Publications de Andrzej Gladysiak

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In this work, we report the synthesis of SION-8, a novel metal-organic framework (MOF) based on Ca(II) and a tetracarboxylate ligand TBAPy(4-) endowed with two chemically distinct types of pores characterized by their hydrophobic and hydrophilic properties ...

Metal-organic frameworks (MOFs) are coordination polymer materials in which inorganic metal ions or clusters are linked with multitopic organic ligands by means of coordination bonds. Their structural versatility allows for design of materials based on pre ...

Sustainable catalysts based on earth-abundant elements are considered as economical alternatives to precious-metal-bearing catalysts and could be impactful for many applications. Self-healing sustainable catalysts, which in addition to their 'green' charac ...

Limiting the increase of CO2 in the atmosphere is one of the largest challenges of our generation(1). Because carbon capture and storage is one of the few viable technologies that can mitigate current CO2 emissions(2), much effort is focused on developing ...

A strategy based on the use of ligand steric hindrance and metal doping is reported for the design and synthesis of near-infrared (NIR) emitting lanthanide-based metal-organic frameworks (MOFs). The lanthanide ions are free of coordinated solvents, and the ...

Metal organic frameworks (MOFs) are increasingly used in applications that rely on the optical and electronic properties of these materials. These applications require a fundamental understanding on how the structure of these materials, and in particular t ...

Prolonged consumption of water contaminated with fluoride ions (F-) at concentrations exceeding 1.5 ppm can lead to considerable health implications, particularly in children and developing embryos. With irreversible and potentially severe forms of fluorid ...

Biologically derived metal-organic frameworks (bio-MOFs) are of great importance as they can be used as models for bio-mimicking and in catalysis, allowing us to gain insights into how large biological molecules function. Through rational design, here we r ...

Recyclable materials for simultaneous detection and uptake of ammonia (NH3) are of great interest due to the hazardous nature of NH3. The structural versatility and porous nature of metal-organic frameworks (MOFs) make them ideal candidates for NH3 capture ...

The threat posed by the presence of artificial volatile organic compounds (VOCs) in the environment is a widely acknowledged fact, both for environmental issues and human health concerns. Ever-increasing production requires the continuous development of te ...

A lanthanide-based metal-organic framework (MOF) named SION-2 displays strong and tuneable uniaxial negative thermal expansion (NTE). The coefficient of thermal expansion alpha(1) reaches -153(6) MK-1 between 100 and 340 K, which is the highest value repor ...

A pyrene-based metal-organic framework (MOF) SION-8 captured iodine (I-2) vapor with a capacity of 460 and 250 mg g(MOF)(-1) at room temperature and 75 degrees C, respectively. Single-crystal X-ray diffraction analysis and van-der-Waals-corrected density f ...

Andrzej Gladysiak

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Biporous Metal-Organic Framework with Tunable CO2/CH4 Separation Performance Facilitated by Intrinsic Flexibility

From structure to application: studies on adenine-, pyrene- and lanthanide-based metal-organic frameworks

Discovery of a self-healing catalyst for the hydrolytic dehydrogenation of ammonia borane

Data-driven design of metal-organic frameworks for wet flue gas CO2 capture

Design of lanthanide-based metal-organic frameworks with enhanced near-infrared emission

Taking lanthanides out of isolation: tuning the optical properties of metal-organic frameworks

Selective, Fast-Response, and Regenerable Metal-Organic Framework for Sampling Excess Fluoride Levels in Drinking Water

Nucleobase pairing and photodimerization in a biologically derived metal-organic framework nanoreactor

A Recyclable Metal-Organic Framework as a Dual Detector and Adsorbent for Ammonia

Sustainable Capture of Aromatic Volatile Organic Compounds by a Pyrene-Based Metal-Organic Framework under Humid Conditions

Formation pathways of metal–organic frameworks proceeding through partial dissolution of the metastable phase

Guest-dependent negative thermal expansion in a lanthanide-based metal-organic framework

Reply to "Inconsistencies in the specific nucleobase pairing motif prone to photodimerization in a MOF nanoreactor"

Incarceration of Iodine in a Pyrene-Based Metal-Organic Framework