Publications associées à Critical light instability in CB/DIO processed PBDTTT-EFT:PC71BM organic photovoltaic devices

Publications associées (44)

Tuning Electronic and Optical Properties of 2D/3D Interfaces of Hybrid Perovskites through Interfacial Charge Transfer: Prediction of Higher-Efficiency Interface Solar Cells Using Hybrid-DFT Methods

The 2D/3D or 2D/quasi-2D composite mixed-dimensional construction of hybrid perovskite interfaces is gaining increasing attention due to their enhanced stability toward degradation without compromising the corresponding solar cell efficiency. Much of this ...

AMER CHEMICAL SOC2025

High‐Efficiency Sn‐Pb Perovskite Solar Cells via Nucleation and Crystallization Control

Mohammad Khaja Nazeeruddin

The rapid crystallization of mixed tin‐lead (Sn‐Pb) perovskites and their dependence on antisolvent processes limit the development of large‐area Sn‐Pb perovskite solar cells (PSCs). Vacuum‐flash‐assisted solution processing (VASP) has emerged as a promisi ...

Wiley2025

Buried Hole-selective Interface Engineering for High-efficiency Tin-lead Perovskite Solar Cells with Enhanced Interfacial Chemical Stability

Guixiang Li

Mixed Sn-Pb perovskites are attracting significant attention due to their narrow bandgap and consequent potential for all-perovskite tandem solar cells. However, the conventional hole transport materials can lead to band misalignment or induce degradation ...

ELSEVIER2025

Template-Assisted Growth of CsxFA1-xPbI3 with Pulsed Laser Deposition for Single Junction Perovskite Solar Cells

Christian Michael Wolff, Kerem Artuk

Cesium-formamidinium lead iodide (CsxFA1-xPbI3) perovskites are a promising methylammonium-free alternative for efficient single-junction solar cells. However, they have not been fully explored by vapor-phase deposition techniques. Herein, a template-assis ...

2025

Enhancing Indoor Photovoltaic Eﬃciency to 37.6% Through Triple Passivation Reassembly and n-Type to p-Type Modulation in Wide Bandgap Perovskites

Michael Graetzel, Lukas Pfeifer

Despite well‐matching indoor illumination spectra, the performance of wide bandgap perovskite solar cells (WB‐PSCs) for indoor photovoltaics (i‐PV) is hindered by photo‐induced halide phase segregation and trap‐assisted non‐radiative recombination. Herein, ...

Wiley2025

Efficient Polycrystalline Single-Cation Perovskite Light-Emitting Diodes by Simultaneous Intracrystal and Interfacial Defect Passivation

Mohammad Khaja Nazeeruddin, Emad Oveisi

Polycrystalline perovskite light-emitting diodes (PeLEDs) have shown great promise with high efficiency and easy processability. However, PeLEDs using single-cation polycrystalline perovskite emitters have demonstrated low efficiency due to defects within ...

2025

Computational Studies on the Stability of Organic-Inorganic Hybrid Halide Lead Perovskites

Mathias Dankl

Perovskite-based solar cells are currently the most rapidly advancing photovoltaic technology but concerns about their long-term stability are still impeding full-scale commercialization. This thesis provides computational insights into some of the stabili ...

EPFL2024

Integration of Metal Meshes as Transparent Conducting Electrodes into Perovskite Solar Cells

Andreas Schueler, Jérémy Jacques Antonin Fleury, René Uwe Schneider, Jakob Heier, Chiara Ongaro

As the demand for photovoltaic technologies continues to grow, the quest for efficient and sustainable transparent conducting electrodes (TCEs) rapidly rises. Traditional solutions, such as indium tin oxide (ITO), face challenges related to indium scarcity ...

Wiley2024

Synergistic Redox Modulation for High-Performance Nickel Oxide-Based Inverted Perovskite Solar Modules

Mohammad Khaja Nazeeruddin, Bin Ding, Xianfu Zhang

Nickel oxide (NiOx)-based inverted perovskite solar cells stand as promising candidates for advancing perovskite photovoltaics towards commercialization, leveraging their remarkable stability, scalability, and cost-effectiveness. However, the interfacial r ...

Wiley2024

Investigating Non-equilibrium Physics in Wide Bandgap Semiconductors and Quantum Materials via Ultrafast Spectroscopy

Hui-Yuan Chen

This thesis uses femtosecond laser spectroscopy in studying strong correlation in condensed matters that are pertinent to future technology: a wide bandgap perovskite and a quantum material, with the employment of ultrafast time-resolved spectroscopy in th ...

EPFL2024

Multifunctional sulfonium-based treatment for perovskite solar cells with less than 1% efficiency loss over 4,500-h operational stability tests

Ulf Anders Hagfeldt, Bowen Yang, Jiajia Suo, Yeonju Kim

The stabilization of grain boundaries and surfaces of the perovskite layer is critical to extend the durability of perovskite solar cells. Here we introduced a sulfonium-based molecule, dimethylphenethylsulfonium iodide (DMPESI), for the post-deposition tr ...

Nature Portfolio2024

Shortwave Infrared-Sensitive, Narrowband Organic Upconversion Devices with a Gain

Wei-Hsu Hu

Sensing and imaging of light in the shortwave infrared (SWIR) range is increasingly used in various fields, including bio-imaging, remote sensing, and semiconductor process control. SWIR-sensitive organic photodetectors (OPDs) are promising because organic ...

EPFL2024

Infrared-reflective ultrathin-metal-film-based transparent electrode with ultralow optical loss for high efficiency in solar cells

Michael Graetzel, Georgios Kakavelakis

In this work we study in-depth the antireflection and filtering properties of ultrathin-metal-film-based transparent electrodes (MTEs) integrated in thin-film solar cells. Based on numerical optimization of the MTE design and the experimental characterizat ...

Nature Portfolio2024

Anomalous Electroluminescence Characteristics of Perovskite Modules

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson

Spatially resolved photoluminescence (PL) and electroluminescence (EL) imaging technologies play a crucial role in evaluating the performance and stability of photovoltaic devices. However, their application in perovskite devices presents unique challenges ...

2024

Methylammonium Nitrate-Mediated Crystal Growth and Defect Passivation in Lead Halide Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Kevin Sivula, Jun Ho Yum, Yeonju Kim

Additive engineering has been a crucial strategy to improve photovoltaic properties by reducing carrier trap centers or increasing carrier diffusion lengths in the lead halide perovskite active layer. We introduced a small amount of CH3NH3 +NO3 - (methylam ...

Amer Chemical Soc2024

Identification and Mitigation of Degradation Mechanisms Induced by Heat and Light in NiOx-based Perovskite Solar Cells

Marion Solange Madeleine Dussouillez

Perovskite solar cells (PSCs) offer an attractive solution to increase the efficiency of PV panels via perovskite/silicon tandems thanks to their potential cost-effectiveness and high efficiency. In inverted PSC architecture (p-i-n), commonly used hole con ...

EPFL2024

Tracking deep-level defects in degrading perovskite solar cells with a multifactorial approach

Vivek Subramanian

In this work, we provide a mechanistic understanding of the degradation of perovskite solar cells in operation by focusing on methylammonium lead triiodide (CH3NH3PbI3 or MAPbI3) and tracking the evolution of electronic defects via photo-induced current tr ...

Elsevier2024

Structural divergence of molecular hole selective materials for viable p-i-n perovskite photovoltaics: a comprehensive review

Mohammad Khaja Nazeeruddin, Peng Gao

Perovskite solar cells (PSCs) have garnered significant attention within the photovoltaic research community due to their remarkable progress in just one decade. Among the device configurations, the p-i-n structured PSC offers several advantages, including ...

Royal Society of Chemistry2024

Perovskite Solar Cells: Challenges Facing Polymeric Hole Selective Materials in p-i-n Configuration

Mohammad Khaja Nazeeruddin

Polymeric hole-selective materials (P-HSMs) offer advantages like solution processability, tunable energy levels, and improved mechanical stability, making them suitable for large-scale and flexible substrates. Poly[bis(4-phenyl) (2,4,6-trimethylphenyl) am ...

WILEY-V C H VERLAG GMBH2024

Durable Perovskite Solar Cells with 24.5% Average Efficiency: The Role of Rigid Conjugated Core in Molecular Semiconductors

Michael Graetzel, Shaik Mohammed Zakeeruddin, Peng Wang, Felix Thomas Eickemeyer

Efficient and robust n-i-p perovskite solar cells necessitate superior organic hole-transport materials with both mechanical and electronic prowess. Deciphering the structure-property relationship of these materials is crucial for practical perovskite sola ...

Wiley-V C H Verlag Gmbh2024