Publications associées à Multifunctional SnO<sub>2</sub> QDs/MXene Heterostructures as Laminar Interlayers for Improved Polysulfide Conversion and Lithium Plating Behavior

Publications associées (13)

Non-fluorinated Asymmetric Ether Electrolytes with Controlled Solvation Structure for High-voltage Lithium Metal Batteries

Ether-based electrolytes are well-suited for lithium metal anodes but suffer from limited oxidative stability, restricting their use with high-voltage cathodes. Fluorination has been employed to mitigate this challenge; however, their recycling poses envir ...

AMER CHEMICAL SOC2025

Swiss CAT plus , a Data-driven Infrastructure for Accelerated Catalysts Discovery and Optimization

Elisa Clerc, Urielle Marine Randrianarisoa, Nicolai Cramer, Pascal Miéville, Florian Patrick Marie Daniel De la Barre De Nanteuil, Edy Mariano, Keyan Michel Villat, Jean-Charles Louis André Cousty

The Catalysis Hub - Swiss CAT+, is a new infrastructure project funded by the ETH Domain, co -head-ed by EPFL and ETHZ. It offers the scientific community a unique integrated technology platform combining automated and high-throughput experimentation with ...

SWISS CHEMICAL SOC2023

Voltage-driven Reactivity of Liquid Ga and CuGa Nanoparticles for Electrocatalytic CO2 Reduction and Synthesis

Valery Okatenko

The rising atmospheric level of carbon dioxide, CO2, contributes to climate change and poses urgent need to find scalable solutions both to decrease its emissions and to be able to recycle it, if the goals of Paris Agreement to limit the temperature rise a ...

EPFL2023

Engineering Graphdiyne for Solar Photocatalysis

Jian Li

Graphdiyne (GDY) with a direct band gap, excellent carrier mobility and uniform pores, is regarded as a promising photocatalytic material for solar energy conversion, while the research on GDY in photocatalysis is a less developed field. Herein, the distin ...

Wiley-VCH Verlag GmbH2023

Iridium-Catalyzed Acid-Assisted Hydrogenation of Oximes to Hydroxylamines

Nicolai Cramer, Josep Más-Roselló

We found that cyclometalated cyclopentadienyl iridium(III) complexes are uniquely efficient catalysts in homogeneous hydrogenation of oximes to hydroxylamine products. A stable iridium C,N-chelation is crucial, with alkoxy-substituted aryl ketimine ligands ...

Wiley-VCH Verlag GmbH2021

Hydrogen Storage by Reduction of CO2 to Synthetic Hydrocarbons

Andreas Züttel, Wen Luo, Kun Zhao, Noris André Gallandat, Jie Zhang

The storage of renewable energy is crucial for the substitution of fossil fuels with renewable energy. Hydrogen is the first step in the conversion of electricity from renewable sources to an energy carrier. However, hydrogen is technically and economicall ...

2021

Investigating the effects of substrate morphology and experimental conditions on the enzymatic hydrolysis of lignocellulosic biomass through modeling

Jeremy Luterbacher

Background Understanding how the digestibility of lignocellulosic biomass is affected by its morphology is essential to design efficient processes for biomass deconstruction. In this study, we used a model based on a set of partial differential equations d ...

BMC2021

Asymmetric Elimination Reaction on Chiral Metal Surfaces

Harald Brune, Samuel Thomas Stolz

The production of enantiopure materials and molecules is of uttermost relevance in research and industry in numerous contexts, ranging from nonlinear optics to asymmetric synthesis. In the context of the latter, dehalogenation, which is an essential reacti ...

Wiley-V C H Verlag Gmbh2021

Towards the Sarpagine-Ajmaline-Macroline Family of Indole Alkaloids: Enantioselective Synthesis of an N-Demethyl Alstolactone Diastereomer

Jieping Zhu, Qian Wang, Dylan Jean Robert Dagoneau

the strategy involving the use of functionalized tetrahydro-6H-cycloocta[b]indol-6-one is reported as a key intermediate for synthesis of members of the sarpagine-ajmaline-macroline family of monoterpene indole alkaloids. The desired tricycle was synthesiz ...

WILEY-V C H VERLAG GMBH2020

Oxidative Print Light Synthesis Thin Film Deposition of Prussian Blue

Hubert Girault, Emad Oveisi, Mounir Driss Mensi, Victor Costa Bassetto, Wanderson Oliveira Da Silva, Dominika Baster

Prussian blue (PB) and Prussian blue analogues (PBAs) are commonly synthesized by conventional methods, such as chemical precipitation, thermal decomposition, and electrochemical deposition. Herein, we have successfully synthesized Prussian blue by oxidati ...

2020

Mitigating voltage losses in photoelectrochemical cell scale-up

Sophia Haussener, Ronald Ramiro Gutierrez Perez

In solar water splitting, efforts in scaling up the photoelectrochemical cell beyond laboratory scale have started to attract significant attention. Several large-area devices have been demonstrated, but typically the efficiencies are much lower than their ...

ROYAL SOC CHEMISTRY2020

TADDOL-based phosphorus(III)-ligands in enantioselective Pd(0)-catalysed C-H functionalisations

Nicolai Cramer, Julia Pedroni

Monodentate TADDOL-derived phosphoramidites and phosphonites are versatile chiral ligands for enantio-selective Pd(0)-catalysed C-H functionalisations. They enable highly selective cyclisations to access a wide range of chiral carbo-and heterocycles. The h ...

Royal Society of Chemistry2015

Novel Approaches for Ruthenium Catalyzed Atom Transfer Radical Addition Reactions

Katrin Anne Thommes

A new catalytic procedure for atom-transfer radical addition (ATRA) and cyclization (ATRC) reactions is described. The combination of the ruthenium(III) complex [RuCl2Cp*(PPh3)] with magnesium allows these reactions to be performed under mild conditions wi ...

EPFL2010