Publications associées à ELECTROWETTING Shake, rattle and roll

Publications associées (36)

Ion Transport at Polymer-Argyrodite Interfaces

Solid-state electrolytes, particularly polymer/ceramic composite electrolytes, are emerging as promising candidates for lithium-ion batteries due to their high ionic conductivity and mechanical flexibility. The interfaces that arise between the inorganic a ...

2024

Contrasting Views of the Electric Double Layer in Electrochemical CO2 Reduction: Continuum Models vs Molecular Dynamics

Sophia Haussener, Evan Fair Johnson

In the field of electrochemical CO2 reduction, both continuum models and molecular dynamics (MD) models have been used to understand the electric double layer (EDL). MD often focuses on the region within a few nm of the electrode, while continuum models ca ...

Amer Chemical Soc2024

Dynamic Behavior of Spatially Confined Sn Clusters and Its Application in Highly Efficient Sodium Storage with High Initial Coulombic Efficiency

Lei Zhang, Kumar Varoon Agrawal, Kangning Zhao

Advanced battery electrodes require a cautious design of microscale particles with built-in nanoscale features to exploit the advantages of both micro- and nano-particles relative to their performance attributes. Herein, the dynamic behavior of nanosized S ...

Wiley-V C H Verlag Gmbh2024

Operando Observation of (Bi)carbonate Precipitation during Electrochemical CO2 Reduction in Strongly Acidic Electrolytes

Corsin Battaglia, Alessandro Senocrate, Nukorn Plainpan

Precipitation of (bi)carbonate salts during the electrochemical CO2 reduction (CO2RR) has been identified as a major cause of degradation and one of the main challenges to be overcome before implementing this technology on the industrial scale. Recently, t ...

Amer Chemical Soc2024

Mechanism of Charge Transport in Lithium Thiophosphate

Michele Ceriotti, Federico Grasselli, Davide Tisi, Lorenzo Gigli

Lithium ortho-thiophosphate (Li3PS4) has emerged as a promising candidate for solid-state electrolyte batteries, thanks to its highly conductive phases, cheap components, and large electrochemical stability range. Nonetheless, the microscopic mechanisms of ...

2024

Surface Charge Boundary Condition Often Misused in CO2 Reduction Models

Sophia Haussener, Etienne Boutin, Evan Fair Johnson

The Poisson-Nernst-Planck equations have been used to model species transport in electrochemical CO2 reduction, where the surface charge boundary condition accounts for the potential drop across the Stern layer. A direct comparison of the published models ...

AMER CHEMICAL SOC2023

Pathways to enhance electrochemical CO2 reduction identified through direct pore-level modeling

Sophia Haussener, Etienne Boutin, Shuo Liu, Evan Fair Johnson

Electrochemical conversion of CO2 to fuels and valuable products is one pathway to reduce CO2 emissions. Electrolyzers using gas diffusion electrodes (GDEs) show much higher current densities than aqueous phase electrolyzers, yet models for multi-physical ...

2023

Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries

Mounir Driss Mensi

Fluorination of solvents, useful for non-aqueous lithium-based batteries, improves the electrochemical stability but decreases the ionic conductivity. Here, the authors report a targeted functionalization of an ether solvent to balance the electrolyte ioni ...

Nature Portfolio2023

Operando Electrochemical Liquid Cell Scanning Transmission Electron Microscopy Investigation of the Growth and Evolution of the Mosaic Solid Electrolyte Interphase for Lithium-Ion Batteries

Corsin Battaglia

The solid electrolyte interphase (SEI) is a key component of a lithium-ion battery forming during the first few dischage/charge cycles at the interface between the anode and the electrolyte. The SEI passivates the anode-electrolyte interface by inhibiting ...

Amer Chemical Soc2023

In Liquido Computation with Electrochemical Transistors and Mixed Conductors for Intelligent Bioelectronics

Matteo Cucchi

Next-generation implantable computational devices require long-term-stable electronic components capable of operating in, and interacting with, electrolytic surroundings without being damaged. Organic electrochemical transistors (OECTs) emerged as fitting ...

Wiley-V C H Verlag Gmbh2023

High temperature electrolysis system and method

Demetri Psaltis, Pooria Hadikhani, Steven Alexandre Schenk, Sylvain Jacky Reinauer

The present invention concerns an electrolysis system for high temperature electrolysis including a plurality of flow-based electrolysis units configured to receive an electrolyte solution and to perform electrolysis to provide a first output gas and a sec ...

2023

Ionization Difference between Weak and Strong Electrolytes as Perturbed by Conductivity Spectra Analysis

Vasily Artemov

While the static structure of aqueous electrolytes has been studied for decades, their dynamic microscopic structure remains unresolved yet critical in many areas. We report a comparative study of dc and ac (1 Hz to 20 GHz) conductivity data of weak and st ...

AMER CHEMICAL SOC2022

Energy Level Alignment at the Cobalt Phosphate/Electrolyte Interface: Intrinsic Stability vs Interfacial Chemical Reactions in 5 V Lithium Ion Batteries

Nicola Marzari, Matteo Cococcioni

The intrinsic stability of the 5 V LiCoPO4-LiCo2P3O10 thin-film (carbon-free) cathode material coated with MoO3 thin layer is studied using a comprehensive synchrotron electron spectroscopy in situ approach combined with firstprinciple calculations. The at ...

AMER CHEMICAL SOC2022

On the design of solid-state Li-ion batteries

Nicola Marzari, Sokseiha Muy

A model for the electrical double layer at solid-state electrochemical interfaces is reported, shedding some light on the design and optimization of future all-solid-state Li-ion batteries. ...

SPRINGERNATURE2021

Tailored Double Emulsions Made Simple

Esther Amstad

Double emulsions, such as water-in-oil-in-water droplets, are important material platforms for conducting fundamental research and for technological applications. To date, well-defined double-emulsion droplets consisting of a single water core and a thin o ...

Wiley-V C H Verlag Gmbh2021

Perspective-Electrochemical Stability of Water-in-Salt Electrolytes

Corsin Battaglia, David Reber

The water-in-salt approach has expanded the electrochemical stability window of aqueous electrolytes, enabling novel aqueous batteries with relatively high cell voltages and energy densities. However, the stability of these electrolytes tends to be overest ...

2020

Aqueous electrolytes for high-voltage batteries and supercapacitors

David Reber

Lithium-ion batteries are widely implemented as energy storage devices due to their high energy density and low cost. They enabled modern portable electronics and electric ve-hicles, and are key to manage the integration of intermittent renewable electrici ...

EPFL2020

Electrochemical reactor

Demetri Psaltis, Seyyed Mohammad Hosseini Hashemi

In an electrochemical reactor (R) for producing oxygen and hydrogen by means of electrolysis of an electrolyte (16), wherein the electrochemical reactor (R) comprises a first electrode set (S) and wherein the first electrode set (S) comprises a first elect ...

2020

'Green' Cr(III)-based electrodeposition of stainless steel-like FeCrNi: synthesis, mechanisms, material properties of films and micro-nanocomponents for bio-medical applications

Enrico Bertero

The electrodeposition (ED) of stainless steel (SS) -like FeCrNi alloys for miniaturised devices is appealing for bio-medicine as it would allow combining excellent material properties (e.g. corrosion resistance, hardness, bio-compatibility) at low-cost. Ho ...

EPFL2020

A Blue Photosensitizer Realizing Efficient and Stable Green Solar Cells via Color Tuning by the Electrolyte

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Peng Wang, Yiming Cao, Yameng Ren, Dan Zhang

Semitransparent dye-sensitized solar cells (DSCs) are appealing as aesthetically pleasing and colorful see-through photovoltaics. Green semitransparent DSCs have been presented, but the best ones rely on green zinc porphyrin photosensitizers and high volat ...

Wiley-V C H Verlag Gmbh2020