Publications associées à Single-site ruthenium catalyst supported on zeolite for CO<inf>2</inf> hydrogenation to methyl formate

Publications associées (20)

Low-Power Tunable Micro-Plasma Devices for Efficient and Scalable CO2 Conversion

CO2 conversion plays a vital role in addressing climate change by cutting greenhouse gas emissions and promoting a circular carbon economy. Rather than releasing carbon dioxide into the atmosphere, carbon dioxide recycling technologies allows transformatio ...

EPFL2025

Ionic Iridium-Catalyzed Hydrogenation of Pyridines

Arthur Rémi Despois

Catalytic hydrogenation stands out as a powerful tool for the atom-economical transformation of unsaturated systems. Nitrogen heterocycles are widespread in organic chemistry, they are found in many natural products and exhibit notable biological activitie ...

EPFL2025

Low CO2 mass transfer promotes methanol and formaldehyde electrosynthesis on cobalt phthalocyanine

Liping Zhong, Thi Ha My Pham

Cobalt phthalocyanine supported on carbon nanotubes (CoPcCNT) usually catalyzes the electroreduction of CO2 (CO2RR) to CO, although several reports have also indicated methanol formation. Herein, by analyzing the effects of CoPc loading and CO2 partial pre ...

Royal Society of Chemistry2024

Inverse design of metal-organic frameworks for direct air capture of CO2via deep reinforcement learning

Berend Smit, Sauradeep Majumdar, Xiaoqi Zhang

The combination of several interesting characteristics makes metal-organic frameworks (MOFs) a highly sought-after class of nanomaterials for a broad range of applications like gas storage and separation, catalysis, drug delivery, and so on. However, the e ...

Royal Soc Chemistry2024

Electrochemical synthesis of propylene from carbon dioxide on copper nanocrystals

Michael Graetzel, Shaik Mohammed Zakeeruddin, Oliver Kröcher, Dan Ren, Jing Gao, Alimohammad Bahmanpour

The conversion of carbon dioxide to value-added products using renewable electricity would potentially help to address current climate concerns. The electrochemical reduction of carbon dioxide to propylene, a critical feedstock, requires multiple C-C coupl ...

NATURE PORTFOLIO2023

Arctic tropospheric ozone: assessment of current knowledge and model performance

Jakob Boyd Pernov, Luca Pozzoli, Ilann Ernest Valentin Bourgeois

As the third most important greenhouse gas (GHG) after carbon dioxide (CO2) and methane (CH4), tropospheric ozone (O3) is also an air pollutant causing damage to human health and ecosystems. This study brings together recent research on observations and mo ...

Copernicus Publications2023

Development of C-C and C-O bond cleavage catalysts for the depolymerization of plastics

Wei-Tse Lee

Chemical recycling of plastics provides more flexibility for materials circulation than landfill disposal or incineration. Intensive research efforts have been devoted to maximizing the efficiency of chemical recycling through catalyst development. The fro ...

EPFL2022

Carbon dioxide activation and hydrogenation over copper-based catalysts studied by near-ambient pressure X-ray photoelectron spectroscopy

Mo Li

Carbon neutrality has been proposed as a commitment by the international communities for the well-being of human. To achieve carbon neutrality, one practical approach is to synthesize fuels and chemicals through CO2 hydrogenation to replace fossil fuels. C ...

EPFL2021

Silica-copper catalyst interfaces enable carbon-carbon coupling towards ethylene electrosynthesis

Michael Graetzel, Dan Ren, Yelin Hu, Jun Li, Reza Zamani

Membrane electrode assembly (MEA) electrolyzers offer a means to scale up CO2-to-ethylene electroconversion using renewable electricity and close the anthropogenic carbon cycle. To date, excessive CO2 coverage at the catalyst surface with limited active si ...

Nature Research2021

Atomic-Step Enriched Ruthenium-Iridium Nanocrystals Anchored Homogeneously on MOF-Derived Support for Efficient and Stable Oxygen Evolution in Acidic and Neutral Media

Vasiliki Tileli, Bo Li, Junjie Li

Achieving an efficient and stable oxygen evolution reaction (OER) in an acidic or neutral medium is of paramount importance for hydrogen production via proton exchange membrane water electrolysis (PEM-WE). Supported iridium-based nanoparticles (NPs) are th ...

AMER CHEMICAL SOC2021

Micro-Electrode with Fast Mass Transport for Enhancing Selectivity of Carbonaceous Products in Electrochemical CO2 Reduction

Michael Graetzel, Mingkui Wang, Jingshan Luo, Dan Ren

During electrochemical carbon dioxide (CO2) reduction on copper electrodes in an aqueous electrolyte, one of the key challenges is the competition between hydrogen evolution and CO2 reduction, especially under large current density. Here, micro-electrodes ...

2021

Gold-in-copper at low *CO coverage enables efficient electromethanation of CO2

Michael Graetzel, Dan Ren, Jun Li

The renewable-electricity-powered CO2 electroreduction reaction provides a promising means to store intermittent renewable energy in the form of valuable chemicals and dispatchable fuels. Renewable methane produced using CO2 electroreduction attracts inter ...

Nature Research2021

Enhanced Visible-Light-Driven Hydrogen Production through MOF/MOF Heterojunctions

Berend Smit, Kyriakos Stylianou, Pascal Alexander Schouwink, Christopher Patrick Ireland, Maria Fumanal Quintana, Stavroula Kampouri, Fatmah Ebrahim

A strategy for enhancing the photocatalytic performance of MOF- based systems (MOF: metal-organic framework) is developed through the construction of MOF/MOF heterojunctions. The combination of MIL-167 with MIL-125-NH2 leads to the formation of MIL-167/MIL ...

2021

A semiconducting polymer bulk heterojunction photoanode for solar water oxidation

Kevin Sivula, Jun Ho Yum, Liang Yao, Nestor Guijarro Carratala, Yongpeng Liu, Florent Alexandre Boudoire, Arvindh Sekar, Rebekah Anne Wells, Han-Hee Cho

Organic semiconductors hold promise to enable scalable, low-cost and high-performance artificial photosynthesis. However, the performance of systems based on organic semiconductors for light-driven water oxidation have remained poor compared with inorganic ...

NATURE RESEARCH2021

Operando diffuse reflectance infrared detection of cyanide intermediate species during the reaction of formaldehyde with ammonia over V2O(5)/ WO3-TiO2

Oliver Kröcher, Davide Ferri, Rob Jeremiah G. Nuguid

Hydrogen cyanide (HCN) is a highly poisonous gas that can form through the reaction between formaldehyde and ammonia (NH3) in the exhaust. While this detrimental side reaction has been the subject of recent catalytic studies under selective catalytic reduc ...

ELSEVIER2021

Flow boiling heat transfer and two-phase flow phenomena of CO2 in macro-and micro-channel evaporators: Fundamentals, applications and engineering design

John Richard Thome

The paper presents a comprehensive review of fundamentals and engineering applications of CO2 flow boiling heat transfer, flow patterns and two-phase pressure drops in macro- and micro-channel evaporators. First, distinctions of macro- and micro-channels a ...

PERGAMON-ELSEVIER SCIENCE LTD2021

Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds

Athanasios Nenes

The acidity of aqueous atmospheric solutions is a key parameter driving both the partitioning of semi-volatile acidic and basic trace gases and their aqueous-phase chemistry. In addition, the acidity of atmospheric aqueous phases, e.g., deliquesced aerosol ...

Copernicus GmbH2021

Nanocrystals as Precursors in Solid-State Reactions for Size- and Shape-Controlled Polyelemental Nanomaterials

Raffaella Buonsanti, Emad Oveisi, Anna Loiudice, Laia Castilla Amorós, Dragos-Constantin Stoian, Valeria Mantella, Chethana Janardhana Gadiyar, Pranit Srinivas Iyengar

Solid-state reactions between micrometer-size powders are among the oldest, simplest, and still widely used methods for the fabrication of inorganic solids. These reactions are intrinsically slow because, although the precursorsare "well mixed" at the macr ...

AMER CHEMICAL SOC2020

Catalyst Evolution Enhances Production of Xylitol from Acetal-Stabilized Xylose

Jeremy Luterbacher, Benjamin Pierre Le Monnier, Masoud Talebi Amiri, Ydna Marie Questell-Santiago, Jher Hau Yeap

We demonstrate a catalytic process for xylitol production based on the volatility and unique reactivity of diformylxylose (DFX), which can be produced at near theoretical yield from biomass and, contrary to xylose, can be easily purified by distillation. T ...

2020

Where does the river end? Drivers of spatiotemporal variability in CO2 concentration and flux in the inflow area of a large boreal lake

Natacha Pasche, Hannah Elisa Chmiel

River inflow affects the spatiotemporal variability of carbon dioxide (CO2) in the water column of lakes and may locally influence CO2 gas exchange with the atmosphere. However, spatiotemporal CO2 variability at river inflow sites is often unknown leaving ...

American Society of Limnology and Oceanography2020