Publications associées à The Impact of Toluene on the Performance of Anode-Supported Ni-YSZ SOFC Operated on Hydrogen and Biosyngas

Publications associées (30)

Reversible photo-electrochemical device for solar hydrogen and power generation

Sophia Haussener, Saurabh Yuvraj Tembhurne, Alexandre Dominique M. Cattry, Matthieu Jonin, Mahendra Patel

A reversible photo-electrochemical device operating under concentrated irradiation could offer a stand-alone solution for producing solar fuel (in photo-driven electrolysis mode) and power (in fuel cell mode). This strategy would present the advantage of h ...

2024

Spinel Protective Coatings for Solid Oxide Cell (SOC) Interconnects (ICs)

Samaneh Daviran

Abstract The degradation of metal interconnects (ICs) in Solid Oxide Cells (SOCs) primarily results from chromium (Cr) oxide scale growth on stainless-steel substrates, causing ohmic loss and air-side electrode poisoning by Cr. This thesis addresses these ...

EPFL2024

Insights into Electrocatalyst Transformations Studied in Real Time with Electrochemical Liquid-Phase Transmission Electron Microscopy

Vasiliki Tileli, Tzu-Hsien Shen, Robin Pierre Alain Girod

The value of operando and in situ characterization methodologies for understanding electrochemical systems under operation can be inferred from the upsurge of studies that have reported mechanistic insights into electrocatalytic processes based on such mea ...

American Chemical Society2023

Unidirectional penetration approach for characterizing sulfate attack mechanisms on cement mortars and pastes

Karen Scrivener, William Wilson, Qiao Wang

Degradation of cementitious materials by sulfate ions is commonly classified into chemical and physical sulfate attack. So-called "physical" attack dominates in many field situations, but laboratory testing focuses on "chemical" attack under full-immersion ...

Pergamon-Elsevier Science Ltd2023

Decoupling the Contributions of Different Instability Mechanisms to the PEMFC Performance Decay of Non-noble Metal O2-Reduction Catalysts

Vasiliki Tileli, Robin Pierre Alain Girod

Non-noble metal catalysts (NNMCs) hold the potential to replace the expensive Pt-based materials currently used to speed up the oxygen reduction reaction (ORR) in proton exchange membrane fuel cell (PEMFC) cathodes, but they feature poor durability that in ...

AMER CHEMICAL SOC2023

Pure Amorphous and Ultrathin Phosphate Layer with Superior Ionic Conduction for Zinc Anode Protection

Kangning Zhao

Fast and uniform ion transport within the solid electrolyte interphase (SEI) is considered a crucial factor for ensuring the long-term stability of metal electrodes. In this study, we present the fabrication of ultrathin artificial interphases consisting o ...

Amer Chemical Soc2023

Poisoning effects of chlorine on a solid oxide cell operated in co-electrolysis

Jan Van Herle, Stefan Diethelm, Guillaume Jeanmonod

Although the effects of impurities on the Ni-YSZ electrode of a solid oxide cell in fuel cell operation have been studied, reports on their effects during electrolysis operation are limited. Here, short-term experiments at various current densities and a d ...

ELSEVIER2021

Cu/Metal Oxide Hybrid Nanocrystals as Electrocatalysts for the CO2 Reduction Reaction

Seyedehbehnaz Varandili

The electrochemical CO2 reduction reaction (CO2RR) is envisioned to play a significant role in achieving carbon neutrality while contributing to storing renewable energies. Cu-based materials are among the most promising electrocatalysts. However, 16 diffe ...

EPFL2021

Emergence of Potential-Controlled Cu-Nanocuboids and Graphene-Covered Cu-Nanocuboids under Operando CO2 Electroreduction

Magalí Alejandra Lingenfelder, Fernando Pablo Cometto, Karla Banjac, Thanh Hai Phan

The electroreduction of CO2 (CO2RR) is a promising strategy toward sustainable fuels. Cu is the only Earth-abundant and pure metal capable of catalyzing CO2-to-hydrocarbons conversion with significant Faradaic efficiencies; yet, its dynamic structure under ...

AMER CHEMICAL SOC2021

Cyclic degradation analysis of reversible Solid Oxide Cell short-stack

Jan Van Herle, Stefan Diethelm, Philippe Aubin, Maria del Mar Perez Fortes, Guillaume Jeanmonod, Suhas Nuggehalli Sampathkumar, David Constantin

The deployment of renewable energy systems has been increasing steadily in recent years. The intermittency associated with the renewable electricity supply can be addressed through the usage of energy storage and release systems. In this framework, reversi ...

2020

The Impact of Surfactants on the Inertial Separation of Bubbles in Microfluidic Electrolyzers

Demetri Psaltis, Seyyed Mohammad Hosseini Hashemi, Pooria Hadikhani

Improving the throughput of electrochemical reactions such as water electrolysis is an ongoing effort. In a membrane-less electrolyzer, product separation can be achieved via controlled two-phase flows within the electrochemical flow cells. In this case, i ...

ELECTROCHEMICAL SOC INC2020

Degradation analysis of commercial interconnect materials for solid oxide fuel cells in stacks operated up to 18000 hours

Jan Van Herle, Manuel Bianco

Despite being a mature technology, solid oxide fuel cell (SOFC) devices are still limited by lifetime issues. In SOFC stacks, cell/interconnect interaction is the main responsible for voltage degradation at the oxygen electrode side. Corrosion and chromium ...

2019

Analysis of High Temperature Degradation of Alloys in Solid Oxide Fuel Cell

Manuel Bianco

Solid oxide fuel cells (SOFCs) are approaching commercialization to improve power production efficiency. Currently, cost and lifetime reliability limit their spread in the market. The SOFC is ceramic-based, but refractory metal alloys are in fact the major ...

EPFL2019

Sulfur Poisoning Recovery on a Solid Oxide Fuel Cell Anode Material through Reversible Segregation of Nickel

Jan Van Herle, Oliver Kröcher, Davide Ferri, Hossein Madi, Patrick Simon Steiger

The perovskite-type mixed oxide La0.3Sr0.55Ti0.95Ni0.05O3-delta (LSTN) is demonstrated to exhibit the remarkable property of structural regeneration, where Ni can be reversibly exsoluted from the host perovskite lattice resulting in a regenerable Ni cataly ...

AMER CHEMICAL SOC2019

Ex-situ experimental benchmarking of solid oxide fuel cell metal interconnects

Jan Van Herle, Manuel Bianco

Solid oxide fuel cells (SOFCs) can convert hydrocarbon fuels, such as methane, into heat and electricity with a high conversion efficiency. The fuel flexibility of the SOFC derives from the high operating temperature (600-900 °C). Such a high temperature s ...

2019

Real-Time Optimization of Solid Oxide Fuel Cell Systems : Methodology and Implementation

Tafarel de Avila Ferreira

Optimization of industrial processes aims at minimizing operating cost or maximizing economic profit while respecting plant constraints. In process industry, real-time optimization (RTO) is often considered to ensure optimal plant operation and constraint ...

EPFL2019

Long-term evolution of solid oxide fuel and electrolysis cell 3-D microstructure

Giorgio Rinaldi

Solid oxide fuel cells (SOFC) are highly efficient electrochemical conversion devices for the production of electricity that combine fuel flexibility with low emissions of pollutants. The reverse operation in electrolysis mode (SOEC) allows storing electri ...

EPFL2019

Sustainable, Reshapable Surfactant-Polyelectrolyte Plastics Employing Water as a Plasticizer

Paul Joseph Dyson, Zhaofu Fei, Antoine Philippe Van Muyden, Zhangjun Huang, Haiyan Jia

Natural polymers such as those present in foods contain abundant noncovalent intra- and intermolecular interactions, notably hydrogen bonds, which make them rigid when dry, but on exposure to water soften, due to disruption of these interactions. This soft ...

2019

Selecting the best AOP for isoxazolyl penicillins degradation as a function of water characteristics: Effects of pH, chemical nature of additives and pollutant concentration

César Pulgarin

To provide new insights toward the selection of the most suitable AOP for isoxazolyl penicillins elimination, the degradation of dicloxacillin, a isoxazolyl penicillin model, was studied using different advanced oxidation processes (AOPs): ultrasound (US), ...

Elsevier2017

Data Science Based Mg Corrosion Engineering

Félix Benedito Clément Musil, Robert Horst Meissner

Magnesium exhibits a high potential for a variety of applications in areas such as transport, energy and medicine. However, untreated magnesium alloys are prone to corrosion, restricting their practical application. Therefore, it is necessary to develop ne ...

2019