Publications associées à Interfacial engineering from material to solvent: A mechanistic understanding on stabilizing alpha-formamidinium lead triiodide perovskite photovoltaics

Publications associées (20)

Hybrid organic/metal-oxide shells on semiconductor nanocrystals via colloidal atomic layer deposition

The escalating energy demand and the imperative necessity to reduce the carbon footprint require transformative approaches to energy conversion. Materials chemistry plays a pivotal role in addressing these global challenges by developing novel materials fo ...

EPFL2024

Mitigating Ion Migration with an Ultrathin Self-Assembled Ionic Insulating Layer Affords Efficient and Stable Wide-Bandgap Inverted Perovskite Solar Cells

Paul Joseph Dyson, Yanyan Fang

Wide-bandgap perovskite solar cells (PSCs) are attracting increasing attention because they play an irreplaceable role in tandem solar cells. Nevertheless, wide-bandgap PSCs suffer large open-circuit voltage (V-OC) loss and instability due to photoinduced ...

WILEY-V C H VERLAG GMBH2023

Large Orbital Moment of Two Coupled Spin-Half Co Ions in a Complex on Gold

Stefano Rusponi, Chao Li, Boris Sorokin

The magnetic propertiesof transition-metal ions aregenerallydescribed by the atomic spins of the ions and their exchange coupling.The orbital moment, usually largely quenched due the ligand field,is then seen as a perturbation. In such a scheme, S = 1/2 io ...

AMER CHEMICAL SOC2023

Ion Selective and Water Resistant Cellulose Nanofiber/MXene Membrane Enabled Cycling Zn Anode at High Currents

Kangning Zhao

Aqueous rechargeable zinc ion batteries (ZIBs) are regarded as a promising candidates for next-generation energy storage devices but strongly hindered by the limited utilization of the zinc metal anode (below 5%) due to the active water/anion corrosion. He ...

WILEY-V C H VERLAG GMBH2023

The Three-Phase Contact Potential Difference Modulates the Water Surface Charge

Aleksandra Radenovic, Andrei Kiselev, Vasily Artemov

The surface charge of an open water surface is crucialfor solvationphenomena and interfacial processes in aqueous systems. However, themagnitude of the charge is controversial, and the physical mechanismof charging remains incompletely understood. Here we ...

AMER CHEMICAL SOC2023

Investigation of nickel iron layered double hydroxide for water oxidation in different pH electrolytes

Michael Graetzel, Dan Ren, Lichen Bai

Nickel iron layered double hydroxide (NiFe LDH) is one of the best oxygen evolution reaction (OER) catalysts in alkaline electrolytes. However, it performs poorly in neutral electrolytes, and the detailed mechanism is still unclear. Herein, we introduce el ...

ELSEVIER2023

Folding the Energy Storage: Beyond the Limit of Areal Energy Density of Micro-Supercapacitors

Minkyung Kim

Despite the ever-growing interest in micro-supercapacitors (MSCs) as a promising power source for microelectronics, their low areal energy density has plagued practical applications. Herein, accordion foldable MSCs (af-MSCs) are presented as a cell archite ...

WILEY-V C H VERLAG GMBH2023

A Multiconfigurational Wave Function Implementation of the Frenkel Exciton Model for Molecular Aggregates

Francesco Aquilante

We present an implementation of the Frenkel exciton model into the OpenMolcas program package enabling calculations of collective electronic excited states of molecular aggregates based on a multiconfigurational wave function description of the individual ...

AMER CHEMICAL SOC2023

Silica aerogel as rear reflector in silicon heterojunction solar cells for improved infrared response

Deniz Türkay

Silicon (Si), with its indirect bandgap, is a non-ideal absorber. Thus, various strategies to boost silicon solar cells' efficiency, including advanced texturing, multilayer anti-reflecting coating, and rear reflectors are utilized. Dielectrics, deposited ...

ELSEVIER2023

An experimental and theoretical investigation of the N(D-2) + C6H6 (benzene) reaction with implications for the photochemical models of Titan

Adriana Caracciolo

We report on a combined experimental and theoretical investigation of the N(D-2) + C6H6 (benzene) reaction, which is of relevance in the aromatic chemistry of the atmosphere of Titan. Experimentally, the reaction was studied (i) under single-collision cond ...

ROYAL SOC CHEMISTRY2023

Stability and Reactivity of a Polyoxymethylene Dimethyl Ether over Typical Catalysts for Diesel Emission Control (vol 15, pg 848, 2022)

Oliver Kröcher, Davide Ferri

SPRINGER/PLENUM PUBLISHERS2023

Ultrafast Energy Transfer from Photoexcited Tryptophan to the Haem in Cytochrome c

Majed Chergui, Giulia Fulvia Mancini, Oliviero Cannelli, Dominik Kinschel, Camila Bacellar Cases Da Silveira, Jérémy Raymond Jean Maurice Rouxel, Yang Zhao, Rebecca Ann Ingle

: We report femtosecond Fe K-edge absorption (XAS) and nonresonant X-ray emission (XES) spectra of ferric cytochrome C (Cyt c) upon excitation of the haem (>300 nm) or mixed excitation of the haem and tryptophan (

2023

Thermoplastic Toughening of a Semiaromatic Polyamide with an Amino-telechelic Polyethylene

John Christopher Plummer, Holger Frauenrath, Michael Alan Giffin

Semiaromatic polyamides are used for metal replacementin advancedengineering applications to reduce weight and improve efficiency,but their range of application is limited by their inherent lack ofductility and toughness. Here, we combined semiaromatic pol ...

AMER CHEMICAL SOC2023

Towards high-throughput many-body perturbation theory: efficient algorithms and automated workflows

Giovanni Pizzi, Antimo Marrazzo, Junfeng Qiao

The automation of ab initio simulations is essential in view of performing high-throughput (HT) computational screenings oriented to the discovery of novel materials with desired physical properties. In this work, we propose algorithms and implementations ...

NATURE PORTFOLIO2023

Loss Analysis of a 24.4%-Efficient Front-Junction Silicon Heterojunction Solar Cell and Opportunity for Localized Contacts

Christophe Ballif, Mathieu Gérard Boccard, Luca Massimiliano Antognini, Jean Cattin, Julie Amandine Dreon, Vincent Philippe Paratte, Deniz Türkay

Silicon heterojunction (SHJ) solar cells have recently reached power conversion efficiencies above 25% with various device architectures and with industrial size (>200 cm(2)) wafers. Yet, for an accurate assessment of the efficiency potential and further d ...

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2023

Below the Urbach Edge: Solar Cell Loss Analysis Based on Full External Quantum Efficiency Spectra

Stefaan De Wolf, Jakub Holovsky, Xin Yu Chin

We suggest a new solar cell loss analysis using theexternal quantumefficiency (EQE) measured with sufficiently high sensitivity to alsoaccount for defects. Unlike common radiative-limit methods, wherethe impact of deep defects is ignored by exponential ext ...

AMER CHEMICAL SOC2023

Double Layer Composite Electrode Strategy for Efficient Perovskite Solar Cells with Excellent Reverse-Bias Stability

Michael Graetzel

Perovskite solar cells (PSCs) have become the representatives of next generation of photovoltaics; nevertheless, their stability is insufficient for large scale deployment, particularly the reverse bias stability. Here, we propose a transparent conducting ...

2023

Local Temperature Increments and Induced Cell Death in Intracellular Magnetic Hyperthermia

Débora Bonvin

The generation of temperature gradients on nanoparticles heated externally by a magnetic field is crucially important in magnetic hyperthermia therapy. But the intrinsic low heat i n g power of magnetic nanoparticles, at the conditions allowed for human us ...

AMER CHEMICAL SOC2023

Unraveling the Electrochemical Electrode Coupling in Integrated Organic Electrochemical Transistors

Matteo Cucchi

Organic electrochemical transistors (OECTs) have gained enormous attention due to their potential for bioelectronics and neuromorphic computing. However, their implementation into real-world applications is still impeded by a lack of understanding of the c ...

WILEY-V C H VERLAG GMBH2023

Light-Induced Halide Segregation in 2D and Quasi-2D Mixed-Halide Perovskites

David Lyndon Emsley, Aditya Mishra, Manuel Cordova, Michael Allan Hope

Photoinduced halide segregation hinders widespread application of three-dimensional (3D) mixed-halide perovskites. Much less is known about this phenomenon in lower-dimensional systems. Here, we study photoinduced halide segregation in lower-dimensional mi ...

AMER CHEMICAL SOC2023