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Metal-organic frameworks (MOFs), or coordination polymers (CPs), are networks of organic ligands and metal nodes that form ordered or disordered structures. By selecting appropriate building blocks, CPs with tailored pore shapes, dimensions, and surface ch ...

This work represents a pioneering effort in utilizing continuous flow methods for the post-synthetic modification of a nanoporous metal-organic framework (Fe-BTC or MIL-100(Fe)) with short-chain redox-active oligomers (poly-p-phenylenediamine, PpPDA). The ...

Growing polymers inside porous metal-organic frameworks (MOFs) can allow incoming guests to access the backbone of otherwise non-porous polymers, boosting the number and/or strength of available adsorption sites inside the porous support. In the present wo ...

We introduce a new approach to defect engineering in Zr-based metal-organic frameworks (Zr-MOFs), aiming to reduce Zr site valency while preserving high node connectivity. Using a rapid heat treatment (RHT) in humid air, oxygen vacancies (O-vacancies) were ...

Using azolium-based ligands for the construction of metal-organic frameworks (MOFs) is a viable strategy to immobilize catalytically active N-heterocyclic carbenes (NHC) or NHC-derived species inside MOF pores. Thus, in the present work, a novel copper MOF ...

Herein, data acquisition protocols are explored and data reduction protocols are improved using PDFgetX3 to obtain reliable data for atomic pair distribution function (PDF) analysis from a laboratory‐based Mo K α X‐ray source. A variable counting scheme is ...

The design of metal-organic frameworks (MOFs) having large pore sizes and volumes often requires the use of complex organic ligands, currently synthesized using costly and time-consuming palladium-catalyzed coupling chemistry. Thus, in the present work, a ...

Herein, a post-synthetic modification strategy is used to covalently graft polyamines, including ethylenediamine (ED), diethylenetriamine (DETA), tris(2-aminoethyl)amine (TAEA), and polyethyleneimine (PEI) to the amino-ligand inside of a Cr-MOF, NH2-Cr-BDC ...

The number of synthetic strategies used to functionalize MOFs with polymers is rapidly growing; this stems from the knowledge that non-native polymeric guests can significantly boost MOF performance in a number of desirable applications. The current work p ...

Rigidtritopic linkers of different sizes were used to buildporous U-(IV) and Th-(IV) 3D frameworks. The charge of the polymerscould be tuned by reaction conditions such as the temperature, pH,solvent, ligand, or metal precursor, yielding a series of neutra ...

After grafting polyalkylamine species onto the ligand within a Cr 3+ -MOF, the material was tested for catalyzing cycloaddition reactions between CO 2 and 1,2-epoxybutane (EB). ...

Till Marian Schertenleib

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A local structure perspective on metal-organic frameworks

Post-Synthetic Modification of a MOF via Continuous Flow Methods for Gold E-Waste Recycling

A post-synthetic modification strategy for enhancing Pt adsorption efficiency in MOF/polymer composites

Anisotropic node distortions in amorphous MOFs: Low-valent Zr sites as catalytic hotspots

3D vs. turbostratic: controlling metal-organic framework dimensionality via N-heterocyclic carbene chemistry

Testing Protocols for Obtaining Reliable Pair Distribution Functions from Laboratory X‐Ray Sources Using PDFgetX3

A Simple, Transition Metal Catalyst-Free Method for the Design of Complex Organic Building Blocks Used to Construct Porous Metal-Organic Frameworks

Post-Synthetic Covalent Grafting of Amines to NH2-MOF for Post-Combustion Carbon Capture

Hybridization of Synthetic Humins with a Metal-Organic Framework for Precious Metal Recovery and Reuse

Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids

Immobilizing amine species in a Cr-MOF for enhanced selectivity in CO2 cycloaddition reactions