Silicon heterojunction (SHJ) solar cells have recently reached power conversion efficiencies above 25% with various device architectures and with industrial size (>200 cm(2)) wafers. Yet, for an accurate assessment of the efficiency potential and further development of the technology, the identification of high-performing device configurations, and their detailed analysis is still vital. In this work, we first present an overview of our lab-scale (4 cm(2)) front-junction cells based on n-type wafers with a 24.44% certified efficiency. We report on the key improvements compared with our previously reported devices (i.e., thinner front-side silicon layers and low refractive index rear reflector). Then, we present a detailed power loss analysis, showing that parasitic absorption in the front layer-stack remains a major source of loss despite the recent improvements. Accordingly, we investigate next approaches to circumvent this loss, such as localization of the highly absorbing front layers and switching to a rear-junction architecture. Using numerical calculations, we show that the front-junction configuration can benefit from an efficiency gain of 0.3%(abs) with contact localization if considerably low contact resistivities (
Christophe Ballif, Antonin Faes, Christian Michael Wolff, Marion Solange Madeleine Dussouillez
Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Virginia Carnevali, Nikolaos Lempesis, Mingyang Wei, Vladislav Slama, Lorenzo Agosta
Michael Graetzel, Shaik Mohammed Zakeeruddin, Likai Zheng, Mingyang Wei