, Counting, and Elemental Analysis of Anisotropic Multimetallic Nanoparticles with Single-Particle Inductively Coupled Plasma Mass Spectrometry

Andreas Züttel, Natalia Gasilova, Wen Luo, Mo Li, Cedric David Koolen

Nanoparticles (NPs) have wide applications in physical and chemical processes, and their individual properties (e.g., shape, size, and composition) and ensemble properties (e.g., distribution and homogeneity) can significantly affect the performance. Howev ...

2022

Expeditious Asymmetric Synthesis of Polypropionates Relying on Sulfur Dioxide-Induced C-C Bond Forming Reactions

Pierre Vogel

For a long time, the organic chemistry of sulfur dioxide (SO2) consisted of sulfinates that react with carbon electrophiles to generate sulfones. With alkenes and other unsaturated compounds, SO2 generates polymeric materials such as polysulfones. More rec ...

MDPI2021

A Rosetta-based protein design protocol converging to natural sequences

Bruno Emanuel Ferreira De Sousa Correia, Stéphane Rosset, Zander Harteveld

Computational protein design has emerged as a powerful tool capable of identifying sequences compatible with pre-defined protein structures. The sequence design protocols, implemented in the Rosetta suite, have become widely used in the protein engineering ...

AMER INST PHYSICS2021

Open-access quantitative MRI data of the spinal cord and reproducibility across participants, sites and manufacturers

Dimitri Nestor Alice Van De Ville, Maxime Descoteaux, Nawal Noëlle Kinany

In a companion paper by Cohen-Adad et al. we introduce the spine generic quantitative MRI protocol that provides valuable metrics for assessing spinal cord macrostructural and microstructural integrity. This protocol was used to acquire a single subject da ...

NATURE PORTFOLIO2021

Metal-Free Electrophilic Alkynylation of Sulfenate Anions with Ethynylbenziodoxolone Reagents

Jérôme Waser, Stefano Nicolai, Franck Le Vaillant, Stephanie Grace Elizabeth Amos, Alec Gagnebin

Alkynyl sulfoxides are important building blocks with a unique reactivity in organic chemistry, but only a few reliable methods have been reported to synthesize them. A novel route to access alkynyl sulfoxides is reported herein by using ethynyl benziodoxo ...

2019

R2P2: Making RPCs first-class datacenter citizens

Edouard Bugnion, Evangelos Marios Kogias, Adrien Ghosn, Georgios Prekas, Jonas Fietz

Remote Procedure Calls are widely used to connect datacenter applications with strict tail-latency service level objectives in the scale of µs. Existing solutions utilize streaming or datagram-based transport protocols for RPCs that impose overheads and li ...

USENIX ASSOC2019

Stereoselective synthesis of alkyl-, aryl-, vinyl- and alkynyl-substituted Z-enamides and enol ethers

Jérôme Waser, Matthew Wodrich, Paola Caramenti, Nina Declas, Romain Gaëtan Tessier

Enamides and enol ethers are valuable building blocks in synthetic chemistry, yet their stereoselective synthesis can be challenging. Herein, we report a new stereoselective synthesis of vinyl, aryl, alkynyl, alkyl and thio-substituted Z-enamides and enol ...

2019

A coarse-mesh methodology for modelling of single-phase thermal-hydraulics of ESFR innovative assembly design

Andreas Pautz, Konstantin Mikityuk, Carlo Fiorina, Stefan Radman

The GeN-Foam multi-physics code enables coupled thermal-hydraulic, neutronic, and thermal-mechanical analysis of fast reactor cores with 3-D unstructured deformable meshes. Advances within the Horizon2020 ESFR-SMART project, as well as trends towards highe ...

ELSEVIER SCIENCE SA2019

Formal Analysis of Distance Bounding with Secure Hardware

Serge Vaudenay, Handan Kilinç Alper

A distance bounding (DB) protocol is a two-party authentication protocol between a prover and a verifier which is based on the distance between the prover and the verifier. It aims to defeat threats by malicious provers who try to convince that they are cl ...

2018

Labeled PSI from Fully Homomorphic Encryption with Malicious Security

Zhicong Huang

Private Set Intersection (PSI) allows two parties, the sender and the receiver, to compute the intersection of their private sets without revealing extra information to each other. We are interested in the unbalanced PSI setting, where (1) the receiver's s ...

ASSOC COMPUTING MACHINERY2018

Toward Achieving Harmonization in a Nanocytotoxicity Assay Measurement Through an Interlaboratory Comparison Study

Nadia Rachel Von Moos

Development of reliable cell-based nanotoxicology assays is important for evaluation of potentially hazardous engineered nanomaterials. Challenges to producing a reliable assay protocol include working with nanoparticle dispersions and living cell lines, a ...

2017

Benzimidazolium salt-based solid-state electrolytes afford efficient quantum-dot sensitized solar cells

Paul Joseph Dyson, Zhaofu Fei, Zhangjun Huang

A novel solid-state electrolyte based on 1,3-dihexylbenzimidazolium ([DHexBIm]) cations combined with Br-, BF4- or SCN- anions is used in CdS/CdSe sensitized quantum dot sensitized solar cells (QDSSCs). A power conversion efficiency of 4.26% was achieved w ...

Royal Society of Chemistry2017

Stereoselective synthesis of alkenes via base-metal-catalyzed addition reactions to alkynes and activation of hydrogen peroxide and carbon dioxide by iron complexes

Fedor Zhurkin

Alkene functionality can be found in the majority of natural products, drugs, catalysts and organic materials. Therefore, methods of C-C double bond formation constitute a cornerstone of organic synthesis. Selective formation of either (Z)- or (E)-isomer i ...

EPFL2017

A systematic approach for thermal stability predictions of chemicals and their risk assessment: Pattern recognition and compounds classification based on thermal decomposition curves

Thierry Meyer, Nadia Baati, Annik Nanchen

In the context of process and product design, predictive models are increasingly employed. Decomposition properties of chemicals may be experimentally determined through calorimetric measurements, and a few molecular structure-based models- which correlate ...

Institution of Chemical Engineers2017

Cyclic Hypervalent Iodine Reagents for Atom-Transfer Reactions: Beyond Trifluoromethylation

Jérôme Waser, Yifan Li, Durga Prasada Rao Hari, Maria Victoria Vita

Hypervalent iodine compounds are privileged reagents in organic synthesis because of their exceptional reactivity. Among these compounds, cyclic derivatives stand apart because of their enhanced stability. They have been widely used as oxidants, but their ...

Wiley-Blackwell2016