Publications associées à Hydration and phase assemblage of limestone calcined clay cements (LC3) with clinker content below 50 %

Publications associées (24)

Investigating the ball-milled calcined coal gangue on the hydration of limestone blended cement

Calcined coal gangue (CCG) exhibits promising application potential in limestone-cement binary binders. However, the activity of CCG would possibly be weakened due to the particle agglomeration after calcination. In the present research, we tried to overco ...

2025

CementFF4: Formal atomic charge polarizable force field for cementitious systems – Bulk and surface

Tecla Bottinelli Montandon, Karen Scrivener, Paul Bowen, Manuel Cordova, Ziga Casar

A general-purpose formal charge polarizable force field for cementitious systems, CementFF4, is presented. The force field includes the following species: Ca, Si, O, H, Al, Zn, OH− and H2O. The force field is a significant extension of previous force field ...

Pergamon-Elsevier Science Ltd2025

Kinetics of Al uptake in synthetic calcium silicate hydrate (C-S-H)

Karen Scrivener

The effect of equilibration time on the composition, structure and solubility of calcium aluminate silicate hydrate (C-A-S-H) was investigated in 0.5 M NaOH solutions at Al/Si = 0.1. Longer equilibration time led to longer silica chains, to less Na and, to ...

Pergamon-Elsevier Science Ltd2023

Multi-scale investigation on mechanical behavior and microstructural alteration of C-S-H in carbonated Alite paste

Karen Scrivener

Carbonation treatment is a promising option to enhance recycled concrete aggregate (RCA) quality and eventually improve concrete performance. This study investigated the multi-scale mechanical properties of calcium silicate hydrates (C-S-H) in a mature ali ...

Pergamon-Elsevier Science Ltd2021

The Influence of some calcined clays from Nigeria as clinker substitute in cementitious systems

Karen Scrivener, François Henri Avet

This paper examines the possibility of the use of some clays calcined from Nigeria as partial substitutes for clinker in the production of Limestone Calcined Clay Cement (LC3). The clays were calcined in the oven at a temperature of 800 degrees C and for o ...

2020

Hydration development and thermal performance of calcium sulphoaluminate cements containing microencapsulated phase change materials

Diana Londoño Zuluaga

Microencapsulated phase change materials (MPCM) incorporated in buildings walls can reduce indoor temperature fluctuations, conserving energy and enhancing thermal comfort. MPCM were incorporated in calcium sulphoaluminate cement (CSA) at high concentratio ...

Pergamon-Elsevier Science Ltd2020

Factors influencing the sulfate balance in pure phase C3S/C(3)A systems

Karen Scrivener, Franco Alberto Zunino Sommariva

Understanding the sulfate balance mechanism of cement is needed for an effective use of sustainable blended cements. Pure phase systems allow to study the interaction between sulfate and each of the phases involved in early age hydration separately. This p ...

Pergamon-Elsevier Science Ltd2020

Effect of temperature on the water content of C-A-S-H in plain Portland and blended cements

Karen Scrivener, François Henri Avet

This study aims to investigate the change with temperature of the water content of the C-(A)-S-H of plain cement (PC) and Limestone Calcined Clay Cement (LC3). The water content was determined by various methods: thermogravimetric analysis (TGA), H-1-nucle ...

Pergamon-Elsevier Science Ltd2020

Quantification methods for chloride binding in Portland cement and limestone systems

Wei Sun, Karen Scrivener, Fabien Jacques Michel Georget, Hamed Maraghechi, William Wilson, Shiyu Sui

This paper presents a comparison of methods to quantify the chloride binding capacity for cementitious materials composed of Ordinary Portland Cement (OPC) and Limestone (LS, 0 to 55% replacement). Physical and chemical chloride bindings were investigated ...

Pergamon-Elsevier Science Ltd2019

Modeling the kinetics of the main peak and later age of alite hydration

Alexandre Reda Constantin William Caleb Ouzia

The aim of this thesis is to understand the mechanisms underlying the main hydration peak and later ages of alite hydration; it proposes new mechanistic models for these two stages. Alite is the main constituent of Portland Cement (PC), and is responsible ...

EPFL2019

Reactor Dynamics Investigation Based On Calorimetric Data

Thierry Meyer, Francis Stoessel, Michal Dabros, Charles Ibrahim Guinand

A simple and general procedure has been developed to determine the thermal behaviour of a reactor based on heat balance, PID temperature control, and jacket behaviour. Using only temperature heating/cooling ramps followed by isothermal stages, such a proce ...

Wiley-Blackwell2017

Force-displacement response of in-plane loaded URM walls with a dominating flexural mode

Katrin Beyer, Sarah Petry

This article presents a new mechanical model for the non-linear force-displacement response of unreinforced masonry (URM) walls developing a flexural rocking mode including their displacement capacity. The model is based on the plane section hypothesis and ...

2015

Degradation mechanism of slag blended mortars immersed in sodium sulfate solution

Wei Sun, Karen Scrivener

Additions of slag are usually considered to give cementitious materials which perform well in sulfate bearing environments. This paper compares the deterioration of slag cement blends to those of plain Portland cement and demonstrates that this occurs more ...

Pergamon-Elsevier Science Ltd2015

Stress Fields for the analysis of the faillure load and cracking state of dapped-end beams (Aplicación de modelos de campos de tensiones para el análisis en servicio y rotura de apoyos a media madera)

Jaime Mata Falcon, Aurelio Muttoni, Miguel Fernández Ruiz

The automatic generation of elastic-plastic stress fields (EPSF) for structural concrete members by means of the finite element method has been demonstrated as a suitable approach for the design and assessment of D regions. This methodology allows accounti ...

VI Congreso ACHE2014

Thermal Behavior of Methylammonium Lead-Trihalide Perovskite Photovoltaic Light Harvesters

Michael Graetzel, Mohammad Khaja Nazeeruddin, Peng Gao, Peng Gao, Amalie Dualeh

Recently organicinorganic hybrid perovskites have attracted attention as light harvesting materials in mesoscopic cells. While a considerable number of deposition and formation methods have been reported for the perovskite crystalline material, most involv ...

Amer Chemical Soc2014

Phase compositions and equilibria in the CaO-Al2O3-Fe2O3-SO3 system, for assemblages containing ye'elimite and ferrite Ca-2(Al,Fe)O-5

Karen Scrivener

Phase equilibria in the CaO-Al2O3-Fe2O3-SO3 system have been studied, mainly at 1325 degrees C. In particular the solid solution compositions of ye'elimite Ca-4(Al6O12)SO4 and brownmillerite (C-2(A,F)) phases have been analysed and used to estimate the com ...

Pergamon-Elsevier Science Ltd2013

Extent-based incremental identification of reaction systems using concentration and calorimetric measurements

Dominique Bonvin, Julien Léo Billeter, Sriniketh Srinivasan, Nirav Pravinbhai Bhatt

Extent-based Incremental Model Identification (IMI) uses the concept of extent of reaction and the integral method of parameter estimation to identify reaction kinetics from transient concentration measurements. This study proposes to incorporate calorimet ...

Elsevier2012

Extent-based incremental identification of reaction systems using concentration and calorimetric measurements

Dominique Bonvin, Julien Léo Billeter, Sriniketh Srinivasan

Extent-based incremental identification uses the concept of extents and the integral method of parameter estimation to identify reaction kinetics from concentration measurements. The approach is rather general and can be applied to open both homogeneous an ...

Elsevier Science Sa2012

Experimental DSC-based method to determine glass transition temperature during curing of structural adhesives

Thomas Keller, Anastasios Vassilopoulos, Omar Moussa

A new DSC-based experimental method to efficiently establish the glass transition temperature, Tg, vs. curing degree, α, relationship for structural adhesives was developed. The method approaches the continuous Tg-α relationship with a trilinear curve esta ...

Elsevier2012

Hydration of C(3)A-gypsum systems

Karen Scrivener, Alexandra Quennoz

Hydration of C(3)A-gypsum systems with different gypsum additions was investigated in terms of the phase assemblage, kinetics and microstructural development. The second stage of the reaction, which begins after the depletion of gypsum, was of particular i ...

Pergamon-Elsevier Science Ltd2012