Benefiting from the Unique Properties of Lanthanide Ions

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Purpose: Although clinical 7T MRI offers various advantages compared to lower field strengths, achieving spatially uniform flip angle distributions remains a challenge. Sampling Perfection with Application optimized Contrast using different flip angle Evol ...

Building on recent advances of the embedded cluster approach combined with multiconfigurational theory, this work investigates the electronic states in thorium-doped CaF2 crystals. Th:CaF2 is established as a promising material for solid-state nuclear cloc ...

The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

Cancer is among the leading causes of death worldwide, and as knowledge of the disease continues to grow there is an increasing interest towards precision medicine: more specifically towards the theranostics field, i.e the development of targeted molecular ...

We investigate the magnetic order in single crystalline EuCd2Sb2 thin films using a combined theoretical and experimental approach. Resonant elastic x-ray scattering experiments reveal a sharp magnetic peak at q=(0,0,12) below TN=7.2 K, indicative of inter ...

Superlattice formation afforded by metal halide perovskite nanocrystals has been a phenomenon of interest due to the high structural order induced in these self-assemblies, an order that is influenced by the surface chemistry and particle morphology of the ...

A promising modality of radiation therapy is FLASH: a technique in which the full radiation dose is delivered in just 1/10th of a second. This modality has been proven successful in destroying cancerous cells while sparing healthy tissues. The aim is to de ...

A dinuclear metal-organic cage with four acrylate side chains was prepared by self-assembly. Precipitation polymerization of the cage with N-isopropylacrylamide yielded a thermoresponsive nanogel. The host properties of the cage were retained within the ge ...

Lanthanides are versatile modulators of optoelectronic properties owing to their narrow optical emission spectra across the visible and near-infrared range. Their use in metal halide perovskites (MHPs) has recently gained prominence, although their fate in ...

Control of nanomaterial dimensions with atomic precision through synthetic methods is essential to understanding and engineering of nanomaterials. For single-layer inorganic materials, size and shape controls have been achieved by self-assembly and surface ...

Understanding and manipulating emergent phases, which are themes at the forefront of quantummaterials research, rely on identifying their underlying symmetries. This general principle has been particularly prominent in materials with coupled electronic and ...

This thesis investigates the magnetic properties of single atoms and molecules adsorbed on thin magnesium oxide decoupling layers, grown on a silver single crystal. To address these systems experimentally, we use a low temperature scanning tunneling micros ...

Magnetostriction results from the coupling between magnetic and elastic degrees of freedom. Though it is associated with a relatively small energy, we show that it plays an important role in determining the site of an implanted muon, so that the energetica ...

We have performed electrochemical treatment of the van der Waals antiferromagnetic materials FePS3 and NiPS3 with the ionic liquid EMIM-BF4, achieving significant molecular intercalation. Mass analysis of the intercalated compounds, EMIMx-FePS3 and EMIMx-N ...

Stabilizing liquid-liquid interfaces, whether between miscible or immiscible liquids, is crucial for a wide range of applications, including energy storage, microreactors, and biomimetic structures. In this study, a versatile approach for stabilizing the w ...

Nature provides a wide range of self-assembled structures from the nanoscale to the macroscale. Under the right thermodynamic conditions and with the appropriate material supply, structures like stalactites, icicles, and corals can grow. However, the natur ...

LiReF

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("Re" stands for the rare-earth element) and their doped derivatives have long been recognized as a family of compounds that exhibit rich phenomena in quantum magnetism, drawing wide attention to them from both fundamental researchers and industr ...

The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

Biomimetic retinas with a wide field of view and high resolution are in demand for neuroprosthetics and robot vision. Conventional neural prostheses are manufactured outside the application area and implanted as a complete device using invasive surgery. He ...

Supramolecular self-assembly in water based on non-covalent bonding is attracting major attention due to the potential of hydrogels and aqueous polymers in biomedical applications. Although supramolecular polymerization in organic solvents is well establis ...

Benefiting from the Unique Properties of Lanthanide Ions

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Individually optimized dynamic parallel transmit pulses for 3D high‐resolution SPACE imaging at 7T

Embedded cluster approach for accurate electronic structure calculations of 229Th:CaF2

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Functionalization of harmonic nanoparticles for drug release and multimodal imaging applications

Magnetic structure of a single-crystal thin film of EuCd2Sb2

Long live(d) CsPbBr3 superlattices: colloidal atomic layer deposition for structural stability

Design of a Beam Separator for FLASH Electron Therapy Facilities

Nanogels with Metal‐Organic Cages as Functional Crosslinks

Speciation of Lanthanide Metal Ion Dopants in Microcrystalline All-Inorganic Halide Perovskite CsPbCl3

Controlled Formation of Nanoribbons and Their Heterostructures via Assembly of Mass-Selected Inorganic Ions

Multimodal Approach Reveals the Symmetry-Breaking Pathway to the Broken Helix in EuIn2As2

Magnetism of Single Surface Adsorbed Atoms Studied with Radio-Frequency STM

Magnetostriction-Driven Muon Localization in an Antiferromagnetic Oxide

Molecular intercalation in the van der Waals antiferromagnets FePS3 and NiPS3

A Versatile Approach to Stabilize Liquid-Liquid Interfaces using Surfactant Self-Assembly

Nature-Inspired Stalactite Nanopores for Biosensing and Energy Harvesting

Investigation of Electro-Nuclear Spin States in LiHoF4 Using Cavity-Magnon-Polariton Technique

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Colloidal self-assembly of soft neural interfaces from injectable photovoltaic microdevices

Mechanistic Insight into Supramolecular Polymerization in Water Tunable by Molecular Geometry