Activation of Nitrous Oxide by Dinuclear Ruthenium Complexes

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Diazoolefins tend to be highly reactive compounds that rapidly lose dinitrogen. So far, most experimental evidence for diazoolefins is indirect, via trapping experiments. Here we show that diazoolefins are observed to form in reactions of N-heterocyclic ol ...

Clathrochelate complexes of cobalt are known in the oxidation states I, II, and III. Low-valent Co(I) complexes are highly reactive compounds, and there is only limited knowledge about their structures in the solid state. Herein, we describe the crystallog ...

Two pyrazole-based ligands bearing a pyridine moiety, 3-methyl-1-(pyridin-2-yl)-5-pyrazolone (HLpy), and 3methyl-1-(pyridin-2-yl)-4-trifluoroacetyl-5-pyrazolone (HQpy,CF3), were prepared and fully characterized in the solid-state and the tautomerism of bot ...

Metal-catalysed C-H bond functionalization has received tremendous attention and developed rapidly over the past decades. Cyclopentadienyl (Cp) metal complexes and their asymmetric counterparts (CpX) are part of a central organometallic category empowering ...

The activation of small molecules is a paramount challenge in modern chemistry. The use of cheap and abundant molecules such as N2, H2, CO2, or CO as energy supplies or as precursors for fine chemicals production is highly desirable. In particular, the onl ...

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Activation of Nitrous Oxide by Dinuclear Ruthenium Complexes

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Isolation and characterization of diazoolefins

Ligand Effects in Low-Valent Co(I) Clathrochelate Complexes

Arene-ruthenium(II) complexes with pyrazole-based ligands bearing a pyridine moiety: Synthesis, structure, DFT calculations, and cytotoxicity

Synthesis of Chiral Cyclopentadienyl Complexes and Applications Towards C-H Functionalization

Design, synthesis, reactivity, and magnetic properties of uranium based oxide and nitride complexes

Photo- and thermally-induced electronic and structural dynamics in perovskites and transition metal oxides

Half-clathrochelate Complexes as Versatile Links in Supramolecular Chemistry

Delivery of a Masked Uranium(II) by an Oxide-Bridged Diuranium(III) Complex

Optical absorption properties of metal-organic frameworks: solid stateversusmolecular perspective

Explaining the Advantageous Impact of Tertiary versus Secondary Nitrogen Center on the Activity of PNP-Pincer Co(I)-Complexes for Catalytic Hydrogenation of CO2

Structure-Property Relationships of Microphase-Separated Metallosupramolecular Polymers

Computational characterisation of the selectivity and binding mode of mono- and binuclear transition metal based anticancer compounds

Modular Chiral N-Heterocyclic Carbene Ligands for the Nickel-Catalyzed Enantioselective C-H Functionalization of Heterocycles

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