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Tom Theodorus Antonius Lummen

Cette personne a quitté l’EPFL

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Publications associées (61)

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Tetrasubstituted Thieno[3,2-b]thiophenes as Hole-Transporting Materials for Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Iwan Zimmermann, Inés Garcia Benito

Three hole-transporting materials (HTMs) were prepared following a straightforward synthetic route by cross-linking arylamine-based ligands with a simple thieno[3,2-b]thiophene (TbT) core. The novel HTMs were fully characterized with standard techniques to ...

2020

Perovskite Flash Memory with a Single-Layer Nanofloating Gate

Mohammad Khaja Nazeeruddin, Peng Gao, Tom Theodorus Antonius Lummen, Peng Gao, Hobeom Kim

Here we use triple-cation metal-organic halide perovskite single crystals for the transistor channel of a flash memory device. Moreover, we design and demonstrate a 10 nm thick single-layer nanofloating gate. It consists of a ternary blend of two organic s ...

2020

Phthalocyanines for dye-sensitized solar cells

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen

Phthalocyanines (Pcs) are robust and intensely colored macrocycles (blue pigments) with high chemical, thermal and light stability, properties that are of paramount importance for realistic photovoltaic applications. In particular, Pcs have played a very i ...

2019

Dibenzoquinquethiophene- and Dibenzosexithiophene-Based Hole-Transporting Materials for Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Iwan Zimmermann

Fused oligothiophene-based pi-conjugated organic derivatives have been widely used in electronic devices. In particular, two-dimensional (2D) heteroarenes offer the possibility of broadening the scope by extending the pi-conjugated framework, which endows ...

2019

Nanoscale Perovskite-Sensitized Solar Cell Revisited: Dye-Cell or Perovskite-Cell?

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, So-Min Yoo

A general and straightforward way of preparing few-nanometer-sized well-separated MAPbI(x)Br(3-x) (MA=methylammonium) perovskite photosensitizers on the surface of an approximately 1 mu m thick mesoporous TiO2 photoanode was suggested through a two-step se ...

2020

The Role of Goldschmidt's Tolerance Factor in the Formation of A(2)BX(6) Double Halide Perovskites and its Optimal Range

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Nikita Drigo, Alexander Fedorovskiy

Vacancy-ordered double perovskites is a new branch of lead-free halide perovskites with properties promising for photovoltaic application. In this study, data about the crystal structure of 170 known A(2)BX(6) (X = I, Br, Cl, F) are collected and analyzed ...

2020

Gradient 1D/3D Perovskite Bilayer using 4-tert-Butylpyridinium Cation for Efficient and Stable Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Hiroyuki Kanda, Tom Theodorus Antonius Lummen

To achieve both high efficiency and long-term stability of perovskite solar cells (PSCs), it is effective to use a perovskite layer in which a low-dimensional perovskite layer is stacked on a 3D perovskite layer. However, the guidelines for the effective s ...

2021

Phthalocyanines and porphyrinoid analogues as hole- and electron-transporting materials for perovskite solar cells

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen

Organic-inorganic lead halide perovskite absorbers in combination with electron and hole transporting selective contacts result in power conversion efficiencies of over 23% under AM 1.5 sun conditions. The advantage of perovskite solar cells is their simpl ...

Royal Society of Chemistry2019

Perovskite Solar Cells Using Surface-Modified NiOx Nanoparticles as Hole Transport Materials in n-i-p Configuration

Mohammad Khaja Nazeeruddin, Hiroyuki Kanda, Tom Theodorus Antonius Lummen

Modified NiOx nanoparticles (NPs) developed via surface engineering are applied to a hole transport layer (HTL) in n-i-p-structured perovskite solar cells (PSCs). Hexanoic acid (HA) as a surfactant improves the dispersibility of NiOx NPs in chlorobenzene ( ...

2019

Elucidating the Doping Mechanism in Fluorene-Dithiophene-Based Hole Selective Layer Employing Ultrahydrophobic Ionic Liquid Dopant

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Sanghyun Paek

Perovskite solar cells have set a new milestone in terms of efficiencies in the thin film photovoltaics category. Long-term stability of perovskite solar cells is of paramount importance but remains a challenging task. The lack of perovskite solar cells st ...

2020

In-situ cross-linkable hole transporting triazatruxene monomers for optoelectronic devicestr

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Kasparas Rakstys, Aron Joel Huckaba

The invention discloses a polymerizable triazatruxene-based compound of formula (I), an optoelectronic and/or photoelectrochemical device comprising said compound of formula (I) as hole transporting material in hole transport layer under the form of a poly ...

2019

Simultaneous observation of the quantization and the interference pattern of a plasmonic near-field

Fabrizio Carbone, Tom Theodorus Antonius Lummen, Brett Eugene Barwick, Luca Piazza, Yoshie Murooka

Surface plasmon polaritons can confine electromagnetic fields in subwavelength spaces and are of interest for photonics, optical data storage devices and biosensing applications. In analogy to photons, they exhibit wave-particle duality, whose different as ...

Nature Publishing Group2015

Nanoscale Lead(II) Iodide-sensitized Solar Cell

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, So-Min Yoo

Nanometer-sized PbI2 particles were deposited over mesoporous TiO2 film by spin-coating and tested as a photosensitizer. The as-prepared PbI2-sensitized solar cell gave overall power conversion efficiency of 1.41% which was almost four times better than a ...

2019

Stable and High-Efficiency Methylammonium-Free Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Yi Zhang, Tom Theodorus Antonius Lummen, Wen Luo, Bing Zhang, Florian Berczy

Organic-inorganic metal halide perovskite solar cells (PSCs) have achieved certified power conversion efficiency (PCE) of 25.2% with complex compositional and bandgap engineering. However, the thermal instability of methylammonium (MA) cation can cause the ...

Wiley2020

Ionic dipolar switching hinders charge collection in perovskite solar cells with normal and inverted hysteresis

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Kyung Taek Cho, Iwan Zimmermann, Sadig Aghazada

Drift-diffusion modeling of the ionic dipole switching from the measurement of fast scanned and long pre-biased electrical response is proposed as a novel protocol for evaluation of limit hysteretic effects in perovskite solar cells. Up to eight systems we ...

2019

Methodical review of the literature referred to the dye-sensitized solar cells: Bibliometrics analysis and road mapping

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen

This study presents a systematic review of the literature pertaining to dye-sensitized solar cells (DSSCs), in order to anticipate the direction and speed of change in technology trend. To study the general progression in DSSC research, we have assessed th ...

2019

Effective Preparation of Nanoscale CH3NH3PbI3 Perovskite Photosensitizers for Mesoporous TiO2-Based Solar Cells by Successive Precursor Layer Adsorption and Reaction Process

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Yonghui Lee, Sanghyun Paek, Aron Joel Huckaba, Kyung Taek Cho, Iwan Zimmermann, Hobeom Kim, So-Min Yoo, Alexandre Vincent Laurent Chenu, Michael Gullberg

Nanoscale CH3NH3PbI3 perovskite sensitizers are grown by delivering each precursor successively onto the surface of mesoporous (meso) TiO2 electrodes. Using Pb(NO3)(2) ions as a lead(II) source and CH3NH3I (MAI) for methylammonium and iodide sources, repet ...

2020

Green-Emitting Lead-Free Cs4SnBr6 Zero-Dimensional Perovskite Nanocrystals with Improved Air Stability

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Giulia Grancini, Valentin Ianis Emmanuel Queloz

We report the synthesis and characterization of nanocrystals of a novel fully inorganic lead-free zero-dimensional perovskite, Cs4SnBr6. Samples are made of crystals with an average size of similar to 20 nm with green emission centered around 530 nm. Inter ...

2020

Molecular engineering of simple carbazole-arylamine hole-transport materials for perovskite solar cells

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Yong Ding

We report synthesis and characterization of novel hole-transport materials (HTMs) with substituents, methylsulfonyl, N,N-dimethylamino or methoxy groups, introduced onto the N of the carbazole unit of carbazole-arylamine and their application in perovskite ...

2020

Defect Suppression in Oriented 2D Perovskite Solar Cells with Efficiency over 18% via Rerouting Crystallization Pathway

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Yong Ding, Olga Syzgantseva

Vertically oriented 2D perovskites exhibit promising optoelectronic properties and intrinsic stability, but their photovoltaic application is still limited by the low power conversion efficiency (PCE) compared to 3D analogs. Here, a new crystallization pat ...

2021