Photogeneration of Hydrogen: Insights from a Pt(II)-Complex Incorporated into a Covalent Organic Framework

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We introduce a new approach to defect engineering in Zr-based metal-organic frameworks (Zr-MOFs), aiming to reduce Zr site valency while preserving high node connectivity. Using a rapid heat treatment (RHT) in humid air, oxygen vacancies (O-vacancies) were ...

Hydrogen generated during the waterside corrosion of zirconium claddings can diffuse within the material, forming hydrides that alter the mechanical properties of the claddings. These hydrides may lead to detrimental effects such as delayed hydride crackin ...

Cyclopropanes have emerged as powerful C3 building blocks in organic synthesis. Cyclopropanes serve as precursors to generate reactive intermediates in various total syntheses of natural products and bioactive molecules. Several strategies have been develo ...

An amplitude analysis of the Ds1(2460)+→Ds+π+π- transition is performed simultaneously in B0→D-Ds+π+π-, B+→D¯0Ds+π+π-, and B0→D*-Ds+π+π- decays. The study is based on a data sample of proton-proton collisions recorded with the LHCb detector at centre-of-ma ...

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The effect of the simultaneous presence of fluoride (0.15-1.2 mg L-1), bicarbonates (83.6-596 mg L-1), and synthesized goethite (0.3 mg L-1) at typical concentrations often found in groundwater samples was evaluated on the degradation of 2,4-dichlorophenox ...

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The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

Photogeneration of Hydrogen: Insights from a Pt(II)-Complex Incorporated into a Covalent Organic Framework

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