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Mathieu Gérard Boccard

Cette personne a quitté l’EPFL

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Publications associées (73)

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Carrier-selective contacts using metal compounds for crystalline silicon solar cells

Mathieu Gérard Boccard, Julie Amandine Dreon

Solar cells rely on the efficient generation of electrons and holes and the subsequent collection of these photoexcited charge carriers at spatially separated electrodes. High wafer quality is now commonplace for crystalline silicon (c-Si) based solar cell ...

WILEY2023

Performance Limitations and Analysis of Silicon Heterojunction Solar Cells Using Ultra-Thin MoOx Hole-Selective Contacts

Christophe Ballif, Gabriel Christmann, Mathieu Gérard Boccard, Jean Cattin, Luca Massimiliano Antognini, Vincent Philippe Paratte, Julie Amandine Dreon

We recently showed that silicon heterojunction solar cell with MoOx-based hole-selective contact could reach 23.5% in efficiency with MoOx layers of 4 nm. Such thin MoOx layer enables a considerable current-density gain of over 1 mA/cm(2) compared to the u ...

2021

Nanocrystalline silicon oxide stacks for silicon heterojunction solar cells for hot climates

Christophe Ballif, Mathieu Gérard Boccard, Jean Cattin, Raphaël Monnard, Luca Massimiliano Antognini, Jan Haschke

AIP Publishing2018

Low Temperature p-type Microcrystalline Silicon as Carrier Selective Contact for Silicon Heterojunction Solar Cells

Christophe Ballif, Mathieu Gérard Boccard, Raphaël Monnard, Angela Nicole Fioretti

Silicon heterojunction (SHJ) solar cells have reached record efficiency, particularly in all-back-contacted architectures. Despite this, two-side contacted SHJ cells still suffer from parasitic absorption and series resistance losses in the amorphous silic ...

2019

Influence of the Subcell Properties on the Fill Factor of Two-Terminal Perovskite-Silicon Tandem Solar Cells

Christophe Ballif, Mathieu Gérard Boccard

The performance of a tandem solar cell depends on the performance of its constituting subcells. Although this dependency is theoretically straightforward for open-circuit voltage (V-oc) and short-circuit current, it is indirect for fill factor (FF) and thu ...

2020

Gallium Nitride as Transparent Electron-Selective Contact in Silicon Heterojunction Solar Cells

Christophe Ballif, Mathieu Gérard Boccard, Angela Nicole Fioretti

Carrier-selective, passivating contacts have allowed silicon heterojunction (SHJ) cells to reach recordbreaking efficiencies particularly in all-back-contacted designs. However, two-side-contacted SHJ cell efficiency has been limited due in part to parasit ...

2019

Reassessment of cell to module gains and losses: Accounting for the current boost specific to cells located on the edges

Christophe Ballif, Jacques Levrat, Mathieu Gérard Boccard, Matthieu Despeisse, Olivier Denis Dupré

The power produced by a photovoltaic module is not simply the sum of the powers of its constituents cells. The difference stems from a number of so-called “cell-to-module” (CTM) gain or loss mechanisms. These are getting more and more attention as improvem ...

2018

Silicon Heterojunction Solar Cells on Quasi-mono Wafers

Christophe Ballif, Antoine Descoeudres, Mathieu Gérard Boccard, Matthieu Despeisse, Loris Barraud, Raphaël Monnard, Jan Haschke

We applied hydrogen passivation, gettering and a combination of both to quasi-mono (qm) wafer material to enhance its bulk lifetime and prepared silicon heterojunction (SHJ) solar cells. We find that while our applied hydrogen passivation alone seems not t ...

IEEE2018

Fully textured monolithic perovskite/silicon tandem solar cells with 25.2% power conversion efficiency

Christophe Ballif, Laura Ding, Sylvain Nicolay, Quentin Thomas Jeangros, Davide Sacchetto, Mathieu Gérard Boccard, Matthieu Despeisse, Jérémie Werner, Florent Sahli, Loris Barraud, Raphaël Monnard, Gianluca Cattaneo, Bertrand Yves Paul Paviet-Salomon, Björn Niesen, Matthias Wolfgang Bräuninger

Tandem devices combining perovskite and silicon solar cells are promising candidates to achieve power conversion efficiencies above 30% at reasonable costs. State-of-the-art monolithic two-terminal perovskite/silicon tandem devices have so far featured sil ...

2018

Silicon heterojunction solar cells: Recent technological development and practical aspects - from lab to industry

Christophe Ballif, Mathieu Gérard Boccard, Jan Haschke, Olivier Denis Dupré

We review the recent progress of silicon heterojunction (SHJ) solar cells. Recently, a new efficiency world record for silicon solar cells of 26.7% has been set by Kaneka Corp. using this technology. This was mainly achieved by remarkably increasing the fi ...

2018

Highly Conductive and Broadband Transparent Zr-Doped In2O3 as Front Electrode for Solar Cells (vol 8, pg 1202, 2018)

Christophe Ballif, Mathieu Gérard Boccard, Matthieu Despeisse, Loris Barraud, Raphaël Monnard, Jakub Holovsky, Monica Morales Masis, Oscar Esteban Rucavado Leandro

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC2019

Micromorph silicon solar cell optical performance: Influence of intermediate reflector and front electrode surface texture

Franz-Josef Haug, Mathieu Gérard Boccard

The optical performance of tandem a-Si:H/mu c-Si:H (micromorph) thin film solar cell was investigated experimentally and by means of rigorous 3-D optical simulation. The interplay of intermediate reflectors, with different refractive indices and thicknesse ...

Elsevier Science Bv2014

Highly transparent ZnO bilayers by LP-MOCVD as front electrodes for thin-film micromorph silicon solar cells

Christophe Ballif, Laura Ding, Sylvain Nicolay, Grégory Bugnon, Mathieu Gérard Boccard, Matthieu Despeisse

ZnO bilayer films were deposited by a low-pressure metalorganic chemical vapor deposition technique in a single process step, by doping with boron only the nucleation stage of the growth. The resulting 2 pm thick layers are characterized by low free carrie ...

Elsevier2012

22% Efficient Dopant-free Interdigitated Back Contact Silicon Solar Cells

Christophe Ballif, Mathieu Gérard Boccard, Matthieu Despeisse, Bertrand Yves Paul Paviet-Salomon, Sihua Zhong

In this study, we present dopant-free back contact heterojunction silicon solar cells employing MoOx and MgFx based stacks as hole-and electron-selective contacts deposited using a thermal evaporation process at low temperature. Only two masking steps and ...

AMER INST PHYSICS2018

Temperature‐dependent performance of silicon heterojunction solar cells with transition‐metal‐oxide‐based selective contacts

Mathieu Gérard Boccard, Julie Amandine Dreon

The temperature coefficient (TC) is an essential figure of merit to accurately evaluate solar cell performance at various operating temperatures and hence enabling the comparison between different cell technologies. Recently, solar cells that use passivati ...

2021

ZnO Transparent conductive oxide for thin film silicon solar cells

Christophe Ballif, Sylvie Faÿ, Andrea Feltrin, Peter Cuony, Sylvain Nicolay, Grégory Bugnon, Franz-Josef Haug, Mathieu Gérard Boccard, Matthieu Despeisse

There is general agreement that the future production of electric energy has to be renewable and sustainable in the long term. Photovoltaic (PV) is booming with more than 7GW produced in 2008 and will therefore play an important role in the future electric ...

Spie-Int Soc Optical Engineering, Po Box 10, Bellingham, Wa 98227-0010 Usa2010

Evaluating Materials Design Parameters of Hole-Selective Contacts for Silicon Heterojunction Solar Cells

Christophe Ballif, Mathieu Gérard Boccard, Jan Haschke, Angela Nicole Fioretti

Silicon heterojunction (SHJ) solar cell efficiencies are limited by parasitic absorption from the hydrogenated amorphous silicon (a-Si:H) front contact, but this may be mitigated by selecting an alternative carrier selective contact material with a wider b ...

2020

Hybrid sequential deposition process for fully textured perovskite/silicon tandem solar cells

Christophe Ballif, Laura Ding, Sylvain Nicolay, Quentin Thomas Jeangros, Soo-Jin Moon, Arnaud Walter, Davide Sacchetto, Mathieu Gérard Boccard, Matthieu Despeisse, Jérémie Werner, Florent Sahli, Loris Barraud, Raphaël Monnard, Monica Morales Masis, Gianluca Cattaneo, Bertrand Yves Paul Paviet-Salomon, Björn Niesen, Gizem Nogay, Oscar Esteban Rucavado Leandro, Matthias Wolfgang Bräuninger, Peter Joseph Fiala, Chien-Jen Yang, Fan Fu

Tandem solar cells that feature a high-bandgap perovskite cell on top of a lower bandgap silicon cell have the potential to reach efficiencies > 30%. Here, we present a versatile hybrid deposition method that yields conformal perovskite cells directly on t ...

IEEE2018

Paths for maximal light incoupling and excellent electrical performances in silicon heterojunction solar cells

Christophe Ballif, Mathieu Gérard Boccard, Matthieu Despeisse, Jean Cattin, Raphaël Monnard, Luca Massimiliano Antognini, Vincent Philippe Paratte, Laurie-Lou Senaud, Monica Morales Masis, Bertrand Yves Paul Paviet-Salomon, Oscar Esteban Rucavado Leandro, Jan Haschke, Olivier Denis Dupré, Julie Amandine Dreon, Sihua Zhong, Angela Nicole Fioretti

We discuss here optical losses in silicon heterojunction solar cells and strategies to minimize them. Optical losses originate from most non-crystalline-silicon layers involved in the solar cell. A breakdown for typical values is shown evidencing that supp ...

IEEE2019

Bandgap engineering of indium gallium nitride layers grown by plasma-enhanced chemical vapor deposition

Christophe Ballif, Aïcha Hessler-Wyser, Nicolas Würsch, Franz-Josef Haug, Mathieu Gérard Boccard, Jonathan Emanuel Thomet, Nils Toggwyler, Mélanie Nelly Rouèche

This paper reports on the fabrication of In xGa 1 - xN (InGaN) layers with various compositions ranging from InN to GaN using a cost-effective low-temperature plasma-enhanced chemical vapor deposition (PECVD) method and analyzes the influence of deposition ...

2022