Complexation of [Gd(DTTA–Me)(H2O)2]− by Fluoride and Its Consequences to Water Exchange

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The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

Hydrogen clathrate hydrates are ice-like crystalline substances in which hydrogen molecules are trapped inside polyhedral cages formed by the water molecules. Small cages can host only a single H-2 molecule, while each large cage can be occupied by up to f ...

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Structural and electronic factors are crucial to rationalizethedifferent N,O or N,N chelating coordination of pyrazolones containinga pyridine ring. The reactivity of proligand 3-phenyl-1-(pyridin-2-yl)-5-pyrazolone(HLpy,ph) with the (arene)Ru(II) fragment ...

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Bent (hetero)allenes such as carbodicarbenes and carbodiphosphoranes can act as neutral C-donor ligands, and diverse applications in coordination chemistry have been reported. N-Heterocyclic diazoolefins are heterocumulenes, which can function in a similar ...

Detailed chemical abundances of very metal-poor (VMP; [Fe/H] < -2) stars are important for better understanding the first stars, early star formation, and chemical enrichment of galaxies. Big on-going and coming high-resolution spectroscopic surveys provid ...

Complexation of [Gd(DTTA–Me)(H2O)2]− by Fluoride and Its Consequences to Water Exchange

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Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Large-cage occupation and quantum dynamics of hydrogen molecules in sII clathrate hydrates

Beyond the coupled distortion model: structural analysis of the single domain cupredoxin AcoP, a green mononuclear copper centre with original features

Encoding quantum-chemical knowledge into machine-learning models of complex molecular properties

Unique corrosion behavior of an archaeological Roman iron ring: Microchemical characterization and thermodynamic considerations

Technical note: Two-component electrical-conductivity-based hydrograph separation employing an exponential mixing model (EXPECT) provides reliable high-temporal-resolution young water fraction estimates in three small Swiss catchments

Bridging Native and Intrinsic Structures of Microhydrated Biomolecules by Cold Ion Spectroscopy

Gas/Surface reactions probed by reflection absorption infrared spectroscopy

Machine-learning the electronic density of states: electronic properties without quantum mechanics

Spectral and thermodynamic properties of interacting electrons with dynamical functionals

Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems

Many-body physics with strongly interacting fermions coupled to light

Revealing the Structure of Tryptophan in Microhydrated Complexes by Cold Ion Spectroscopy

Implementing Multi-Electron Transfer Strategies in Uranium Chemistry

Deriving Major Ion Concentrations at High Resolution from Continuous Electrical Conductivity Measurements in Karst Systems

Nature-Inspired Stalactite Nanopores for Biosensing and Energy Harvesting

Computational Studies for the Design of Metalloenzyme Mimics

Liposomes and Lipid Droplets Display a Reversal of Charge-Induced Hydration Asymmetry

Synthesis and Reactivity of an Anionic Diazoolefin

Analysis of accretion disc structure and stability using open code for vertical structure